Skip to main content
Springer Nature Link
Log in

Polyethylenimine Grafted Chitosan Nanofiber Membrane as Adsorbent for Selective Elimination of Anionic Dyes

  • Regular Articles
  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

In order to improve the adsorption capacity of chitosan to organic dyes, the amino rich functionalized chitosan electrospun nanofibers membrane was prepared. In the process of high efficiency synthesis, PGMA and PEI were grafted on the surface of CS NFMs in turn. By means of XRD, ATR-FTIR and XPS, the successful introduction of amino group into CS was confirmed. The selective adsorption capacity of CS-PGMA-PEI NFMs for anionic dyes was studied. The adsorption kinetics analysis shows that the adsorption process of CS-PGMA-PEI NFMs is mainly pseudo second-order model. Its adsorption isotherms can be described by the Langmuir model and it conforms to monolayer adsorption. The maximum adsorption capacity of Congo red calculated by Langmuir model is 657.47 mg/g. CS-PGMA-PEI NFMs has selective adsorption capacity for Congo red/methylene blue mixture. CS-PGMA-PEI NFMs also showed good circulation stability. This study provides a method for the synthesis of water purification membrane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Explore related subjects

Discover the latest articles and news from researchers in related subjects, suggested using machine learning.

References

  1. E. Guivarch, S. Trevin, C. Lahitte, and M. A. Oturan, Environ. Chem. Lett., 1, 38 (2003).

    Article  CAS  Google Scholar 

  2. X. Li, Z. Wang, J. Ning, M. Gao, W. Jiang, Z. Zhou, and G. Li, J. Environ. Manage., 217, 305 (2018).

    Article  CAS  Google Scholar 

  3. S. Hokkanen, A. Bhatnagar, E. Repo, S. Lou, and M. Sillanpää, Chem. Eng. J, 283, 445 (2016).

    Article  CAS  Google Scholar 

  4. L. L. Li, X. Q. Feng, R. P. Han, S. Q. Zang, and G. Yang, J. Hazard. Mater., 321, 622 (2017).

    Article  CAS  Google Scholar 

  5. T. Zhou, C. Li, H. Jin, Y. Lian, and W. Han, ACS Appl. Mater. Interfaces, 9, 6030 (2017).

    Article  CAS  Google Scholar 

  6. F. Fu and Q. Wang, J. Environ. Manage., 92, 407 (2011).

    Article  CAS  Google Scholar 

  7. F. Gode and E. Pehlivan, J. Hazard. Mater., 28, 1493 (2006).

    Google Scholar 

  8. C. A. Martínez-Huitle and E. Brillas, Appl. Catal., B, 87, 105 (2009).

    Article  CAS  Google Scholar 

  9. J. Ge, D. Zong, Q. Jin, J. Yu, and B. Ding, Adv. Funct. Mater, 28, 1705051 (2018).

    Article  CAS  Google Scholar 

  10. R. Zhao, X. Li, B. Sun, Y. Li, Y. Li, R. Yang, and C. Wang, J. Mater. Chem. A, 5, 1133 (2017).

    Article  CAS  Google Scholar 

  11. E. Haque, V. Lo, A. I. Minett, A. T. Harris, and T. L. Church, J. Mater. Chem. A, 2, 193 (2014).

    Article  CAS  Google Scholar 

  12. C. Li, T. Lou, X. Yan, Y. Z. Long, G. Cui, and X. Wang, Int. J. Biol. Macromol, 106, 768 (2018).

    Article  CAS  Google Scholar 

  13. A. Alsbaiee, B. J. Smith, L. Xiao, Y. Ling, D. E. Helbling, and W. R. Dichtel, Nature, 529, 190 (2016).

