Abstract
The abandoned mining wastes still represent one of the significant environmental hazards. Kef Ettout tailings is one example that was exposed to severe ambient conditions and must be assessed to determine its potential risks. The initial mine wastes, the tailings, and agricultural soils were investigated. The results showed that the winds and runoff water distributed the potentially toxic metals and the alkaline pH of tailings and soils, the carbonate, and TOC content controlled the metal bioavailability. About 22% of Pb and 70 and 98% of Zn and Cd, respectively, were leached from tailings. Despite the initial wastes were richer in Zn (1.5 times) than in Pb, the tailings kept much more Pb (1.6 times) than Zn. In agricultural soils, the mean concentrations of Pb, Zn, and Cd were 69, 141, and 1.8 mg kg−1, respectively. The enrichment factor and geoaccumulation index showed that more than 75% of soils were considered strongly contaminated. Speciation results indicated that about 97% of initial wastes metals were bounded to residual fractions. However, in tailings, 9–30, 4–10, and < 6% of Pb, Zn, and Cd, respectively, were in stable forms. Redistribution index (Utf) and relative binding intensity (IR) of metal tailing had confirmed that the tailings continued to provide more Zn quantity than Pb and Cd. In soils, the highest percentages of Pb and Zn were closely associated with organic matter, the Cd was significantly bounded to the exchangeable fraction, and the mean decreasing factor mobility order was Cd (66) < Pb (73) < Zn (78). Therefore, this tailings type must be rehabilitated to limit its risks, particularly of Zn.
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References
Abdallah S, Al-Hobaib KQ, Al-Jaseem HMBA, Ahmed HA (2012) Environmental impact assessment inside and around Mahd Adh Dhahab gold mine, Saudi Arabia. Arab J Geosci 5:985–997
AFNOR, (1979) France (norms AFNOR, www.afnor.fr)
Agnieszka S, Wieslaw Z (2002) Application of sequential extraction and the ICPAES method for study of the partitioning of metals in fly ashes. Microchem J 72:9–16
Alekseenko VA, Pashkevich MA, Alekseenko AV (2017) Metallisation and environmental management of mining site soils. J Geochem Explor 174:121–127
Alexander CR, Smith RG, Calder FD, Schropp SJ, Windom HL (1993) The historical record of metal enrichments in two Florida estuaries. Estuaries 16:627–637
Baize D (1997) Teneurs totales en éléments traces métalliques dans les sols (France). Références et stratégies d’interprétation. INRA Éditions, Paris, p 410
Banin A, Gerstl Z, Fine PN, Metsger Z, Newzella D (1990) Minimizing soil contamination through control of sludge transformations in soil, Joint German-Israel Research. Projects Report No Wt 8678/458
Batik P (1980) Carte géologique de la Tunisie; feuille n°11: Hédil. Service Géologique, Office National des Mines
Bergaya E, Vayer M (1997) CEC of clays: measurement by adsorption of a copper ethylenediamine complex. Appl Clay Sci 12:275–280
Bian Z, Miao X, Lei S, Chen S, Wang W, Struthers S (2012) The challenges of reusing mining and mineral-processing wastes. Science 337:702–703
Blanchard C (2000) Caractérisation de la mobilisation potentielle des polluants inorganiques dans les sols pollués. Thèse spécialité: Science et technique du déchet Ecole doctorale de chimie de Lyon France, 241p
Bodar CW, Pronk ME, Sijm DT (2006) The European Union risk assessment on zinc and zinc compounds: the process and the facts. Integr Environ Asses 1(4):301–319
Bolan N, Kunhikrishnan A, Thangarajan R, Kumpiene J, Park J, Makino T, Kirkham MB, Scheckel K (2014) Review remediation of heavy metal(loid)s contaminated soils: to mobilize or to immobilize? J Hazard Mater 266:141–166
Bosmans H, Paenhuys J (1980) The distribution of heavy metals in the soils of the Kempen. Pédologie 15:191–223
Bowen HJM (1979) Environmental chemistry of the elements. Academic Press, London
Buccolieri A, Buccolieri G, Dell’Atti A, Strisciullo G, Gagliano-Candela R (2010) Monitoring of total and bioavailable heavy metals concentration in agricultural soils. Environ Monit Assess 168:547–560
