Abstract
Excess fluoride in groundwater affects the human health and results in dental and skeletal fluorosis. Higher concentration of fluoride was noted in hard rock terrain of the south India, in the Krishnagiri district of Tamilnadu. The region has a complex geology ranging from ultra basic to acid igneous rocks, charnockite and gneissic rocks. Thirty-four groundwater samples were collected from this study area and analysed for major cations and anions along with fluoride. The order of dominance of cations is Na+ > Mg2+ > Ca2+ > K+ and the anions in the following order HCO3 − > Cl− > NO3 − > SO4 2−. It is found that nearly 58 % of the samples have more fluoride ranging from 1 to 3 mg/L. It is also noted that high fluoride waters correspond to magnesium water types. This is due to the release of fluoride from the magnesium-bearing minerals like, biotite, hornblende, etc., or weathering of apatite/hydroxyapatites found in charnockites.









Similar content being viewed by others
References
Agrawal V, Vaish AK, Vaish P (1997) Ground water quality: focus on fluoride and fluorosis in Rajasthan. Curr Sci 73(9):743–746
Apambire WB, Boyle DR, Michel FA (1997) Geochemistry, genesis and health implication of floriferous groundwater in the upper regions, Ghana. Environ Geo l33:13–24
APHA (1995) Standard methods for the examination of water and waste water. 19th edition, APHA, Washington DC, USASS
Banks D, Reimann C, Røyset O, Skarphagen H, Sæther OM (1995) Natural concentrations of major and trace elements in some Norwegian bedrock groundwaters. Appl Geochem 10:1–16
Bell, Ludwig (1970) The study of fluoride to man ingestion from water in fluorides and human health, WHO Geneva
Cao J, Zhao Y, Liu J (2000) Fluoride in the environment and bricktea-type fluorosis in Tibet. J Fluor Chem 106:93–97
Carrillo-Rivera JJ, Cardona A, Edmunds WM (2002) Use of abstraction regime and knowledge of hydrogeological conditions to control high-fluoride concentration in abstracted groundwater: San Luis Potosí basin, Mexico. J Hydrol 261:24–47
Central Groundwater Board (2009) District groundwater brochure, Krishnagiri district Tamilnadu, CGWB
Chae GT, Yun ST, Choi BY, Kim K, Shevalier M (2005) Geochemical concept and technical development of geological CO2 sequestration for reduction of CO2. Econ Environ Geol 38:1–22 (in Korean)
Chae GT, Yun ST, Mayer B (2007) Fluorine geochemistry in bedrock groundwater of South Korea. Sci Total Environ 385:272–283
Chaturvedi AK, Yadava KP, Pathak KC, Singh VN (1990) Defluoridation of water by adsorption on fly ash. Water Air Soil Pollut 49:51–61
Chidambaram S (2000) Hydrogeochemical studies of groundwater in Periyar district, Tamilnadu, India, unpublished Ph.D thesis, Department of Geology, Annamalai University, Tamilnadu, India
Chidambaram S, Ramanathan AL, Vasudevan S (2003) Fluoride removal studies in Water using natural materials. Water SA 29:339–344
Chidambaram S, Bala Krishna Prasad M, Manivannan R, Karmegam U, Singaraja C, Anandhan P, Prasanna MV, Manikandan S (2012) Environmental hydrogeochemistry and genesis of fluoride in groundwaters of Dindigul district, Tamilnadu (India). Environ Earth Sci. doi:10.1007/s12665-012-1741-9
Choubasia SL, Sompura K (1996) Dental fluorosis in tribal villages of Dungerpur district Rajasthan. Poll Res 15(1):45–47
Deshmukh AN, Valadaskar PM, Malpe DB (1995) Fluoride in environment: a review. Gondwana Geol Mag 9:1–20
Deutsch WJ, Jenne EA, Krupka KM (1982) Solubility equilibria in basalt aquifers—the Columbia Plateau, eastern Washington, USA. Chem Geol 36:15–34
Dowgiałło J (2000) Thermal water prospecting results at Jelenia Góra- Cieplice (Sudetes, Poland) versus geothermometric forecasts. Environ Geol 39:433–436
Edmunds WM, Smedley PM (1996) Groundwater geochemistry and health—an overview. In Appleton JD, Fuge R and McCall GJH (Eds)
Fordyce FM, Vrana K, Zhovinsky E, Povoroznuk V, Toth G, Hope BC, Iljinsky U, Baker J (2007) A health risk assessment for fluoride in Central Europe. Environ Geochem Health 29:83–102. doi:10.1007/s10653-006-9076-7
Frengstad B, Banks D, Siewers U (2001) The chemistry of Norwegian groundwaters: IV. The dependence of element concentrations in crystalline bedrock groundwaters. Sci Total Environ 277:101–117