    Article  CAS  Google Scholar 

  14. H. Zhang, W. Liu, F. Tian, Z. Tang, and H. Lin, RSC Adv., 9, 36517 (2019)

    Article  CAS  Google Scholar 

  15. Y. Wu, X. Qiu, Sh. Cao, J. Chen, X. Shi, and H. Deng, J Colloid and Interface Sci., 539, 533 (2019).

    Article  CAS  Google Scholar 

  16. L. Hou, N. Wang, J. Wu, Z. Cui, L. Jiang, and Y. Zhao, Adv. Funct. Mater, 28, 1801114 (2018).

    Article  CAS  Google Scholar 

  17. P. Liu, C. Zhu, and A. P. Mathew, J. Hazardous Mater., 371, 484 (2019).

    Article  CAS  Google Scholar 

  18. Y. Huang, Y.-E. Miao, and T. Liu, J. Appl. Polym. Sci., 131, 40864 (2014).

    Google Scholar 

  19. S. Haider and S.-Y. Park, J. Membr. Sci., 328, 90 (2009).

    Article  CAS  Google Scholar 

  20. C. Ning, L. Chao, H. Chao, X. Luo, S. Liang, Y. Xue, and F. Yu, Appl. Surf. Sci., 369, 492 (2016).

    Article  CAS  Google Scholar 

  21. J. He, W. Wang, F. Sun, W. Shi, D. Qi, K. Wang, R. Shi, F. Cui, C. Wang, and X. Chen, ACS Nano, 9, 9292 (2015).

    Article  CAS  Google Scholar 

  22. J. Yan, Y. Huang, Y. E. Miao, W. W. Tjiu, and T. Liu, J. Hazard. Mater., 283, 730 (2015).

    Article  CAS  Google Scholar 

  23. R. Zhao, Y. Tian, S. Li, T. Ma, H. Lei, and G. Zhu, J. Mater. Chem. A, 7, 22559 (2019).

    Article  CAS  Google Scholar 

  24. G. Ma, Y. Liu, C. Peng, D. Fang, B. He, and J. Nie, Carbohydr. Polym., 86, 505 (2011).

    Article  CAS  Google Scholar 

  25. P. Zhao, Y. Liu, L. Xiao, H. Deng, Y. Du, and X. Shi, J. Mater. Chem. B, 3, 7577 (2015).

    Article  CAS  Google Scholar 

  26. Y. Chen, B. Pan, S. Zhang, H. Li, L. Lv, and W. Zhang, J. Hazard. Mater., 190, 1037 (2011).

    Article  CAS  Google Scholar 

  27. R. Zhao, Y. Wang, X. Li, B. Sun, and C. Wang, ACS Appl. Mater. Interfaces, 7, 26649 (2015).

    Article  CAS  Google Scholar 

  28. L. Lv, J. Zhang, S. Yuan, L. Huang, S. Tang, B. Liang, and S. O. Pehkonen, RSC Adv., 6, 78136 (2016).

    Article  CAS  Google Scholar 

  29. Z. Zhu, P. Wu, G. Liu, X. He, B. Qi, G. Zeng, W. Wang, Y. Sun, and F. Cui, Chem. Eng. J., 313, 957 (2017).

    Article  CAS  Google Scholar 

  30. D. Yang, L. Li, B. Chen, S. Shi, J. Nie, and G. Ma, Polymer, 163, 74 (2019).

    Article  CAS  Google Scholar 

  31. M. K. Purkait, A. Maiti, S. DasGupta, and S. De, J. Hazard. Mater., 145, 287 (2007).

    Article  CAS  Google Scholar 

  32. S. Deng, G. Zhang, S. Liang, and P. Wang, ACS Sustainable Chem. Eng., 5, 6054 (2017).

    Article  CAS  Google Scholar 

  33. D. Setyono and S. Valiyaveettil, J. Hazard. Mater., 302, 120 (2016).

    Article  CAS  Google Scholar 

  34. J. Fu, J. Zhu, Z. Wang, Y. Wang, S. Wang, R. Yan, and Q. Xu, J. Colloid Interface Sci., 461, 292 (2015).

    Article  CAS  Google Scholar 

  35. Y. Wang, Y. Xie, Y. Zhang, S. Tang, C. Guo, J. Wu, and R. Lau, Chem. Eng. Res. Des., 114, 258 (2016).

    Article  CAS  Google Scholar 

  36. I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918).

    Article  CAS  Google Scholar 