Camden-Smith BPC, Tutu H (2014) Geochemical modelling of the evolution and fate of metal pollutants arising from an abandoned gold mine tailings facility in Johannesburg. Water Sci Technol 69(5):1108–1114
Canadian Council of Ministers of the Environment (1991) Canadian water quality guidelines for the protection of aquatic life: guidance on the site-specific application of water quality guidelines in Canada: procedures for deriving numerical water quality objectives. In: Canadian environmental quality guidelines, Canadian Council of Ministers of the Environment, Winnipeg
Chai Y, Guo J, Chai S, Cai J, Xue L, Zhang Q (2015) Source identification of eight heavy metals in grassland soils by multivariate analysis from the Baicheng–Songyuan area, Jilin Province, Northeast China. Chemosphere 134:67–75
Charef A, Sheppard SMF (1991) The diapir related Bou Grine Pb–Zn deposit (Tunisia): evidence for role of hot sedimentary basin brines. In: Pagel M, Leroy J (eds) Source, transport and deposition of metals. Balkema, Rotterdam, pp 269–272
Chotpantarat S, Chunhacherdchai L, Wikiniyadhanee R, Tongcumpou C (2015) Effects of humic acid amendment on the mobility of heavy metals (Co, Cu, Cr, Mn, Ni, Pb, and Zn) in gold mine tailings in Thailand. Arab J Geosci 8:7589–7600
D.G.R.E (2000) Annuaire de l’exploitation des nappes. Rapport D.G.R.E, Tunis 282p
Daldoul G, Souissi R, Souissi F, Jemmali N, Chakroun HK (2015) Assessment and mobility of heavy metals in carbonated soils contaminated by old mine tailings in North Tunisia. J Afr Earth Sci 110:150–159
Dang Z, Liu C, Haigh MJ (2002) Mobility of heavy metals associated with the natural weathering of coal mine spoils. Environ Pollut 118:419–426
Davidson CM, Duncan AL, Littlejohn D, Ure AM, Garden LM (1998) A critical evaluation of the three-stage BCR sequential extraction procedure to assess the potential mobility and toxicity of heavy metals in industrially-contaminated land. Anal Chim Acta 363:45–55
Deneux-Mustin S, Roussel-Debet S, Mustin C, Henner P, Munier-Lamy C, Colle C, Berthelin J, Garnier-Laplace J, Leyval C (2003) Mobilité et transfert racinaire des éléments traces : influence des micro-organismes du sol. Pref Elisabeth Leclerc-Cessac Paris, Tec et Doc
Escarre J, Lefebvre C, Raboyeau S, Dossantos A, Gruber W, Cleyet Marel JC, Frerot H, Noret N, Mahieu S, Collin C, Van Oort F (2011) Heavy metal concentration survey in soils and plants of the Les Malines Mining District (Southern France): implications for soil restoration. Water Air Soil Poll 216:485–504
Esshaimi M, Ouazzani N, El Gharmali A, Berrkhis F, Valiente M, Mandi L (2013) Speciation of heavy metals in the soil and the tailings, in the zinc-lead Sidi Bou Othmane abandoned mine. Environ Earth Sci 3(8):138–147
Ettler V, Mihaljevic M, Kribek B, Majer V, Sebek O (2011) Tracing the spatial distribution and mobility of metal/metalloid contaminants in Oxisols in the vicinity of the Nkana copper smelter, Copperbelt province, Zambia. Geoderma 164:73–84
Fang ZQ (2016) Pollution Characteristics of Heavy Metal in Soil from Lead and Zinc mine and its Stabilization Study. China University of Mining & Technology, Beijing
Fiedler HD, Lopez-Sanchez JF, Rubio R, Rauret G, Quevauviller PH, Ure AM, Muntau H (1994) Study of the stability of extractable trace metal contents in a river sediment using sequential extraction. Analyst 119:1109–1114
Fijałkowski K, Kacprzak M, Grobelak A, Placek A (2012) The influence of selected soil parameters on the mobility of heavy metals in soils. Inż Och Środ 15:81–92
Gworek B, Barański A, Czarnowski K, Sienkiewicz J, Porębska G (2000) Risk assessment in contaminated land management. Rocz Gleboznawcze 3:101–110
Haghiri F (1974) Plant uptake of cadmium as influenced by cation exchange capacity, organic matter, zinc and soil temperatures. J Environ Qual 3:180–183
Hakanson L (1980) An ecological risk index for aquatic pollution control, a sedimentological approach. Water Res 14:975–1001
