Skip to main content
SpringerLink
Log in

Fine structure and physical properties of poly(buthylene terephthalate) sheets prepared by roller drawing method

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

Poly(butylene terephthalate) sheets were prepared by roller-drawing method with various draw ratio. The drawing temperature is 100 °C and draw ratios were varied 2, 2.5, 3, 3.5 and 4. The effect of draw ratio on the crystal structure, the molecular orientation, dynamic viscoelastic properties, sonic modulus and tensile properties of the roller-drawn PBT sheets were investigated. In WAXD results, with increasing of the draw ratio, (010) and (100) planes of preferred orientation have the strongest intensity on the equator. In the meridional scans, it was confirmed that α and β crystal co-existed in the roller drawn PBT sheets with various draw ratio. Uniaxially roller-drawn PBT sheets clearly increased orientation along the stretched direction at high draw ratio. And the four-methylene groups of PBT orient along the surface of the sheet. The mechanical properties of PBT sheets were improved by orientation-induced crystallization during roller drawing process at 100 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. V. Korshak and S. V. Vinogradova, “Polyester”, Pergamon, Oxford, 1956.

    Google Scholar 

  2. R. Jakeways, I. M. Ward, M. A. Wilding, I. H. Hall, I. J. Desborough, and M. G. Pass, J. Polym. Sci., Polym. Phys., 13, 799 (1975).

    Article  CAS  Google Scholar 

  3. R. Jakeways, T. Smith, I. M. Ward, and M. A. Wilding, J. Polym. Sci., Polym. Lett. Ed., 14, 41 (1976).

    Article  CAS  Google Scholar 

  4. I. H. Hall and M. G Pass, Polymer, 17, 807 (1976).

    Article  CAS  Google Scholar 

  5. U. Alter and R. Bornart, Colloid. Polym. Sci., 254, 348 (1976).

    Article  CAS  Google Scholar 

  6. I. J. Desborough and I. H. Hall, Polymer, 18, 825 (1977).

    Article  CAS  Google Scholar 

  7. K. Tashiro, Y. Nakai, M. Kobayashi, and H. Tadokoro, Macromolecules, 13, 137 (1980).

    Article  CAS  Google Scholar 

  8. B. Bornschlegl and R. Bonart, Colloid. Polym. Sci., 258, 319 (1980).

    Article  CAS  Google Scholar 

  9. U. Alter and R. Bornart, Colloid. Polym. Sci., 259, 332 (1980).

    Google Scholar 

  10. W. Strohmeier and W. F. X. Frank, Colloid. Polym. Sci., 260, 937 (1982).

    Article  CAS  Google Scholar 

  11. I. S. Davison, A. J. Manuel, and I. M. Ward, Polymer, 24, 30 (1983).

    Article  Google Scholar 

  12. V. K. Datye and P. L. Taylor, Macromolecules, 18, 671 (1985).

    Article  CAS  Google Scholar 

  13. B. C. Perry, J. L. Koenig, and J. B. Lando, Macromolecules, 20, 422 (1987).

    Article  CAS  Google Scholar 

  14. M. A. Gomez, M. H. Cozine, and A. E. Tonelli, Macromolecules, 21, 388 (1988).

    Article  CAS  Google Scholar 

  15. R. Al-Jishi and P. L. Taylor, Macromolecules, 21, 2240 (1988).

    Article  CAS  Google Scholar 

  16. R. P. Grasso, B. C. Perry, J. L. Koenig, and J. B. Lando, Macromolecules, 22, 1267 (1989).

    Article  CAS  Google Scholar 

  17. J. Roebuck, R. Jakeways, and I. M. Ward, Polymer, 33, 227 (1992).

    Article  CAS  Google Scholar 

  18. J. Y. Kim, S. W. Kang, and S. H. Kim, Fiber. Polym., 7, 358 (2006).

    Article  CAS  Google Scholar 

  19. A. Kaito, K. Nakayama, and Zubaidi, J. Appl. Polym. Sci., 45, 1203 (1992).

    Article  CAS  Google Scholar 

  20. A. Kaito, K. Nakayama, and H. Kanetsuna, J. Appl. Poym. Sci., 28, 1207 (1983).

    Article  CAS  Google Scholar 

  21. A. Kaito, K. Nakayama, and H. Kanetsuna, J. Appl. Poym. Sci., 30, 1241 (1985).

    Article  CAS  Google Scholar 

  22. A. Kaito, K. Nakayama, and H. Kanetsuna, J. Appl. Poym. Sci., 30, 4591 (1985).

    Article  CAS  Google Scholar 

  23. K. Nakayama, K. Miyashita, A. Kaito, and H. Kanetsuna, Kobunshi Ronbunshu, 43, 25 (1985).

    Google Scholar 

  24. A. Kaito, K. Nakayama, and H. Kanetsuna, J. Macromol. Sci. Phys., B26, 281 (1987).

    CAS  Google Scholar 

  25. S. H. Lee and H. H. Cho, J. Korean Fiber. Soc., 38, 326 (2001).

    CAS  Google Scholar 

  26. S. H. Lee and H. H. Cho, J. Korean Fiber. Soc., 39, 30 (2002).

    CAS  Google Scholar 

  27. S. H. Lee, K. H. Kim, T. Kikutani, and H. H. Cho, e-Polymers, 25, 1 (2003).

    Google Scholar 

  28. S. H. Lee, K. Nakayama, and H. H. Cho, Tex. Sci. Eng., 44, 293 (2007).

    CAS  Google Scholar 

  29. S. H. Lee, K. Nakayama, and H. H. Cho, e-Polymers, in press (2008).

  30. www.oki-koisoku.co.jp

Download references

Author information

Authors and Affiliations

  1. Macromolecular Technology Research Center, National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki, Japan

    Kazuo Nakayama

  2. Deparment of Organic Material Science and Engineering, Pusan National University, Busan, 609-735, Korea

    Sun Hee Lee, Kazuo Nakayama & Hyun Hok Cho

Authors
  1. Sun Hee Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kazuo Nakayama
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hyun Hok Cho
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hyun Hok Cho.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lee, S.H., Nakayama, K. & Cho, H.H. Fine structure and physical properties of poly(buthylene terephthalate) sheets prepared by roller drawing method. Fibers Polym 9, 740–746 (2008). https://doi.org/10.1007/s12221-008-0116-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-008-0116-z

Keywords

Search

Navigation