Skip to main content
Log in

Nanostructured Al-Based Metal Matrix Composite Coating Production by Pulsed Gas Dynamic Spraying Process

  • Peer-Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

The advantage of combining cryomilling and pulsed gas dynamic spraying (PGDS) processes in order to produce a nanostructured, dense and wear resistant coating was demonstrated. Cryomilling was successfully employed to synthesize particulate B4C reinforced Al matrix nanocomposite feedstock powders, while the PGDS process shows the ability of preserving the microstructure of the starting material. In this study, nanocrystalline and conventional Al5356 + 20%B4C composite as well as the unreinforced Al5356 alloy feedstock powders were used. The influence of the nature of the feedstock material on the microstructure and mechanical properties of the coatings was studied. The PGDS process provides an opportunity to preserve the phase of the starting material, to produce hard and dense coatings with good cohesion between deformed particles and good adhesion to the substrate. High dry sliding wear resistance was observed when cryomilled composite material was used.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. D.J. Lloyd, Particle Reinforced Aluminum and Magnesium Matrix Composites, Int. Mater. Rev., 1994, 39(1), p 1-23

    Article  CAS  Google Scholar 

  2. S. Elomari, R. Boukhili, and M.D. Skibo, Dynamic Mechanical Analysis of Prestrained Al2O3/Al Metal-Matrix Composite, J. Mater. Sci., 1995, 30, p 3037-3044

    Article  CAS  Google Scholar 

  3. I.A. Ibrahim, F.A. Mohamed, and E.J. Lavernia, Particulate Reinforced Metal Matrix Composites - a review, J. Mater. Sci., 1991, 26, p 1137-1156

    Article  CAS  Google Scholar 

  4. F.A. Girot, J.M. Quenisset, and R. Nashlain, Discontinuously-Reinforced Aluminium Matrix Composites, Compos. Sci. Technol., 1987, 30(3), p 155-159

    Article  CAS  Google Scholar 

  5. R.H. Jones, C.A. Lavender, and M.T. Smith, Yield Strength-Fracture Toughness Relationships in Metal Matrix Composites, Scripta Metall., 1987, 21, p 1565-1574

    Article  CAS  Google Scholar 

  6. V.C. Nardone, Assessment of Models Used to Predict the Strength of Discontinuous Silicon Carbide Reinforced Aluminium Alloys, Scripta Metall., 1987, 21(10), p 1313-1318

    Article  CAS  Google Scholar 

  7. A. Daoud and W. Reif, Influence of Al2O3 Particulate on the Aging Response of Al-Based Composites, J. Mater. Proc. Tech., 2002, 123(2), p 313-318

    Article  CAS  Google Scholar 

  8. M. Kouzeli and A. Mortensen, Size Dependent Strengthening in Particle Reinforced Aluminium, Acta Mater., 2002, 50, p 39-51

    Article  CAS  Google Scholar 

  9. C. Liu, S. Qin, G. Zhang, and M. Naka, Micromechanical Properties of High Fracture Performance SiCp-6061Al/6061Al Composite, Mater. Sci. Eng. A, 2002, 332, p 203-209

    Article  Google Scholar 

  10. J.B. Fogagnolo, F. Velasco, M.H. Robert, and J.M. Torralba, Effect of Mechanical Alloying on the Morphology, Microstructure and Properties of Aluminium Matrix Composite Powders, Mater. Sci. Eng. A, 2003, 342, p 131-143

    Article  Google Scholar 

  11. J. Ye, B.Q. Han, Z. Lee, B. Ahn, S.R. Nutt, and J.M. Schoenung, A Tri-Modal Aluminium Based Composite with Super-High Strength, Scripta Mater., 2005, 53(5), p 481-486

    Article  CAS  Google Scholar 

  12. F. Thévenot, Boron Carbide: A Comprehensive Review, J. Eur. Ceram. Soc., 1990, 6, p 205-225

    Article  Google Scholar 

  13. K.B. Lee, H.S. Sim, S.Y. Cho, and H. Kwon, Reaction Products of Al-Mg/B4C Composite Fabricated by Pressureless Infiltration Technique, Mater. Sci. Eng. A, 2001, 302(2), p 227-234

    Article  Google Scholar 

  14. A.J. Pyzik and D.B. Beaman, AI-B-C Phase Development and Effects on Mechanical Properties of B4C/AI- Derived Composites, J. Am. Ceram. Soc., 1995, 78, p 305-312

    Article  CAS  Google Scholar 

  15. J.P. Lucas, J.J. Stephens, and F.A. Greulich, The Effect of Reinforcement Stability on Composition Redistribution in Cast Aluminium Metal Matrix Composites, Mater. Sci. Eng. A, 1991, 131, p 221-230

    Article  Google Scholar 

  16. G.K. Hu, E.J. Lavernia, W.C. Harrigan, J. Kajuch, and S. Nutt, Microstructural Investigation on B4C/Al7093 Composite, Mater. Sci. Eng. A, 2001, 297, p 94-104

