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Cutting fluid corrosion inhibitors from inorganic to organic: Progress and applications

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Abstract

Water-based cutting fluid has a broad application area and a hundred year history, but its poor corrosion inhibition and anti-rust ability limit its further promotion. Adding corrosion inhibitors can effectively solve the above problems. However, no review papers are available on cutting fluid corrosion inhibitors, and their mechanism, suitability, and performance influencing factors have not been revealed. This article discusses cutting fluid corrosion inhibitors to fill the gaps in theoretical research and industrial applications. Inorganic matters are initially used in corrosion inhibition due to their strong oxidizing properties. Therefore, the film formation mechanism of inorganic corrosion inhibitor oxide and precipitation film is first analyzed, and the applications in corrosive medium are summarized. Given that inorganic corrosion inhibitors are not environmentally friendly and expensive, organic corrosion inhibitors are currently used as replacement. Thus, the film formation mechanism of different organic corrosion inhibitors adsorption film is analyzed, and their suitability with metals is determined. The influence of molecular structure and temperature on their corrosion inhibition effect is also studied, and the performance of inorganic and organic corrosion inhibitors is compared. However, single organic corrosion inhibitors are greatly affected by metal surface state, temperature, and immersion time. Therefore, the synergistic film formation after the compounding of organic and inorganic corrosion inhibitors is analyzed. In addition, the influence rate of concentration, molecular structure, and temperature on corrosion inhibition performance is revealed, and a matching database of corrosion inhibitor type and metal type in cutting is established. Finally, in view of the limitations of cutting fluid corrosion inhibitors, the establishment of a molecular dynamics model of corrosion inhibitor failure and accelerates corrosion and the development of general-purpose green additives based on the molecular design and physical and chemical analysis of the suitability of corrosion inhibitor and base liquid are prospected.

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Funding

This study was financially supported by: the National Key Research and Development Program of China (Grant No. 2020 YFB2010500), the National Natural Science Foundation of China (Grant Nos. 51975305 and 51905289), the Major Science and Technology Innovation Engineering Projects of Shandong Province (Grant No. 2019JZZY020111), the Natural Science Foundation of Shandong Province (Grant Nos. ZR2020KE027, ZR2020ME158 and ZR2019PEE008) and the Applied Basic Research Youth Project of Qingdao science and technology plan (Grant No. 19-6-2-63-cg).

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Authors and Affiliations

  1. School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao, 266520, China

    Haogang Li, Yanbin Zhang & Changhe Li

  2. Hanergy (Qingdao) Lubrication Technology Co., Ltd., Qingdao, 266200, China

    Zongming Zhou

  3. Nanjing Kerun Lubricants Co., Ltd., Nanjing, 211106, China

    Xiaolin Nie

  4. Chengdu Tool Research Institute Co., Ltd., Chengdu, 610500, China

    Yun Chen

  5. School of Mechanical Engineering, Chongqing University, Chongqing, 400044, China

    Huajun Cao

  6. Sichuan Future Aerospace Industry LLC., Shifang, 618400, China

    Bo Liu

  7. Shanghai Jinzhao Energy Saving Technology Co., Ltd., Shanghai, 200436, China

    Naiqing Zhang

  8. Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah, 27272, United Arab Emirates

    Zafar Said

  9. Mechanical Engineering Department, Curtin University, Miri, 98009, Malaysia

    Sujan Debnath

  10. College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China

    Muhammad Jamil

  11. Mechanical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Hafiz Muhammad Ali

  12. Department of Mechanical Engineering, IK Gujral Punjab Technical University, 144603, Punjab, India

    Shubham Sharma

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  1. Haogang Li
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  2. Yanbin Zhang
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  3. Changhe Li
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  4. Zongming Zhou
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  5. Xiaolin Nie
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  6. Yun Chen
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  7. Huajun Cao
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  8. Bo Liu
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  9. Naiqing Zhang
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  10. Zafar Said
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  11. Sujan Debnath
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  12. Muhammad Jamil
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  13. Hafiz Muhammad Ali
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  14. Shubham Sharma
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by [Zongming Zhou], [Xiaolin Nie], [Yun Chen], [Huajun Cao], [Bo Liu], [Naiqing Zhang], [Zafar Said], [Sujan Debnath], [Muhammad Jamil], [Hafiz Muhammad Ali], and [Shubham Sharma]. The first draft of the manuscript was written by [Haogang Li], [Yanbin Zhang] and [Changhe Li] and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Changhe Li.

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Li, H., Zhang, Y., Li, C. et al. Cutting fluid corrosion inhibitors from inorganic to organic: Progress and applications. Korean J. Chem. Eng. 39, 1107–1134 (2022). https://doi.org/10.1007/s11814-021-1057-0

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  • DOI: https://doi.org/10.1007/s11814-021-1057-0

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