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Challenge of biodiesel production from sewage sludge catalyzed by KOH, KOH/activated carbon, and KOH/CaO

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Abstract

The considerable compounds content, abundance, and low costs involved has led to the proposal to use sewage sludge as raw material for biodiesel production. The transesterification reaction is catalyzed using an acid catalyst instead of base catalysts because of the high free fatty acid concentration. However, the use of a base catalyst, particularly a solid base catalyst, has certain advantages, including faster reaction speed and easier separation. In this study, we utilize in situ transesterification by base catalyst (KOH, KOH/activated carbon (AC) and KOH/CaO) with sewage sludge as raw material. Many conditions have been tested to increase biodiesel yield through single-factor tests, including mass fraction and catalyst dosage. Preliminary experiments have optimized reaction time and temperature. However, the three catalysts did not work better than H2SO4, which had a maximum yield of 4.6% (dry sewage sludge base) considering the purity by KOH, KOH/CaO, and KOH/AC. The features of the catalyst were analyzed using XRD, BETand SEM. As to BETof KOH/AC and the good spiculate formation of KOH crystal appears to be essential to its function. As for KOH/CaO, the formation of K2O and absorption points is likely essential.

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Acknowledgments

The present study is supported by the Major Science and Technology Program for Water Pollution Control and Treatment (No. 2013ZX07314-001-006-01); Fundamental Research Funds for the Central Universities (No. 51308538); and the Research Funds of Renmin University of China (No. 15XNLD04).

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Authors and Affiliations

  1. School of Environment and Natural Resources, Renmin University of China, Beijing, 100872, China

    Xuemin Wu, Fenfen Zhu, Juanjuan Qi, Fawei Yan & Chenghui Li

  2. Shougang Research Institute of Technology, Beijing, 100043, China

    Luyao Zhao

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  1. Xuemin Wu
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  2. Fenfen Zhu
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  3. Juanjuan Qi
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  4. Luyao Zhao
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  5. Fawei Yan
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Correspondence to Fenfen Zhu.

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Wu, X., Zhu, F., Qi, J. et al. Challenge of biodiesel production from sewage sludge catalyzed by KOH, KOH/activated carbon, and KOH/CaO. Front. Environ. Sci. Eng. 11, 3 (2017). https://doi.org/10.1007/s11783-017-0913-y

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  • DOI: https://doi.org/10.1007/s11783-017-0913-y

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