Halim MA, Majumder RK, Zaman MN, Hossain S, Rasul MG, Sasak K (2013) Mobility and impact of trace metals in Barapukuria coal mining area, Northwest Bangladesh. Arab J Geosci 6(12):4593–4605
He ZL, Yanga XE, Stoffellab PJ (2005) Trace elements in agroecosystems and impacts on the environment. J Trace Elem Med Biol 19:125–140
Ho D, Evans GJ (1997) Operational speciation of cadmium, copper, lead and zinc in the NIST standard reference materials 2710 and 2711 (Monatna soil) by the BCR sequential extraction procedure and flame atomic absorption spectrometry. Anal Commun 34:363–364
Huang SW, Jin JY (2008) Status of heavy metals in agricultural soils as affected by different patterns of land use. Environ Monit Assess 139(1–3):317–327
Huang H, Li T, Gupta D, He Z, Yang XE, Ni B, Li M (2012) Heavy metal phytoextraction by Sedum alfredii is affected by continual clipping and phosphorus fertilization amendment. J Environ Sci 24:376–386
Huynh TH (2009) Impacts des métaux lourds sur l’interaction plante/verre de terre/microflore tellurique. Université Paris-Est, Océan 170p
Kabala C, Singh BR (2001) Fractionation and mobility of copper, lead and zinc in soil profiles in the vicinity of a copper smelter. J Environ Qual 30:485–492
Kabata-Pendias A, Pendias H (2001) Trace elements in soils and plants. CRC Press Inc. 3ème Ed Kalbitz K, Wennrich R. Sci Total Environ, Boca Raton, pp 209–227
Kalbitz K, Rupp H, Meißner R, Braumann F (1998) Veränderungen in der Stoffdynamik eines Niedermoorgebietes durch Renaturierungsmaßnahmen. In: Geller W et al (ed) Gewässerschutz im Einzugsgebiet der Elbe. UFZ, Umweltforschungszentrum Leipzig-Halle GmbH. Vieweg+Teubner Verlag
Karczewska A (1996) Metal species distribution in top- and sub-soil soil in an area affected by copper smelter emissions. Appl Geochem 11:35–42
Khamseh A, Shahbazi F, Oustan S, Najafi N, Davatgar N (2017) Impact of tailings dam failure on spatial features of copper contamination (Mazraeh mine area, Iran). Arab J Geosci 10:244
Kossoff D (2014) Mine tailings dams: characteristics, failure, environmental impacts, and remediation. Appl Geochem 51:229–245
Kucharski R, Sas-Nowosielska A, Małkowski E, Japenga J, Kuperberg JM (2008) Phytoremediation technologies used to reduce environmental threat posed by metal-contaminated soils: theory and reality. In: Barnes I, Kharytonov MM (eds) Simulation and assessment of chemical processes in a multiphase environment. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht
Lama EJ, Cánovasb EJM, Gálveza ME, Montofréb ÍL, Keithc BF, Fazd Á (2017) Evaluation of the phytoremediation potential of native plants growing on a copper mine tailing in northern Chile. J Geochem Explor 182:210–217
Lamy I (2002) Réactivité des matières organiques des sols vis-à-vis des métaux. J Natl l’étude Sols 22
Lei M, Zhang Y, Khan S, Qin PF, Liao BH, Liao BH (2010) Pollution, fractionation, and mobility of Pb, Cd, Cu, and Zn in garden and paddy soils from a Pb/Zn Mining area. Environ Monit Assess 168:215–222
Li LY, Li RS (2000) The role of clay minerals and effect of H+ ions on removal of heavy metal (Pb2+) from contaminated soil. Can Geotech J 37:296–307
Liakopoulos A, Lemiere B, Michael K, Crouzet C, Laperche V, Romaidis I, Drougas I, Lassin A (2010) Environmental impacts of unmanaged solid waste at a former base metal mining and ore processing site (Kirki, Greece). Waste Manag Res 28:996–1009
Lopez-Sanchez JF, Sahuquillo A, Fiedler HD, Rubio R, Rauret G, Muntau H, Quevauviller P (1998) CRM 601, a stable material for its extractable content of heavy metals. Analyst 123:1675–1677
Ma LQ, Rao GN (1997) Chemical fractionation of cadmium, copper, nickel, and zinc in contaminated soils. J Environ Qual 13:372–376
Martin R, Sanchez DM, Gutierrez AM (1998) Sequential extraction of U, Th, Ce, La and some heavy metals in sediments from Ortigas River, Spain. Talanta 46:1115–1121
McLean JE, Bledsoe BE (1992) Behaviour of metals in soils. U.S. Environmental Protection Agency /540/S92/018
