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Natural Material Shungite as Solid-Phase Extraction Sorbent for the Extraction of Red Synthetic Dye Ponceau 4R from Tap Water, Wine, and Juice

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Abstract

A natural nanomaterial shungite (NMSh) was used as solid-phase extraction (SPE) absorbent and showed excellent absorption capacity for red synthetic dye. NMSh is a mixture of various carbon allotropes, which is used as an inexpensive and effective sorbent in various scientific and food research around the world. NMSh is not just amorphous carbon, but the mixture of various carbon allotropes; shungite has been categorized as a promising material for the development of nanotechnology, which is of great interest for the development of science and technology. This fact served as the basis for selecting shungite as a material to create sorbents that will be used in the preparation of samples for analysis. For the determination of the red synthetic dye Ponceau 4R in samples of wine and juice, an SPE method with NMSh packed cartridge combined with HPLC–UV detection was developed to determine Ponceau 4R in tap water, wine, and juice samples. Particle size and mass of NMSh sorbent were studied, and a comparison between activated and non-activated NMSh was made for use as a sorbent. Under optimized conditions, the extraction of analyte was 99.3% for wine and 94.3% for juice with relative standard deviations (RSD) during the day equal to 0.18% for juice and 0.15% for wine. The results showed that this method is very sensitive and effective for the determination of food dyes in very complex matrices and in a low concentration. Based on the study was developed the method to determine the dyes in alcoholic and non-alcoholic drinks.

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References

  • Aguilar-Arteaga K, Rodríguez JA, Barrado E (2010) Magnetic solids in analytical chemistry: a review. Anal Chim Acta 674:157–165

    Article  CAS  Google Scholar 

  • Alimzhanova M, Adilbekov E, Kapar A, Sagandykova G, Ashimuly K (2016) A stationary phase for solid-phase extraction based on natural nanomaterial shungite. International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM 2:17–24

    Google Scholar 

  • Anderton SM, Incarvito CD, Sherma J (2006) Determination of natural and synthetic colors in alcoholic and non alcoholic beverages by quantitative HPTLC. J Liq Chromatogr Relat Technol 20:101–110

    Article  Google Scholar 

  • Augusto F, Hantao LW, Mogollón NGS, Braga SCGN (2013) New materials and trends in sorbents for solid-phase extraction. TrAC 43:14–23

    CAS  Google Scholar 

  • Automation of AOAC 988.13 for the identification of FD&C color additives in foods using solid phase extraction , Gilson, Inc. World Headquarters, 2012.

  • Baggiani C, Anfossi L, Giovannoli C (2007) Solid phase extraction of food contaminants using molecular imprinted polymers. Anal Chim Acta 591:29–39

    Article  CAS  Google Scholar 

  • Bastami K. D., Neyestani M. R., Shemirani F., Soltani F., Haghparast S., & Akbari A. (2015) Heavy metal pollution assessment in relation to sediment properties in the coastal sediments of the southern Caspian Sea. Marine Pollution Bulletin, Iran, vol. 92/issues 1: 237–243

  • Berthod L, Roberts G, Mills GA (2014) A solid-phase extraction approach for the identification of pharmaceutical–sludge adsorption mechanisms. Journal of Pharmaceutical Analysis, United Kingdom 4(2):117–124

    Article  Google Scholar 

  • Bielicka-Daszkiewicz K, Hadzicka M, Voelkel A, Bielicka-Daszkiewicz K, Hadzicka M, Voelkel A (2012) Optimization of SPE/GC/HPLC analytical procedure for determination of phenol, quinones, and carboxylic acids in water samples. ISRN Chromatography, Poland: 1–7

  • Bonan S, Fedrizzi G, Menotta S, Elisabetta C (2013) Simultaneous determination of synthetic dyes in foodstuffs and beverages by high-performance liquid chromatography coupled with diode-array detector. Dyes and Pigments 99:36–40

    Article  CAS  Google Scholar 

  • Borisovna SN. (2012) NSAS-H2O systems - electrolytes in micellar extraction and photometric determination of synthetic food colors, Diss. Doc. Chem. Sciences: Saratov

  • Capriotti AL, Cavaliere C, Giansanti P, Gubbiotti R, Samperi R, Laganà A (2010) Recent developments in matrix solid-phase dispersion extraction. J Chromatogr A 1217:2521–2532

    Article  CAS  Google Scholar 

  • Chiang T-L, Wang Y-C, Ding W-H (2011) Trace determination of rhodamine B and rhodamine 6G dyes in aqueous samples by solid-phase extraction and high-performance liquid chromatography coupled with fluorescence detection, detection of rhodamine dyes by HPLC-FLD

  • Simón de Dios, Díaz-García ME (2010) Multifunctional nanoparticles: analytical prospects, Anal. Chim. Acta 666: 1-22

  • Efremov SA, Nechipurenko SV, Kazankapova MK, Washington S, Tassibekov KhS, Nauryzbaev MK (2013) Physico-chemical characteristics of NMSh rock of Kazakhstan. Eurasian Chemico-Technological Journal, Kazakhstan 15:241–249

    Article  CAS  Google Scholar 

  • Giakisikli G, Anthemidis AN (2013) Magnetic materials as sorbents for metal/metalloid preconcentration and/or separation. A review. Anal Chim Acta 789:1–16

    Article  CAS  Google Scholar 

  • González-Curbelo MÁ, Herrera-Herrera AV, Hernández-Borges J, Rodríguez-Delgado MA (2013) Analysis of pesticides residues in environmental water samples using multiwalled carbon nanotubes dispersive solid-phase extraction. J Sep Sci 36:556–563

