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Organic geochemical characteristics of the Upper Cretaceous–Early Paleogene source rock and correlation with some Egyptian mummy bitumen and oil from the southern Gulf of Suez, Egypt

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Abstract

Previous research has focused upon the geochemical fingerprinting of oil and mummy bitumen in order to define their biomarker characteristics and their geographical origins. Here, a set of source rock samples comprising the Upper Cretaceous–Early Paleogene sequence from the Ras El Bahar-2 borehole on the western coast of the southern Gulf of Suez is investigated for a comparative molecular biomarker link between source rock bitumen and oil and mummy bitumen. The analysed source rocks are quantitatively rich in organic content and qualitatively derived from algae and bacteria deposited in highly reducing environments. The source rocks are sulphur-rich and related to type II-S kerogen, having the ability to generate hydrocarbons at low levels of thermal maturity. For oil and seeps, they are genetically related. The biomarkers suggest their derivation from siliciclastic source rocks that received substantial terrestrial inputs within predominantly Tertiary basins and were deposited in normal marine conditions with pervasive suboxia. The source rock bitumen is correlatable with the Cleopatra mummy bitumen, whereas the oil seeps are comparable with the bitumen from some Egyptian mummies reported in the literature.

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References

  • Barakat AO, Mostafa A, Qian Y, Kim M, Kennicutt MC II (2005) Organic geochemistry indicates Gebel El Zeit, Gulf of Suez, is a source of bitumen used in some Egyptian mummies. Geoarchaeology. Int J 20(3):211–228

    Google Scholar 

  • Buckley SA, Evershed RP (2001) Organic chemistry of embalming agents in Pharaonic and Graeco-Roman mummies. Nature 413:837–841

    Article  Google Scholar 

  • Charrié-Duhaut A, Connan J, Rouquette N, Adam P, Barbotin C, de Rozières M-F, Tchapla A, Albrecht P (2007) The canopic jars of Rameses II: real use revealed by molecular study of organic residues. J Archaeol Sci 34(6):957–967

    Article  Google Scholar 

  • Clark KA, Evershed RP (2005) Detection, use and occurrence of petroleum in Egyptian embalming. Poster, vol. 2, Books of Abstracts of the Communications presented to the 22nd International Meeting on Organic Geochemistry, Seville-Spain, 12–16 September 2005, 1099–1100

  • Connan J (1999) Use and trade of bitumen in antiquity and prehistory: molecular archaeology reveals secrets of past civilizations. Philos Trans R Soc Biol Sci 354:33–50

    Article  Google Scholar 

  • Connan J, Dessort D (1991) Le bitume dans l’Antiquité. La Recherche 229:152–159

    Google Scholar 

  • Connan J, Nissenbaum A, Dessort D (1992) Molecular archaeology: export of Dead Sea asphalt to Canaan and Egypt in the Chalcolithic–Early Bronze Age (4th–3rd millennium BC). Geochim Cosmochim Acta 56:2743–2759

    Article  Google Scholar 

  • EGPC (Egyptian General Petroleum Corporation) (1996) Gulf of Suez oil fields (a comprehensive overview). EGPC, Cairo, p 736

    Google Scholar 

  • El Diasty WS, Peters KE (2014) Genetic classification of oil families in the central and southern sectors of the Gulf of Suez, Egypt. J Petr Geol 37(2):105–126

    Article  Google Scholar 

  • Hammond PC (1959) The Nabatean bitumen industry at the Dead Sea. Biblic Archaeol 22:40–48

    Article  Google Scholar 

  • Harrel JA, Lewan MD (2002) Sources of mummy bitumen in ancient Egypt and Palestine. Archaeometry 44:285–293

    Article  Google Scholar 

  • Huang H, Pearson MJ (1999) Source rock palaeoenvironments and controls on the distribution of dibenzothiophenes in lacustrine crude oils, Bohai Bay Basin, Eastern China. Org Geochem 30:1455–1470

    Article  Google Scholar 

  • Hughes WB, Holba AG, Dzou LI (1995) The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks. Geochim Cosmochim Acta 59:3581–3598

    Article  Google Scholar 

  • Lewan MD, Kotarba MJ, Curtis JB, Więcław D, Kosakowski P (2006) Oil generation kinetics for organic facies with type-II and -IIS kerogen in the Menilite shales of the polish Carpathians. Geochim Cosmochim Acta 70:3351–3368

    Article  Google Scholar 

  • Macke C, Macke-Ribet C, Connan J (2002) Ta Set Neferou: une nécropole de Thèbes-Ouest et son histoire. momification, chimie des baumes, anthropologie, paléopathologie, Dar Namatallah Press, Giza, Le Caire, République Arabe d’Egypte 5, 426 p

  • Mackenzie AS, Patience RL, Maxwell JR, Vandenbroucke M, Durand B (1980) Molecular parameters of maturation in the Toarcian shales, Paris Basin, France. Changes in the configuration of acyclic isoprenoids alkanes, steranes and triterpanes. Geochim Cosmochim Acta 44:1709–1721

    Article  Google Scholar 

  • Maurer J, Möhring T, Rullkötter J, Nissenbaum A (2002) Plant lipids and fossil hydrocarbons in embalming material of roman period mummies from Dakhleh Oasis, Western Desert, Egypt. J Archaeol Sci 29(7):751–762

