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Ion imprinted activated carbon solid-phase extraction coupled to flame atomic absorption spectrometry for selective determination of lead ions in environmental samples

  • Environmental Engineering
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Abstract

A simple lead ion imprinted sorbent was synthesized by coupling activated carbon with a known metal chelating compound, iminodiacetic acid. The ion imprinted sorbent has been characterized using Fourier transform infrared spectroscopy, elemental analysis and thermogravimetric analysis and subjected for the extraction and determination of trace Pb(II) in environmental water samples. The optimum pH value for sorption of the lead ion was 6.5. The sorption capacity of lead imprinted sorbent was 42.2 mg g−1. The chelating imprinted sorbent can be reused for five cycles of sorption-desorption without any significant change in sorption capacity. Compared with non-imprinted polymer particles, the lead ion imprinted sorbent showed high adsorption capacity, significant selectivity, good site accessibility for Pb(II). The equilibrium adsorption data of Pb(II) by modified resin were analyzed by Langmuir, Freundlich, Temkin and Redlich-Peterson models.

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Authors and Affiliations

  1. Department of Environmental Engineering, Faculty of Environmental and Energy, Science Research Branch, Islamic Azad University, Tehran, Iran

    Kiyana Naraghi & Amir Hesam Hassani

  2. Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran

    Homayon Ahmad Panahi

  3. Department of Chemistry, Varamin (Pishva) Branch, Islamic Azad University, Varamin, Iran

    Elham Moniri

Authors
  1. Kiyana Naraghi
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  2. Homayon Ahmad Panahi
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  3. Amir Hesam Hassani
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  4. Elham Moniri
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Correspondence to Homayon Ahmad Panahi.

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Naraghi, K., Panahi, H.A., Hassani, A.H. et al. Ion imprinted activated carbon solid-phase extraction coupled to flame atomic absorption spectrometry for selective determination of lead ions in environmental samples. Korean J. Chem. Eng. 31, 1818–1823 (2014). https://doi.org/10.1007/s11814-014-0104-5

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  • DOI: https://doi.org/10.1007/s11814-014-0104-5

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