Mil-Homens M, Stevens RL, Abrantes FF, Cato I (2006) Heavy metal assessment for surface sediments from three areas of the Portuguese continental shelf. Cont Shelf Res 26(10):1184–1205
Moncur MC, Ptacek CJ, Blowes DW, Jambor JL (2005) Release transport and attenuation of metals from an old tailings impoundment. Appl Geochem 20:639–659
Montoroi JP (1997) Electric conductivity of soil solution and aqueous. Etude Gest Sols 4:279–298
Mouni L, Belkhiri L, Bouzaza A, Bollinger JC (2017) Interactions between Cd, Cu, Pb, and Zn and four different mine soils. Arab J Geosci 10:77
Mseddi H (2013) Caractérisation des rejets miniers des sédiments et des sols d’El Akhouat (bassin versant aval de l’oued Siliana) phytoremediation des sols pollués -Tunisie-. Thèse de Doctorat de l’Université de Tunis El Manar, Tunisie. 221p
Müller G (1969) Index of geoaccumulation in sediments of the Rhine River. J Geol 2:109–118
Narwal RP, Singh BR, Salbu B (1999) Association of cadmium, zinc, copper and nickel with components in naturally heavy metal rich soils studied by parallel and sequential extractions. Commun Soil Sci Plant 30:1209–1230
Neal NH, Sposito G (1986) Effect of organic matter on the distribution, extractability and uptake of cadmium in soils. Soil Sci 44:641–650
Nganje TN, Adamu CI, Ugbaja AN, Ebieme E, Sikakwe GU (2011) Environmental contamination of trace elements in the vicinity of Okpara coal mine, Enugu, Southeastern Nigeria. Arab J Geosci 4(1–2):199–205
Obiora SC, Chukwu A, Davies TC (2016) Heavy metals and health risk assessment of arable soils and food crops around Pb–Zn mining localities in Enyigba, southeastern Nigeria. J Afr Earth Sci 116:182–189
Ociepa E, Kisiel A, Lach J (2010) Effect of fertilization with sewage sludge and composts on the change of cadmium and zinc solubility in soils. J Environ Stud 2:171–175
Othmani MA (2013) Caractérisation des rejets miniers de Touiref (Nord-Ouest de la Tunisie) et dynamique des métaux lourds dans les conditions superficielles et impact sur l’environnement. Thèse de Doctorat de l’Université de Tunis El Manar, Tunisie, 243p
Ouchir N, Ben Aissa L, Boughdiri M, Aydi A (2016) Assessment of heavy metal contamination status in sediments and identification of pollution source in Ichkeul Lake and rivers ecosystem, northern Tunisia. Arab J Geosci 9:539
Papadopoulou-Vrynioti K, Alexakis D, Bathrellos GD, Skilodimou HD, Vryniotis D, Vasiliades E (2014) Environmental research and evaluation of agricultural soil of the Arta plain, western Hellas. J Geochem Explor 136:84–92
Parizanganeh A, Hajisoltani P, Zamani A (2010) Assessment of heavy metal pollution in surficial soils surrounding Zinc Industrial Complex in Zanjan-Iran. Procedia Environ Sci 2:162–166
Perel’man AI (1986) Geochemical barriers: theory and practical applications. Appl Geochem 1(6):669–680
Plassard F, Winiarski T, Petit-Ramel M (2000) Retention and distribution of three heavy metals in a carbonated soil: comparison between batch and unsaturated column studies. J Contam Hydrol 42:99–111
Prasad MNV, Freitas H (2003) Metal hyperaccumulation in plants biodiversity prospecting for phytoremediation technology. Electron J Biotechnol 6:275–321
Rao SC, Northup BK (2008) Forage and grain soybean effects on soil water content and use efficiency. Crop Sci 48(2):789–793
Rauret G, López-Sánchez JF, Sahuquillo A, Barahona E, Lachica M, Ure AM, Davidson CM, Gomez A, Luck D, Bacon J, Yli-Halla M, Muntau H, Quevauviller P (2000) Application of a modified BCR sequential extraction (three-step) procedure for the determination of extractable trace metal contents in a sewage sludge amended soil reference material (CRM483), complemented by a three-year stability study of acetic acid and EDTA extractable metal content. J Environ Monit 2:228–233
Rayment GE, Lyons DJ (2011) Soil chemical methods—Australasia. CSIRO Publishing, Melbourne 495+20 pp
Rodriguez L, Ruiz E, Alonso-Azcarate J, Rincon J (2009) Heavy metal distribution and chemical speciation in tailings and soils around a Pb-Zn mine in Spain. J Environ Manag 90:1106–1116