    Article  Google Scholar 

  • Moldowan JM, Seifert WK, Gallegos EJ (1985) Relationship between petroleum composition and depositional environment of petroleum source rocks. Am Assoc Petr Geol Bull 69:1255–1268

    Google Scholar 

  • Moldowan JM, Dahl J, Huizinga B, Fago F (1994) The molecular fossil record of oleanane and its relation to angiosperms. Science 265:768–771

    Article  Google Scholar 

  • Mostafa AR (1993) Organic geochemistry of source rocks and related crude oils in the Gulf of Suez, Egypt. Berl Geowiss Abh Reihe A 147: p 163

    Google Scholar 

  • Nissenbaum A (1978) Dead Sea asphalts: historical aspects. Am Assoc Petr Geol Bull 62(5):837–844

    Google Scholar 

  • Nissenbaum A (1992) Molecular archaeology: organic geochemistry of Egyptian mummies. J Archaeol Sci 19:1–6

    Article  Google Scholar 

  • Nissenbaum A (1999) Ancient and modern medicinal applications of Dead Sea asphalt (bitumen). Isr J Earth Sci 48:301–308

    Google Scholar 

  • Nissenbaum A, Aizenshtat AZ, Goldberg M (1980) The floating asphalt blocks of the Dead Sea. In: Douglas AG, Maxwell JR (eds) Advances in organic geochemistry 1979. Pergamon Press, London, pp 157–161

    Google Scholar 

  • Peters KE (1986) Guidelines for evaluating petroleum source rock using programmed pyrolysis. Am Assoc Petr Geol Bull 70:318–329

    Google Scholar 

  • Peters KE, Cassa MR (1994) Applied source rock geochemistry. In: Magoon, L.B., Dow, W.G. (Eds.), The Petroleum System–from Source to Trap. Am Assoc Petr Geol Mem 60:93–120

  • Peters KE, Fraser TH, Amris W, Rustanto B, Hermanto E (1999) Geochemistry of crude oils from eastern Indonesia. Assoc Petr GeolBull 83:1927–1942

    Google Scholar 

  • Peters KE, Walters CC, Moldowan JM (2005) The Biomarker guide, 2nd edn. In: Part I “Biomarkers and isotopes in the environmental and human history”, and Part II “Biomarkers and isotopes in petroleum exploration and earth history”, Cambridge University Press, p 1155

  • Robison VD (1995) Source rock characterization of the late cretaceous brown limestone of Egypt. In: Katz B (ed) Petroleum source rocks. Springer, Berlin, pp 265–281

    Chapter  Google Scholar 

  • Rullkötter J, Nissenbaum A (1988) Dead Sea asphalt in Egyptian mummies: molecular evidence. Naturwissenschaften 75:618–621

    Article  Google Scholar 

  • Shanmugam G (1985) Significance of coniferous rain forests and related organic matter in generating commercial quantities of oil, Gippsland basin, Australia. Am Assoc Petr Geol Bull 69:1241–1254

    Google Scholar 

  • Sinninghe Damsté JS, Rijpstra WIC, de Leeuw JW, Schenck PA (1988) Origin of organic sulphur compounds and sulphur-containing high molecular weight substances in sediments and immature crude oils. In: Mattavelli, L. Novelli, L. (Eds.), Advances in Organic Geochemistry 1987. Org Geochem 13:593–606

  • Sinninghe Damsté JS, Kenig F, Koopmans MP, Koster J, Schouten S, Hayes JM, de Leeuw JW (1995) Evidence for gammacerane as an indicator of water column stratification. Geochim Cosmochim Acta 59:1895–1900

    Article  Google Scholar 

  • Tissot BP, Welte DH (1984) Petroleum formation and occurrence, 2nd edn. Springer, New York, p 699

    Book  Google Scholar 

  • Waples DW, Machihara T (1991) Biomarkers for geologists: a practical guide to the application of steranes and triterpanes in petroleum geology. Am Assoc Petr Geol Methods Exploration Series, no. p 9:91

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Acknowledgments

The authors thank the Egyptian General Petroleum Company (GPC) for providing the raw data upon which the present work is based. Gratitude is also expressed to StratoChem Services, New Maadi, Cairo, Egypt for supporting GC and GC–MS analyses. We also thank the reviewers for their constructive criticism of the paper which improved its quality.

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Authors and Affiliations

  1. Faculty of Science, Geology Department, Mansoura University, Mansoura, 35516, Egypt

    W. Sh. El Diasty, S. Y. El Beialy & H. A. El Adl

  2. Faculty of Science, Department of Environmental Sciences, Alexandria University, Alexandria, Egypt

    A. R. Mostafa

  3. School of Geosciences, University of Aberdeen, Aberdeen, UK

    K. J. Edwards

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  1. W. Sh. El Diasty
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  2. A. R. Mostafa
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  3. S. Y. El Beialy
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  4. H. A. El Adl
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  5. K. J. Edwards
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Correspondence to W. Sh. El Diasty.

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El Diasty, W.S., Mostafa, A.R., El Beialy, S.Y. et al. Organic geochemical characteristics of the Upper Cretaceous–Early Paleogene source rock and correlation with some Egyptian mummy bitumen and oil from the southern Gulf of Suez, Egypt. Arab J Geosci 8, 9193–9204 (2015). https://doi.org/10.1007/s12517-015-1855-y

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  • DOI: https://doi.org/10.1007/s12517-015-1855-y

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