Fung K, Zhang Z, Wong J, Wong M (1999) Fluoride contents in tea and soil from tea plantations and the release of fluoride into tea liquor during infusion. Environ Pollut 104:197–205
Gaciri SJ, Davies TC (1993) The occurrence and geochemistry of fluoride in some natural waters of Kenya. J Hydrol 143:395–412
Geological Survey of India (2009) Miscellaneous Publication No. 30, Part-xxii Geology and Mineral Resources of India, GSI
Gizaw B (1996) The origin of high bicarbonate and fluoride concentration in waters of the Main Ethiopian Rift Valley, East African Rift system. J Afr Earth Sci 22:391–402
Handa BK (1975) Geochemistry and genesis of fluoride containing groundwater in India. Ground Water 13:275–281
Hurtado R, Gardea-Torresdey J (2004) Environmental evaluation of fluoride in drinking water at “Los altos de Jalisco,” in the central Mexico region. J Toxicol Environ Health 67:1741–1753
Jacks G, Bhattacharya P, Chaudhary V, Singh KP (2005) Controls on the genesis of some high-fluoride groundwater in India. Appl Geochem 20:221–228
Jolly SS, Prasad S, Sharma R, Chander R (1973) Endemic fluorosis in Punjap. I. Skeletal aspects. Fluoride 6:4–18
Jubb T, Annand TE, Main DC, Murphy GM (1993) Phosphorus supplements and fluorosis in cattle a northern Australian experience. Aust Vet J 70:379–383
Karthikeyan G, Anitha P, Apparao BV (1996) Contribution of fluoride in water and food to the prevalence of fluorosis in areas of Tamil Nadu in South India. ISFR Fluoride 29:151–155
Kim JY, Chon HT (2001) Pollution of a water course impacted by acid mine drainage in the Imgok creek of the Gangreung coal field, Korea. Appl Geochem 16:1387–1396
Kim K, Jeong GY (2005) Factors influencing natural occurrence of fluoride rich groundwaters. A case study in the southeastern part of the Korean Peninsula. Chemosphere 58:1399–1408
Lee JU, Chon HT, John YW (1997) Geochemical characteristics of deep granitic groundwater in Korea. J Korea Soc Groundwater Environ 4:199–211 (in Korean)
Li Y-H, Wang S, Zhang X, Wei J, Xu CZ, Luan Z, Wu D (2003) Adsorption of fluoride from water by aligned carbon nano tubes. Mater Res Bull 38:469–476
Loganathan P, Gray CW, Hedley MJ, Roberts HC (2006) Total and soluble fluorine concentrations in relation to properties of soils in New Zealand. Eur J Soil Sci 57:411–421
Mameri N, Yeddou AR, Lounici H, Grib H, Belhocine D, Bariou B (1998) Defluoridation of septentrional Sahara water of north Africa by electrocoagulation process using bipolar aluminium electrodes. Water Res 32(5):1604
Manikandan S, Chidambaram S, Prasanna MV, Thivya C, Karmegam U (2011) Hydrochemical characteristics and groundwater quality assessment in Krishnagiri District, Tamilnadu, India. Int J Earth Sci Eng 4(4):623–632
Manivannan R, Chidambaram S, Srinivasamoorthy K (2010) A statistical approach to study the spatial and temporal variation of Electrical conductivity of groundwater in Dindigul district, Tamilnadu-using GIS. In: Chidambaram S (ed) Recent trends in water research, remote sensing and general perspectives. IK International, New Delhi, pp 186–196
Manivannan R, Chidambaram S, Anandhan P, Karmegam U, Sinagaraja C, Johnsonbabu G, Prasanna MV (2011) Study on the significance of temporal ion chemistry in groundwater of Dindigul District, Tamilnadu, India. E J Chem 8(2):938–944
Meenakshi, Maheshwari RC (2006) Fluoride in drinking water and its removal. J Hazard Matter 137(1):456–463
Naseem S, Rafique T, Bashir E, Bhanger MI, Laghari A, Usmani TH (2010) Lithological influences on occurrence of high-fluoride groundwater in Nagar Parkar area, Thar Desert, Pakistan. Chemosphere 78:1313–1321
Nordstrom DK, Ball JW, Donahoe RJ, Whittemore D (1989) Groundwater chemistry and water–rock interactions at Stripa. Geochim Cosmochim Acta 53:1727–1740
Nordstron BK, Jenne EA (1977) Fluoride solubility equilibrium in select geothermal waters. Geochim Cosmochim Acta 41:175–188
Pertti L, Backman B (1995) The occurrence and geochemistry of fluorides with special reference to natural waters in Finland. Report of investigation. Geological Survey of Finland, pp 128
