Abstract
This study investigates optimization of various competitive adsorption parameters for removal of Cd(II), Ni(II) and Pb(II) from aqueous solutions by commercial activated carbon (AC) using the Taguchi method. Adsorption parameters such as initial metal concentration of each metal ion (C0,i ), initial pH (pH0), adsorbent dosage (m) and contact time (t) in batch technique were studied to observe their effects on the total adsorption capacity of metals onto activated carbon (q tot ). The adsorbent dosage has been found to be the most significant parameter. Interactions between C0,Cd ×C0,Ni , C0,Cd ×C0,Pb and C0,Ni ×C0,Pb have been considered for simultaneous metal ions adsorption. The optimum condition for adsorption of metal ions were obtained with C0,i =100 mg L−1, pH0=7, m=2 g L−1 and t=80 min. Finally, experimental results showed that a multi-staged adsorptive treatment would be necessary to reach the minimal discharge standards of metal ions in the effluent.
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K. Kadirvelu, C. Faur-Brasquet and P. Le Cloirec, Langmuir, 16, 8404 (2000).
M. Madhava Rao, D. K. Ramana, K. Seshaiah, M. C. Wang and S.W. Chang Chien, J. Hazard. Mater., 166, 1006 (2009).
V. C. Srivastava, I. D. Mall and I.M. Mishra, J. Hazard. Mater., B134, 257 (2006).
P. Senthil Kumar and K. Kirthika, J. Eng. Sci. Technol., 4, 351 (2009).
K. Li and X. Wang, Bioresour. Technol., 100, 2810 (2009).
Tolerance limits for industrial effluents, http://www.worldenviro.com/effstd.htm.
R.C. Bansal and M. Goyal, Activated carbon adsorption, Taylor & Francis, USA (2006).
D. Mohan and K. P. Singh, Water Res., 36, 2304 (2002).
J. Hanzlik, J. Jehlicka, O. Sebekb, Z. Weishauptova and V. Machovk, Water Res., 38, 2178 (2004).
K. Swayampakula, V.M. Boddu, S. K. Nadavala and K. Abburi, J. Hazard. Mater., 170, 680 (2009).
L. Zhi-rong, Z. Li-min, W. Peng, Z. Kai, W. Chuan-xi and L. Huihua, J. China Univ. Mining. Technol., 18, 255 (2008).
T. Terdkiatburana, S. Wang and M. O. Tade, Chem. Eng. J., 139, 437 (2008).
B.C. Son, K. Park, S.H. Song and Y. J. Yoo, Korean J. Chem. Eng., 21, 1168 (2004).
M. H. Kasnejad, A. Esfandiari, T. Kaghazchi and N. Asasian, J. Taiwan Inst. Chem. E., 43, 736 (2012).
A. Esfandiari, T. Kaghazchi and M. Soleimani, J. Taiwan Inst. Chem. E, 43, 631 (2012).
H. Sharififard, M. Soleimani and F. Zokaee Ashtiani. J. Taiwan Inst. Chem. E, 43, 696 (2012).
M. Soleimani and T. Kaghazchi, J. Chin. Inst. Chem. Eng., 39, 9 (2008).
T. Kaghazchi and H. Shamsi Jazeyi, J. Ind. Eng. Chem., 17, 608 (2011).
M. Soleimani and T. Kaghazchi, Bioresour. Technol., 99, 5374 (2008).
T. Kaghazchi, N. Asasian Kolur and M. Soleimani, J. Ind. Eng. Chem., 16, 368 (2010).
N. Asasian, T. Kaghazchi and M. Soleimani, J. Ind. Eng. Chem., 18, 283 (2012).
V. C. Srivastava, I. D. Mall and I.M. Mishra, Ind. Eng. Chem. Res., 46, 5697 (2007).
G. Taguchi and R. Jugulum, The Mahalanobis-Taguchi Strategy, Wiley, New York (2002).
R. L. Mason, R. F. Gunst and J. L. Hess, Statistical design and analysis of experiments with applications to engineering and science, Wiley-Interscience, New Jersey (2003).
V. C. Srivastava, I. D. Mall and I. M. Mishra, J. Chem. Eng., 140, 136 (2008).
F. Boudrahema, F. Aissani-Benissad and H Ait-Amar, J. Environ. Manage., 90, 3031 (2009).
V. C. Srivastava, I. D. Mall and I.M. Mishra, Chem. Eng. Process., 47, 1269 (2008).
A. Uccer, A. Uyanik and S. F. Aygun, Sep. Purif. Technol., 47, 113 (2006).
V.C. Srivastava, I. D. Mall and I.M. Mishra, Colloids Surf. A: Physicochem. Eng. Aspects, 312, 172 (2008).
R. Roy, A primer on the taguchi method, Society Manufacturing Engineers, Deorborn Michigan (1990).
N. Gamze Turan, S. Elevli and B. Mesci, Appl. Clay. Sci., 52, 392 (2011).
M. J. K. Bashir, H. Abdul Aziz, M. S. Yusoff and M. N. Adlan, Desalination, 254, 154 (2010).
K. Yetilmezsoya, S. Demirel and R. J. Vanderbei, J. Hazard. Mater., 171, 551 (2009).
A. Özer, G. Gürbüza, A. Calimliand B. K. Körbahti, Chem. Eng. J., 146, 377 (2009).
S. Ricordel, S. Taha, I. Cisse and G. Dorange, Sep. Purif. Technol., 24, 389 (2001).
S. B. Chen, Y. B. Ma, L. Che and K. Xian, Geochem. J., 44, 233 (2010).
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Kavand, M., Kaghazchi, T. & Soleimani, M. Optimization of parameters for competitive adsorption of heavy metal ions (Pb+2, Ni+2, Cd+2) onto activated carbon. Korean J. Chem. Eng. 31, 692–700 (2014). https://doi.org/10.1007/s11814-013-0280-8
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DOI: https://doi.org/10.1007/s11814-013-0280-8