Abstract
With rising ore prices and the continued demand for higher quality steels, much work has been carried out into refining and control prospects of steel chemistry. As several technologies around the world are exploring the control of phosphorus with high priority, an overview of current knowledge, ongoing research, and specific interest areas is presented. The reliance of the basic oxygen furnace steelmaking on iron ore quality is considered with regard to impurity levels, as well as the phosphorus content of direct reduced iron introduction to the electric arc furnace process. This article reviews methods to control phosphorus in steelmaking and proposes a practical approach based on laboratory-scale equilibrium experiments. The article ends by exploring energy savings in steelmaking as well as speculating on further avenues of steel production profitability.
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References
World Steel Association, World Crude Steel Production (Brussels, Belgium: World Steel Association, 2013), https://www.worldsteel.org/dms/internetDocumentList/press-release-downloads/2013/April-2013-Production.
World Steel Association, Steel Statistical Yearbook 2013 Production (Brussels: World Steel Association, 2013).
Natural Gas Monthly Price, http://www.indexmundi.com/commodities/?commodity=natural-gas.
Iron Ore Monthly Price, http://www.indexmundi.com/commodities/?commodity=iron-ore.
R. Husken, R. Fechner, and J. Cappel, Iron Steel Technol. 8, 46 (2011).
I. Olefjord, Int. Met. Rev. 23, 149 (1978).
J.R. Low, D.F. Stein, A.M. Turkalo, and R.P. Laforce, Trans. AIME 242, 14 (1968).
C.L. Briant and S.K. Banerji, In Treatise on Materials Science and Technology: Embrittlement of Engineering Alloys, 1st ed. (New York, NY: Academic Press, 1983), pp. 21–58.
G. Dieter and D. Bacon, Mechanical Metallurgy, 3rd ed. (New York, NY: McGraw-Hill, 1986).
W.M. Guo, Z.C. Wang, Y. de Li, N. Xu, and J. Bo Shi, Metallogr. Microstruct. Anal. 2, 249 (2013).
T.A. Boom, D.R. Fosnacht, and D.M. Haezebrouck, Ironmaker Steelmaker 17, 59 (1990).
World Steel Association, Electric Arc Furnace Simulation User Guide (Brussels: World Steel Association, 2006).
T.A. Boom, D.R. Fosnacht, and D.M. Haezebrouck, Ironmaker Steelmaker 17, 35 (1990).
N. Sano, W.-K. Lu, and P.V. Riboud, Advanced Physical Chemistry for Process Metallurgy, 1st ed. (New York: Academic Press, 1997), pp. 45–56.
M.A. Tayeb, R. Fruehan, and S. Sridhar (Paper presented at the AISTech Conference, Indianapolis, IN, 2014).
M.A. Tayeb, R. Fruehan, and S. Sridhar, Liquid Metal Processing and Casting, ed. M.J.M. Krane, A. Jardy, R.L. Williamson, and J.J. Beaman (Warrendale, PA: TMS; Hoboken, NJ: Wiley & Sons, 2013), pp. 353–358.
C.P. Manning and R.J. Fruehan, Metall. Mater. Trans. B 44, 37 (2013).
P. Wei, M. Sano, M. Hirasawa, and K. Mori, ISIJ Int. 31, 358 (1991).
P. Wei, M. Sano, M. Hirasawa, and K. Mori, ISIJ Int. 33, 479 (1993).
J. Ekengård, A.M.T. Andersson, and P.G. Jönsson, Ironmaking Steelmaking 35, 575 (2008).
J. Ekengård (Ph.D. dissertation, Stockholm, Sweden, 2004).
Y. Chung and A.W. Cramb, Philos. Trans. R. Soc. A 356, 981 (1998).
A. Jakobsson, M. Nasu, J. Mangwiru, K.C. Mills, and S. Seetharaman, Philos. Trans. R. Soc. A 365, 995 (1998).
G.N. Shannon, R.J. Fruehan, and S. Sridhar, Metall. Mater. Trans. B 40, 727 (2009).
P.V. Riboud and L.D. Lucas, Can. Metall. Q. 20, 199 (1981).
M. Han and Y. Zhao, Expert Syst. Appl. 38, 14786 (2011).
K.S. Coley and G. Brown (Paper presented at the International Conference on the Technology of Ironmaking and Steelmaking, Jamshedphur, India, 2013).
G. Brooks, Y. Pan, and K. Coley, Metall. Mater. Trans. B 36, 525 (2005).
R.J. Fruehan, O. Fortini, H.W. Paxton, and R. Brindle, Report to the U.S. Department of Energy, Office of Industrial Technologies (Washington, DC: Department of Energy, 2000).
M.A. Tayeb, Introduction to EAF Steelmaking (Jubail: SABIC, 2009).
R.J. Fruehan, The Making, Shaping and Treating of Steel, 11th ed. (Pittsburgh: The AISE Steel Foundation, 1998).
D. Zuliani, S. Khouri, and V. Scipolo, Iron Steel Technol. 10, 160 (2013).
H. Tanabe and M. Nakada, NKK Tech. Rev. 88, 18 (2003).
N. Sasaki, Y. Ogawa, K.-I. Miyamoto, and S. Mukawa, Nippon Steel Tech. Report 104, 26 (2013).
W.T. Jeans, ISIJ Int. 318 (1884).
M.A. Tayeb, R. Fruehan, and S. Sridhar (Paper presented at the 5th International Congress on the Science and Technology of Steelmaking, Dresden, Germany, 2012).
T.P. Battle and J.M. McClelland, AlSTech 2011 Conference Proc. (Warrendale, PA: AIST, 2011), pp. 943–954.
Association for Iron & Steel Technology, 2012 EAF Roundup (Warrendale, PA: AIST, 2012).
R. Lule, F. Lopez, J. Espinoza, R. Torres, and R.D. Morales, The Production of Steels: Applying 100% DRI for Nitrogen Removal (Charlotte, NC: Midrex, 2009).
E. Pretorius, H. Oltmann, and J. Jones, EAF Fundamentals (York, PA: LWB Refractories).
Update Client Magazine, ArcelorMittal (2012).
U.S. Environmental Protection Agency, Available and Emerging Technologies for Reducing Greenhouse Gas Emissions from the Iron and Steel Industry (Washington, DC: U.S. Environmental Protection Agency, 2012).
Z.-H. Tian, B.-H. Li, X.-M. Zhang, and Z.-H. Jiang, J. Iron. Steel Res. Int. 16, 6 (2009).
H. Yi, G. Xu, H. Cheng, J. Wang, Y. Wan, and H. Chen, Proc. Environ. Sci. 16, 791 (2012).
L.J. Westholm, Water 2, 826 (2010).
J. Geiseler, Waste Manag. 16, 59 (1996).
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Tayeb, M.A., Spooner, S. & Sridhar, S. Phosphorus: The Noose of Sustainability and Renewability in Steelmaking. JOM 66, 1565–1571 (2014). https://doi.org/10.1007/s11837-014-1093-x
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DOI: https://doi.org/10.1007/s11837-014-1093-x