    Article  Google Scholar 

  17. D.C. Halverson, A.J. Pyzik, I.A. Aksay, and W.E. Snowden, Processing of Boron Carbide-Aluminium Composites, J. Am. Ceram. Soc., 1989, 72, p 775-780

    Article  CAS  Google Scholar 

  18. B.S. Lee and S. Kang, Low-Temperature Processing of B4C-Al Composites Via Infiltration Technique, Mater. Chem. Phys., 2001, 67(1-3), p 249-255

    Article  CAS  Google Scholar 

  19. G.M. Bond and O.T. Inal, Shock Compacted Aluminum/Boron Carbide Composites, Comp. Eng., 1995, 5, p 9-16

    Article  CAS  Google Scholar 

  20. S. Suresh, A. Mortensen, and A. Needleman, Fundamentals of Metal-Matrix Composites, Butterworth-Heinemann, Boston, 1993

    Google Scholar 

  21. N. Zhao, J. Li, and X. Yang, Influence of the P/M Process on the Microstructure and Properties of WC Reinforced Copper Matrix Composite, J. Mater. Sci., 2004, 39, p 4829-4834

    Article  CAS  Google Scholar 

  22. J.C. Lee, J.P. Ahn, J.H. Shim, and H.I. Lee, Control of the Interface in SiC/Al Composites, Scripta Mater., 1999, 41(8), p 895-900

    Article  CAS  Google Scholar 

  23. M.C. Gui, S.B. Kang, and K. Euh, Thermal Expansion Behaviour of Plasma Sprayed Al-SiCp Composites, Mater. Sci. Technol., 2008, 24(11), p 1362-1368

    Article  CAS  Google Scholar 

  24. T.P.D. Rajan, R.M. Pillai, and B.C. Pai, Review: Reinforcement Coatings and Interfaces in Aluminium Metal Matrix Composites, J. Mater. Sci., 1998, 33(10), p 3491-3503

    Article  CAS  Google Scholar 

  25. T.W. Clyne and P.J. Withers, An Introduction to Metal Matrix Composites, Cambridge University Press, New York, 1993

    Book  Google Scholar 

  26. S. Guo, Y. Kagawa, H. Inui, and J.-M. Yang, Interfacial Compatibility of C/Au-Coated SiTiCO Fiber-Reinforced Ti Matrix Composite, Scripta Mater., 2003, 49(3), p 231-236

    Article  CAS  Google Scholar 

  27. J. Carmai, K.H. Baik, F.P.E. Dunne, and B. Cantor, Interface Effects During Consolidation in Titanium Alloy Components Locally Reinforced with Matrix-Coated Fibre Composite, Acta Mater., 2002, 50(20), p 4981-7993

    Article  CAS  Google Scholar 

  28. V.L. Tellkamp, A. Melmed, and E.J. Lavernia, Mechanical Behavior and Microstructure of a Thermally Stable Bulk Nanostructured Al Alloy, Metall. Mater. Trans. A, 2001, 32(9), p 2335-2343

    Article  Google Scholar 

  29. C. Suryanarayana, Mechanical Alloying and Milling, Prog. Mater. Sci., 2001, 46(1), p 1-184

    Article  CAS  Google Scholar 

  30. C. Goujon, P. Goeuriot, M. Chedru, J. Vicens, J.L. Chermant, F. Bernard, J.C. Niepce, P. Verdier, and Y. Larrent, Cryomilling of Al/AlN Powders, Powder Technol., 1999, 105(1-3), p 328-336

    Article  CAS  Google Scholar 

  31. F. Zhou, J. Lee, S. Dallek, and E.J. Lavernia, High Grain Size Stability of Nanocrystalline Al Prepared by Mechanical Attrition, J. Mater. Res., 2001, 16(12), p 3451-3458

    Article  CAS  Google Scholar 

  32. J. Ye, J. He, and J.M. Schoenung, Cryomilling for the Synthesis of a B4C Reinforced Al Nanocomposite (Part II), Metall. Trans. A, 2006, 37, p 3111-3117

    Article  Google Scholar 

  33. J. Ye, B.Q. Han, and J.M. Schoenung, Mechanical Behaviour of an Al-Matrix Composite Reinforced with Nanocrystalline Al-Coated B4C Particulates, Philos. Mag. Lett., 2006, 86(11), p 721-732

    Article  CAS  Google Scholar 

  34. M. Yandouzi, E. Sansoucy, L. Ajdelsztajn, and B. Jodoin, WC-Based Cermet Coatings Produced by Cold Gas Dynamic and Pulsed Gas Dynamic Spraying Processes, Surf. Coat. Technol., 2007, 202(2), p 382-390