    Article  Google Scholar 

  • Hurst WJ, Mckim JM, Martin RA Jr (2014) Determination of tartrazine in food products by HPLC. Journal of Food Science. 46:419

    Article  Google Scholar 

  • Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58

    Article  CAS  Google Scholar 

  • Karatayev M, Clarke ML (2016) A review of current energy systems and green energy potential in Kazakhstan. Renewable and Sustainable Energy Reviews, United Kingdom 55:491–504

    Article  Google Scholar 

  • Li R, Jiang Z-T, Wang R-X (2009) Solid phase extraction combined direct spectrophotometric determination of brilliant blue in food using β-cyclodextrin polymer, Food Anal. Methods 2:264–270

    Google Scholar 

  • Methodology M 04–48 (2012). Determination of synthetic food colors in beverages , Capillary electrophoresis system.

  • Pardasani D, Kanaujia PK, Purohit AK, Shrivastava AR, Dubey DK (2011) Magnetic multi-walled carbon nanotubes assisted dispersive solid phase extraction of nerve agents and their markers from muddy water. Talanta 86:248–255

    Article  CAS  Google Scholar 

  • Pindado Jimenez O, Perez Pastor RM, Escolano Segovia O, Del Reino Querencia S (2015) Exploring petroleum hydrocarbons in groundwater by double solid phase extraction coupled to gas chromatography-flame ionization detector. Talanta, Spain 131:315–324

    Article  Google Scholar 

  • Qin X, Zhu X (2016) Determination of allura red in food by ionic liquid ß-cyclodextrin-cross-linked polymer solid phase extraction and high-performance liquid chromatography. Anal Lett 49:189–199

    Article  CAS  Google Scholar 

  • Shah SN, Uzcan F, Soylak M (2021) Ultrasound-assisted deep eutectic solvent microextraction procedure for traces Ponceau 4R in water and cosmetic samples International Journal of Environmental Science and Technology, https://doi.org/10.1007/s13762-021-03154-z

  • Souza-Silva EA, Risticevic S, Pawliszyn J (2013) Recent trends in SPME concerning sorbent materials, configurations and in vivo applications. TrAC 43:24–36

    CAS  Google Scholar 

  • Soylak M, Cihan Z (2013) Solid-phase extraction of tartrazine on multiwalled carbon nanotubes for separation and enrichment. Toxicol Environ Chem 95:559–566

    Article  CAS  Google Scholar 

  • Soylak M, Elci L (1997) Preconcentration and Separation of Trace Metal Ions From Sea Water Samples by Sorption on Amberlite XAD-16 After Complexation with Sodium Diethyl Dithiocarbamate. Int J Environ Anal Chem 66:51–59

    Article  CAS  Google Scholar 

  • Soylak M, Unsal YE, Yilmaz E, Tuzen M (2006) Determination of rhodamine B in soft drink, waste water and lipstick samples after solid phase extraction. Food Chem Toxicol 49:1796–1799

    Article  Google Scholar 

  • Unsal YE, Soylak M, Tuzen M (2012) Column solid-phase extraction of sunset yellow and spectrophotometric determination of its use in powdered beverage and confectionery products. Int J Food Sci Technol 47:1253–1258

    Article  CAS  Google Scholar 

  • Wierucka M, Biziuk M (2014) Application of magnetic nanoparticles for magnetic solid-phase extraction in preparing biological, environmental and food samples. TrAC 59:50–58

    CAS  Google Scholar 

  • Yi LX, Fang R, Chen GH (2013) molecularly imprinted solid-phase extraction in the analysis of agrochemicals. J Chromatogr Sci 51:608–618

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was conducted under the project AP08857501 «Improvement and development of highly sensitive methods for ensuring food safety in Kazakhstan» funded by the Ministry of Education and Science of Kazakhstan from 2020 to 2022. The research was supported by the Postdoctoral Fellowship of Mereke Alimzhanova provided by al-Farabi Kazakh National University. The authors wish to thank the “National nanotechnology laboratory of open type” KazNU and “Instrumental analysis” laboratory of Nicolaus Copernicus University for SEM analysis of NMSh. The authors are also thankful to Tokpayev R. and Kabulov A., Khavaza T. for providing NMSh breeds for research work.

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Authors and Affiliations

  1. Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, 96A street Tole bi, 050012, Almaty, Kazakhstan

    Alipuly Alham

  2. Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 al-Farabi Ave, 050040, Almaty, Kazakhstan

    Aibat Ibraimov

  3. Faculty of Physics and Technology, Al-Farabi Kazakh National University, 71 al-Farabi Ave, 050040, Almaty, Kazakhstan

    Mereke Alimzhanova & Madina Mamedova

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  1. Alipuly Alham
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  2. Aibat Ibraimov
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  3. Mereke Alimzhanova
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  4. Madina Mamedova
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Correspondence to Mereke Alimzhanova or Madina Mamedova.

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A. Alipuly declares that he has no conflict of interest. A.B. Ibraimov declares that he has no conflict of interest. M.B. Alimzhanova declares that she has no conflict of interest. M.R. Mamedova declares that she has no conflict of interest.

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Alham, A., Ibraimov, A., Alimzhanova, M. et al. Natural Material Shungite as Solid-Phase Extraction Sorbent for the Extraction of Red Synthetic Dye Ponceau 4R from Tap Water, Wine, and Juice. Food Anal. Methods 15, 707–716 (2022). https://doi.org/10.1007/s12161-021-02162-6

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  • DOI: https://doi.org/10.1007/s12161-021-02162-6

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