Abstract
In this study, pure and NH2-functionalized graphene oxide (GO) nanosheets have been added to the cement mortar with different weight percents (0.05, 0.10, 0.15, 0.20 and 0.25 wt%). In addition, the effects of functionalizing GO on the microstructure and mechanical properties (flexural/compressive strengths) of cement composite have been investigated for the first time. Scanning electron microscopy (SEM) images showed that GO filled the pores and well dispersed in concrete matrix, whereas exceeding GO additive from 0.10 wt% caused the formation of agglomerates and microcracks. In addition, mercury intrusion porosimetry confirmed the significant effects of GO and functionalizing groups on filling the pores. NH2-functionalizing helped to improve the cohesion between GO nanosheets and cement composite. Compressive strengths increased from 39 MPa for the sample without GO to 54.23 MPa for the cement composites containing 0.10 wt% of NH2-functionalized GO. Moreover, the flexural strength increased to 23.4 and 38.4% by compositing the cement paste with 0.10 wt% of pure and NH2-functionalized GO, compared to the sample without GO, respectively. It was shown that functionalizing considerably enhanced the mechanical properties of GO/cement composite due to the interfacial strength between calcium silicate hydrates (C-S-H) gel and functionalized GO nanosheets as observed in SEM images. The morphological results were in good agreement with the trend obtained in mechanical properties of GO/cement composites.
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References
Kim K Y, Yun T S and Park K P 2013 Cem. Concr. Res. 50 34
Van T K, De Belie N and Lehmann F 2012 Constr. Build Mater. 28 333
Komloš K, Babál B, Vaniš M and Kozánková J 1994 Bull. Mater. Sci. 17 181
Majid A, Liu A, Sou H and Chouw N 2012 Constr. Build Mater. 30 814
Soroushian P, Tlili A, Alhozaimy A and Khan A 1993 Constr. Build Mater. 7 221
Gopalakrishnan K, Birgisson B, Taylor P and Attoh-Okine N O 2011 Nanotechnology in civil infrastructure (Springer-Verlag, Berlin, Heidelberg) p 207
Ab Rahman I, Malik Masudi S, Luddin N and Ahmad Sheikh R 2014 Bull. Mater. Sci. 37 213
Najigivi A, Abdul Rashid S, Aziz F N A and Mohd Salleh M A 2012 Mater. Struct. 45 1007
Supit S W M and Ahmed Shaikh F U 2014 Mater. Struct. DOI:10.1617/s11527-014-0329-0
Nazari A 2011 Mater. Struct. 44 773
Camiletti J, Soliman A M and Nehdi M L 2013 Mater. Struct. 46 881
Li Z, Wang H H S and Lu Y W M 2006 Mater. Lett. 60 356
Chang T P, Shih J Y, Yang K M and Hsiao T C 2007 J. Mater. Sci. 42 7478
Peyvandi A and Soroushian P 2015 Mater. Struct. 48 461
Siddique R and Mehta A 2014 Constr. Build Mater. 50 116
Lv S, Ma Y, Qiu C, Sun T, Liu J and Zhou Q 2013 Constr. Build Mater. 49 121
Pan Z, Duan W, Li D and Collins F 2012 WO Patent App. PCT/AU2012/001, 582
Gong K, Pan Z, Korayem A H, Qiu L, Li D, Collins F et al 2014 J. Mater. Civil Eng. 27 A4014010
Paiva M C, Zhou B, Fernando K A S, Lin Y, Kennedy J M and Sun Y-P 2004, Carbon 42 2849
Li G Y, Wang P M and Zhao X 2005 Carbon 43 1239
Markar J M and Beaudoin J J 2004 Sp. Pub. Roy. Soc. Chem. 292 331
Jiao Q, Zhang S, Wang J, Li H, Wu Q and Zhao Y 2015 Fuller Nanotub. Car. N 23 680
Alkhateb H, Al-Ostaz A, Cheng A H D and Li X 2013 J. Nanomech. Micromech. 3 67
Yan J, Wang Q, Wei T, Jiang L, Zhang M, Jing X and Fan Z 2014 ACS Nano 8 4720
Tao Y, Xie X, Lv W, Tang D M, Kong D, Huang Z et al 2013 Sci. Rep. 3 2975
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ABRISHAMI, M.E., ZAHABI, V. Reinforcing graphene oxide/cement composite with NH2 functionalizing group. Bull Mater Sci 39, 1073–1078 (2016). https://doi.org/10.1007/s12034-016-1250-7
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DOI: https://doi.org/10.1007/s12034-016-1250-7