Rouvier H (1977) Géologie de l'extrême Nord tunisien: Tectonique et paléogéographies superposées à l'extrémité orientale de la chaîne nord-maghrébine. Doctorat d'Etat. 2 Volumes, Univer Paris-Orsy 703 p
Sainfeld P (1952) Les gites plombo-zincifères de la Tunisie. Ann Mines Géol 9 Tunis:285
Salbu B, Krekling T, Oughton DH (1998) Characterization of radioactive particles in the environment. Analyst 123:843–849
Salomons W (1993) Adoption of common schemes for single and sequential extractions of trace metals in soil and sediments. Int J Environ Anal Chem 51:3–4
Salomons W, Stigliani W (1995) Biogeodynamics of pollutants in soils and sediments. Springer-Verlag, Berlin, 352p
Schultz LG (1964) Quantitative interpretation of mineral composition from X-ray and chemical data for the Pierre Shale U. S. Geol. Survey Prof. Paper 391C, United States Government Printing Office, Washington, D.C., C1-C31
Sebei A (2007) Impact des rejets miniers sur l’environnement. Cas de bassins versants des Oueds Mellègue et Tessa (Tunisie septentrionale). Thèse de Doctorat de l’Université deTunis El Manar, Tunisie, 256p
Sherlock EJ, Lawrence RW, Poulin R (1995) On the neutralization of acid rock drainage by carbonate and silicate minerals. Environ Geol 25:43–54
Sliti N (2013) Minéralogie et composition chimiques des rejets miniers et des sols dans l’ancien district de Khanguet Kef Ettout. Mastère de Recherche de l’Université de Tunis El Manar, Tunisie, 131p
Staunton S (2002) Direct and indirect effects of organic matter on metal immobilisation in soil. Dev Soil Sci 28(Part A):79–97
Sutherland RA (2000) Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii. Environ Geol 39:611–627
Trefrey JH, Presley BJ (1976) Heavy metals in sediments from San Antonio Bay and the Northwest Gulf of Mexico. Environ Geol 1(5):283–294
Trifi M, Dermech M, Charef A, Azouzi R, Hjiri B (2018) Extraction procedures of toxic and mobile heavy metal fraction from complex mineralogical tailings affected by acid mine drainage. Arab J Geosci 11:328
Ure AM, Quevauviller P, Muntau P, Greipink B (1993) Speciation of heavy metals in soils and sediments. An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the Commission of the European Communities. Int J Environ Anal Chem 51(1–4):135–151
Usero J, Gamero M, Morillo J, Gracia I (1998) Comparative study of three sequential extraction procedures for metals in marine sediments. Environ Int 24:478–496
Vamerali T, Bandiera M, Mosca G (2010) Field crops for phytoremediation of metal – contaminated land. A review. Environ Chem Lett 8:1–17
Van der Marel HW (1966) Quantitative analysis of clay minerals and their admixtures. Contrib Mineral Petrol 12(1):96–138
Van Loon GW, Duffy SJ (2007) Chemia środowiskowa, Wyd. Naukowe PWN, Warszawa
Wang L, Li Y, Haoran Wang H, Cui X, Wang Xing LA, Wang X, Wang C, Gan D (2017) Weathering behavior and metal mobility of tailings under an extremely arid climate at Jinchuan Cu-Ni sulfide deposit Western China. J Geochem Explor 173:1–12
Yadav HL, Jamal A (2015) Impact of mining on water resources in India. Int J Adv Res 3(10):1009–1015
Yuan CG, Shi JB, He B, Liu JF, Liang LN, Jiang GB (2004) Speciation of heavy metals in marine sediments from the East China Sea by ICP-MS with sequential extraction. Environ Int 30:769–783
Zhong L, Liu L, Yang J (2012) Characterization of heavy metal pollution in the paddy soils of Xiangyin County, Dongting lake drainage basin, central south China. Environ Earth Sci 67(8):2261–2268
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The constructive and thorough reviews of anonymous reviewers are warmly acknowledged. Additionally, we would like to thank Pr. Simon Sheppared for the English language revision.
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Sliti, N., Abdelkrim, C. & Ayed, L. Assessment of tailings stability and soil contamination of Kef Ettout (NW Tunisia) abandoned mine. Arab J Geosci 12, 73 (2019). https://doi.org/10.1007/s12517-018-4204-0
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DOI: https://doi.org/10.1007/s12517-018-4204-0