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Hydrogen reduced sodium vanadate nanowire arrays as electrode material of lithium-ion battery

氢还原钒酸钠纳米线阵列作为锂离子电池的电极

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Abstract

Vanadates and vanadium oxides are potential lithiumion electrode materials because of their easy preparation and high capacity properties. This paper reports the electrochemical lithium-storage performance of VO2 and NaV2O5 composite nanowire arrays. Firstly, Na5V12O32 nanowire arrays are fabricated by a hydrothermal method, and then VO2 and NaV2O5 composite nanowire arrays are prepared by a reduction reaction of Na5V12O32 nanowire arrays in hydrogen atmosphere. Crystal structure, chemical composition and morphology of the prepared samples are characterized in detail. The obtained composite is used as an electrode of a lithium-ion battery, which exhibits high reversible capacity and good cycle stability. The composite obtained at 500 °C presents a specific discharge capacity up to 345.1 mA × h/g after 50 cycles at a current density of 30 mA/g.

摘要

钒酸盐和氧化钒是潜在的锂离子电池电极材料,具有易于制备和高容量的特点。本文报道了 VO2 和NaV2O5 复合纳米线阵列的电化学锂储存性能。首先,采用水热法制备Na5V12O32 纳米线阵列, 然后将Na5V12O32 纳米线阵列在500 °C 的氢气氛中还原反应制备VO2 和NaV2O5 复合纳米线阵列。对 制备样品的晶体结构,化学组成和形态特征进行了表征。结果表明,所得复合纳米线阵列用作锂离子 电池的电极,具有高可逆容量和良好的循环稳定性。在电流密度为30 mA/g 时经过 50 次循环后,500 °C 下获得的复合物具有高达345.1 mA·h/g 的放电比容量。

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Authors and Affiliations

  1. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China

    Xue-liu Xu  (徐学留), Kang Hua  (华康), Dong Fang  (方东), Rui Bao  (鲍瑞) & Jian-hong Yi  (易健宏)

  2. State Key Laboratory of Porous Metal Materials, Northwest Institute for Nonferrous Metal Research, Xi’an, 710016, China

    Guang-zhong Li  (李广忠)

  3. Yunnan Tin Group (Holding) Co., Ltd., Kunming, 650000, China

    Ze-wei Fu  (符泽卫) & Jun-tao Hu  (胡俊涛)

  4. Department of Chemistry and Physics, Fayetteville State University, Fayetteville, NC, 28301, USA

    Zhi-ping Luo  (罗治平)

  5. School of Foreign Languages, Wuhan Textile University, Wuhan, 430073, China

    Xue-qin Lu  (陆雪芹)

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  1. Xue-liu Xu  (徐学留)
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Correspondence to Xue-qin Lu  (陆雪芹) or Dong Fang  (方东).

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Foundation item: Project(51201117) supported by the National Natural Science Foundation of China

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Xu, Xl., Li, Gz., Fu, Zw. et al. Hydrogen reduced sodium vanadate nanowire arrays as electrode material of lithium-ion battery. J. Cent. South Univ. 26, 1540–1549 (2019). https://doi.org/10.1007/s11771-019-4110-y

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