  37. Y. S. Ho, C. T. Huang, and H. W. Huang, Process Biochem., 81, 352 (2003).

    CAS  Google Scholar 

  38. H. Zheng, D. Liu, Y. Zheng, S. Liang, and Z. Liu, J. Hazard. Mater., 167, 141 (2009).

    Article  CAS  Google Scholar 

  39. X. J. Zheng, X. X. Li, J. Y. Li, L. W. Wang, L. J. Jin, J. Liu, Y. Pei, and K. Y. Tang, Int. J. Biol. Macromol., 107, 283 (2018).

    Article  CAS  Google Scholar 

  40. S. Chatterjee, M. W. Lee, and S. H. Woo, Bioresour. Technol., 101, 1800 (2010).

    Article  CAS  Google Scholar 

  41. S. Chatterjee, D. S. Lee, M. W. Lee, and S. H. Woo, Bioresour. Technol., 100, 2803 (2009).

    Article  CAS  Google Scholar 

  42. S. Chatterjee, S. Chatterjee, B. P. Chatterjee, and A. K. Guha, Colloids Surf., A, 299, 146 (2007).

    Article  CAS  Google Scholar 

  43. L. Wang and A. Wang, J. Hazard. Mater., 147, 979 (2007).

    Article  CAS  Google Scholar 

  44. H. Hou, R. Zhou, P. Wu, and L. Wu, Chem. Eng. J., 211–212, 336 (2012).

    Article  CAS  Google Scholar 

  45. A. Roy, B. Adhikari, and S. B. Majumder, Ind. Eng. Chem. Res., 52, 6502 (2013).

    Article  CAS  Google Scholar 

  46. V. Vimonses, S. Lei, B. Jin, C. W. K. Chow, and C. Saint, Chem. Eng. J., 148, 354 (2009).

    Article  CAS  Google Scholar 

Download references

Ackowledgment

This work was supported by the National Natural Science Foundation of China (Grant No. 51973009).

Author information

Authors and Affiliations

  1. Beijing Laboratory of Biomedical Materials, Key Laboratory of Biomedical Materials of Nature Macromolecules, Ministry of Education, Beijing University of Chemical Technology, Beijing, 100029, China

    Xinwen Gong, Dongxue Yang, Jun Nie & Guiping Ma

  2. School of Resources, Environment and Materials, Guangxi University, Guangxi, 530004, China

    Nannan Wang

  3. Department of Aviation Quartermaster and Fuel, Air Force Logistics College, Xuzhou, Jiangsu, 221000, China

    Shian Sun

Authors
  1. Xinwen Gong
    View author publications

    You can also search for this author inPubMed Google Scholar

  2. Dongxue Yang
    View author publications

    You can also search for this author inPubMed Google Scholar

  3. Nannan Wang
    View author publications

    You can also search for this author inPubMed Google Scholar

  4. Shian Sun
    View author publications

    You can also search for this author inPubMed Google Scholar

  5. Jun Nie
    View author publications

    You can also search for this author inPubMed Google Scholar

  6. Guiping Ma
    View author publications

    You can also search for this author inPubMed Google Scholar

Corresponding authors

Correspondence to Nannan Wang or Guiping Ma.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gong, X., Yang, D., Wang, N. et al. Polyethylenimine Grafted Chitosan Nanofiber Membrane as Adsorbent for Selective Elimination of Anionic Dyes. Fibers Polym 21, 2231–2238 (2020). https://doi.org/10.1007/s12221-020-1321-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-020-1321-7

Keywords