Mo coatings with or without incorporated MoSi2 were fabricated by atmospheric plasma spraying, and their microstructure, microhardness, bond strength, and wear resistance were compared. Two kinds of spray powder, i.e., pure Mo and a blend of Mo and MoSi2, were sprayed onto low-carbon steel. Microstructural analysis of the MoSi2-Mo coating showed MoSi2 homogeneously distributed in a Mo matrix. Addition of MoSi2 particles increased the microhardness of the as-sprayed Mo coating. The adhesion strength of the Mo coating was better than that of the MoSi2-Mo coating. Wear test results showed that the wear rate and friction coefficient of the two coatings increased with increasing load, and the friction coefficient of the MoSi2-Mo coating was lower than that of the Mo coating. The MoSi2-Mo composite coating exhibited better wear resistance than the Mo coating. The wear failure mechanisms of the two coatings were local plastic deformation, delamination, oxidation, and adhesion wear.
Similar content being viewed by others
References
Z. Liu and M. Hua, Wear Transition and Mechanism in Lubricated Sliding of a Molybdenum Coating, Tribol. Int., 1999, 32(9), p 499-506
B. Hwang, J. Ahn, and S. Lee, Effects of Blending Elements on Wear Resistance of Plasma-Sprayed Molybdenum Blend Coatings Used for Automotive Synchronizer Rings, Surf. Coat. Technol., 2005, 194(2-3), p 256-264
S. Usmani and S. Sampath, Time-Dependent Friction Response of Plasma-Sprayed Molybdenum, Wear, 1999, 225-229, p 1131-1140
S.C. Modi and Eklavya Calla, A Study of High-Velocity Combustion Wire Molybdenum Coatings, J. Therm. Spray Technol., 2001, 10(3), p 480-486
S. Sampath and S.F. Wayne, Microstructure and Properties of Plasma-Sprayed Mo-Mo2C Composites, J. Therm. Spray Technol., 1994, 3(3), p 282-288
L. Prchlik, J. Gutleber, and S. Sampath, Deposition and Properties of High-Velocity-Oxygen-Fuel and Plasma-Sprayed Mo-Mo2C Composite Coatings, J. Therm. Spray Technol., 2001, 10(4), p 643-655
D. Debasish, S. Mantry, D. Behera, and B.B. Jha, Improvement of Microstructural and Mechanical Properties of Plasma Sprayed Mo Coatings Deposited on Al-Si Substrates by Pre-mixing of Mo with TiN Powder, High Temp., 2014, 52(1), p 19-25
J.A. Hawk and D.E. Alman, A Comparative Study of the Abrasive Wear Behavior of MoSi2, Scr. Metall. Mater., 1995, 32, p 725-730
J.A. Hawk and D.E. Alman, Abrasive Wear Behavior of a Brittle Matrix (MoSi2) Composite Reinforced with a Ductile Phase (Nb), Wear, 2001, 251(1-12), p 890-900
J.H. Yan, Z. Zhang, L.F. Liu, H.M. Xu, and Z.Y. Mao, Effect of Nano-ZrO2 on the Microstructure, and High Temperature Tribological Properties of MoSi2 Coating, J. Therm. Spray Technol., 2013, 22(6), p 873-881
P.Q. La, Q.J. Xue, and W.M. Liu, Tribological Properties of MoSi2-MoS2 Coatings Coupling with SAE 52100 Steel Under Reciprocating Sliding, Surf. Coat. Technol., 2001, 135(2-3), p 118-125
J.H. Yan, J.J. Xu, R.U. Din, Y. Wang, and L.F. Liu, Preparation of Agglomerated Powders for Air Plasma Spraying MoSi2 Coating, Ceram. Int., 2015, 41, p 10547-10556
J.H. Yan, Y. Wang, L.F. Liu, Y.M. Wang, and F. Chen, Preparation of Protective MoSi2 Coating on Niobium Substrate, J. Therm. Spray Technol., 2015, 24(6), p 1093-1099
J.H. Yan, L.F. Liu, Z.Y. Mao, H.M. Xu, and Y.M. Wang, Effect of Spraying Powders Size on the Microstructure, Bond Strength, and Microhardness of MoSi2 Coating Prepared by Air Plasma Spraying, J. Therm. Spray Technol., 2015, 24(6), p 934-939
X.B. Zhao and Z.H. Ye, Microstructure and Wear Resistance of Molybdenum Based Amorphous Nanocrystalline Alloy Coating Fabricated by Atmospheric Plasma Spraying, Surf. Coat. Technol., 2013, 228(S1), p 266-270
V.V. Sobolev and J.M. Guilemany, Investigation of Coating Porosity Formation During High Velocity Oxy-Fuel (HVOF) Spraying, Mater. Lett., 1994, 18(5-6), p 304-308
J.K. Yoon, G.H. Kim, J.Y. Byun, J.K. Lee, and J.S. Kim, Formation of Crack-Free MoSi2/α-Si3N4 Composite Coating on Mo Substrate by Ammonia Nitridation of Mo5Si3 Layer Followed by Chemical Vapor Deposition of Si, Surf. Coat. Technol., 2003, 165(1), p 81-89
X.H. Wang, F. Han, X.M. Liu, S.Y. Qu, and Z.D. Zou, Effect of Molybdenum on the Microstructure and Wear Resistance of Fe-Based Hard Facing Coatings, Mater. Sci. Eng. A, 2008, 489(1-2), p 193-200
X. Fei, Y. Niu, H. Ji, L. Huang, and X. Zheng, A Comparative Study of MoSi2 Coatings Manufactured by Atmospheric and Vacuum Plasma Spray Processes, Ceram. Int., 2011, 37(3), p 813-817
Z.J. Yin, S.Y. Tao, X.M. Zhou, and C.X. Ding, Microstructure and Mechanical Properties of Al2O3-Al Composite Coatings Deposited by Plasma Spraying, Appl. Surf. Sci., 2008, 254(6), p 1636-1643
M. Amiriyan, H.D. Alamdari, C. Blais, S. Savoie, R. Schulz, and M. Gariépy, Dry Sliding Wear Behavior of Fe3Al and Fe3Al/TiC Coatings Prepared by HVOF, Wear, 2015, 342-343, p 154-162
Acknowledgments
This project was jointly supported by the National Natural Science Foundation of China (Grant No. 51475161), the Scientific Research Fund of Hunan Provincial Education Department (Grant No. 15A059), and the State Key Laboratory of Powder Metallurgy of Central South University.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yan, J., He, Z., Wang, Y. et al. Microstructure and Wear Resistance of Plasma-Sprayed Molybdenum Coating Reinforced by MoSi2 Particles. J Therm Spray Tech 25, 1322–1329 (2016). https://doi.org/10.1007/s11666-016-0440-6
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11666-016-0440-6