Prasanna MV, Chidambaram S, Srinivasamoorthy K, Anandhan P, John peter A, Senthil Kumar G (2008) Evaluation of mechanisms controlling hydrogeochemical nature of groundwater in Gadilam river basin, Tamilnadu, India. Icfai J Earth Sci 2(1):47–60
Raju NJ, Dey S, Das K (2009) Fluoride contamination in groundwaters of Sonbhadra District, Uttar Pradesh. India Curr Sci 96:699–702
Ramanathan S (1956) Ultrabasic rock of Salem and Dodkanya and their relationship with Charnocite, unpublished Ph.D Thesis University of Madras
Sarma DRR, Rao SLN (1997) Fluoride concentrations in ground waters of Visakhapatnam, India. Bull Environ Contam Toxicol 58(2):241
Saxena VK, Ahmad S (2002) Inferring the chemical parameter for the dissolution of the fluoride in groundwater. Environ Geol 25:475–481
Saxena VK, Ahmed S (2001) Dissolution of fluoride in groundwater: a water–rock interaction study. Environ Geol 40:1084–1087
Schultheiss WA, Godley GA (1995) Chronic fluorosis in cattle due to the ingestion of a commercial lick. J S Afr Vet Assoc 66(2):83–84
Sexena VK, Ahmed S (2003) Inferring the chemical parameters for the dissolution of fluoride in groundwater. Environ Geol 43:731–736
Shah MT, Danishwar S (2003) Potential fluoride contamination in the drinking water of Naranji area, northwest frontier province, Pakistan. Environ Geochem Health 25:475–481
Shomar B, Müller G, Yahya A, Askar S, Sansur R (2004) Fluorides in groundwater, soil and infused-black tea and the occurrence of dental fluorosis among school children of the Gaza Strip. J Wat Health 2:23–35
Siddiqui AH (1955) Fluorosis in Nalgonda district, Hydrabad—Deccan. Br Med J 2:1408–1413
Soto-Rojas AE, Ureña-Cirett JL, Martínez-Mier EA (2004) A review of the prevalence of dental fluorosis in Mexico. Pan Am J Public Health 15:9–18
Srinivasamoorthy K, Vasanthavigar M, Vijayaraghavan K, Chidambaram S, Anandhan P, Vasudevan S, Manivannan R, Rajivgandhi R, Pethaperumal S (2008) Application of statistical analysis for source determination of major ions around Veeran Lake, Tamilnadu, India. Annamalai University Science Journal 45:13–18
Sujatha D (2003) Fluoride levels in the groundwater of the south-eastern part of Ranga Reddy district, Andhra Pradesh. India Environ Geol 44:587–591
Susheela AK (1993) A treatise on Fluorosis, 2nd ed, Fluorosis Research and Rural Development Foundation, New Delhi, India
Suttie JW (1969) Fluoride content of commercial dairy concentrates and alfalfa forage. J Agric Food Chem 17:1350–1352
Teotia SPS, Teotia M (1991) Endemic fluoride: bones and teeth—update. Ind J Environ Toxicol 1(1):1–16
Truesdell AH, Jones BF (1974) WATEQ, a computer program for calculating chemical equilibria of natural waters. J Res US Geol Surv 2:1233–1248
Valenzuela-Vasquez L, Ramírez-Hernández J, Reyes-Lopez J, Sol-Uribe A, Lázaro-Mancilla O (2006) The origin of fluoride in groundwater supply to Hermosillo City, Sonora, Mexico. Environ Geol 51:17–27
White DE, Hem JD, Warming GA (1963) Chemical composition of subsurface water. USGS professional papers 440-F. U.S. Geological Survey WHO
WHO (1984) Guidelines for drinking water quality, vol 3. Drinking Water Quality Control in Small Community Supplies, Geneva
Yadav AK, Khan P (2010) Fluoride and fluorosis status in groundwater of Todaraisingh Area of District Tonk Rajasthan, India. A Case Study. Int J Chem Environ Pharmaceut Res 1(1):6–11
Yun ST, Chae GT, Koh YK, Kim SR, Choi BY, Lee BH, Kim SY (1998a) Hydrogeochemical and environmental isotope study of groundwaters in the Pungki area. J Kor Soc Groundwater Environ 5:177–191
Yun ST, Koh YK, Choi HS, Youm SJ, So CS (1998b) Geochemistry of geothermal waters in Korea: environmental isotope and hydrochemical characteristics. II. Jungwon and Munkyeong areas. Econ Environ Geol 31:201–213
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Manikandan, S., Chidambaram, S., Ramanathan, A. et al. A study on the high fluoride concentration in the magnesium-rich waters of hard rock aquifer in Krishnagiri district, Tamilnadu, India. Arab J Geosci 7, 273–285 (2014). https://doi.org/10.1007/s12517-012-0752-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12517-012-0752-x