    Article  CAS  Google Scholar 

  35. M. Yandouzi, A.J. Bottger, R.W.A. Hendrikx, M. Brochu, P. Richer, A. Charest, and B. Jodoin, Microstructure and Mechanical Properties of B4C Reinforced Al-based Matrix Composite Coatings Deposited by CGDS and PGDS Processes, Surf. Coat. Technol., 2010, 205(7), p 2234-2246

    Article  CAS  Google Scholar 

  36. M. Yandouzi and B. Jodoin, Cermet Coatings Prepared by Pulsed Gas Dynamic Spraying Process: Effect of the Process Parameters, Surf. Coat. Technol., 2008, 203(1-2), p 104-114

    Article  CAS  Google Scholar 

  37. B. Jodoin, L. Ajdelsztajn, P. Richer, A. Erdi-Betchi, and M. Yandouzi, Pulsed-Gas Dynamic Spraying: Process Analysis, Development and Selected Coating Examples, Surf. Coat. Technol., 2007, 201(16-17), p 7544-7551

    Article  CAS  Google Scholar 

  38. L. Ajdelsztajn, B. Jodoin, G.E. Kim, J. Schoenung, and J. Mondoux, Cold Spray Deposition of Nanocrystalline Aluminum Alloys, Met. Mater. Trans. A, 2005, 36, p 657-666

    Article  Google Scholar 

  39. R. Vintila, A. Charest, R.A.L. Drew, and M. Brochu, Synthesis and Consolidation via Spark Plasma Sintering of Nanostructured Al5356/B4C Composite, Sci. Eng. A, 2011, 528(13-14), p 4395-4407

    Article  Google Scholar 

  40. B. Jodoin, Methods and Apparatuses for Material Deposition, Canadian Patent, WO2006119620 (A1), Nov 16, 2006, Canada

  41. B. Jodoin, Methods and Apparatuses for Material Deposition, US Patent Application #20080233282, 25 Sep 2008

  42. J. Villafuerte, D. Vanderzwet, M. Yandouzi, and B. Jodoin, Shokwave Induced Spraying, Adv. Mater. Proc., 2009, 167(3), p 32-34

    CAS  Google Scholar 

  43. F. Robitaille, M. Yandouzi, S. Hind, and B. Jodoin, Metallic Coating of Aerospace Carbon/Epoxy Composites by the Pulsed Gas Dynamic Spraying Process, Surf. Coat. Technol., 2009, 203(19), p 2954-2960

    Article  CAS  Google Scholar 

  44. ASTM E 1920-03 (Reapproved 2008), Standard Guide for Metallographic Preparation of Thermal Sprayed Coatings, Annual Book of ASTM Standards, ASTM, USA, 2003

  45. EN 15340, European Standard Method-Determination of Shear Load Resistance of Thermally Sprayed Coatings, A91-229, 2007

  46. G. Marot, J. Lesage, Ph. Demarecaux, M. Hadad, St. Siegmann, and M.H. Staia, Interfacial Indentation and Shear Tests to Determine the Adhesion of Thermal Spray Coatings, Surf. Coat. Technol., 2006, 201(5), p 2080-2085

    Article  CAS  Google Scholar 

  47. ASTM G133-05, Standard Test Method for Linearly Reciprocating Ball-on-Flat Sliding Wear, Annual Book of ASTM Standards, ASTM, USA, 1995

  48. D.B. Witkin and E.J. Lavernia, Synthesis and Mechanical Behaviour of Nanostructured Materials Via Cryomilling, Prog. Mater. Sci., 2006, 51, p 1-60

    Article  CAS  Google Scholar 

  49. M. Yandouzi, P. Richer, and B. Jodoin, SiC Particulate Reinforced Al-12Si Alloy Composite Coatings Produced by the Pulsed Gas Dynamic Spray Process: Microstructure and Properties, Surf. Coat. Technol., 2009, 203(20-21), p 3260-3270

    Article  CAS  Google Scholar 

  50. O. Sarikaya, S. Anik, S. Aslanlar, S.C. Okumus, and E. Celik, Al-12Si/B4C Composite Coatings on Al-Si Substrate by Plasma Spray Technique, Mater. Des., 2007, 28(9), p 2443-2450

    Article  CAS  Google Scholar 

  51. J. Zhang and A.T. Alpas, Transition Between Mild and Severe Wear in Aluminium Alloys, Acta Mater., 1997, 2(2), p 513-528

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Yandouzi.

Additional information

This article is an invited paper selected from presentations at the 2011 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Thermal Spray 2011: Proceedings of the International Thermal Spray Conference, Hamburg, Germany, September 27-29, 2011, Basil R. Marple, Arvind Agarwal, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and André McDonald, Ed., ASM International, Materials Park, OH, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yandouzi, M., Bu, H., Brochu, M. et al. Nanostructured Al-Based Metal Matrix Composite Coating Production by Pulsed Gas Dynamic Spraying Process. J Therm Spray Tech 21, 609–619 (2012). https://doi.org/10.1007/s11666-011-9727-9

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-011-9727-9

Keywords

Navigation