Abstract
In our previous study, a method to fabricate super-ductile polypropylene/low-density polyethylene (PP/LDPE) blends was proposed, and a fiber-shape structure was shown to be formed, presenting necking propagation during tensile testing. In this study, the mechanical properties and thermal behavior of the necking region of tested super-ductile PP/LDPE samples were carefully investigated and further compared with the melt-stretched, untested, and thermo-mechanical-history-removed samples by differential scanning calorimetry and tensile testing. The results suggest that the tested samples have high mechanical properties and are more thermo-mechanically stable than the common PP/LDPE blends and melt-stretched samples. Additionally, to investigate their structure-property relationship, the necking region of the tested samples was further characterized by scanning electron microscopy and hot-stage polarized light microscopy. It can be concluded that the variation of the microstructure can be attributed to the cold-drawn fibers (CDFs), which were more stable thermally, formed during the tensile test. Furthermore, the CDFs were used for the filler in PP/LDPE blends. The experimental results of the different PP/LDPE composites indicate that the CDFs are a good reinforcement candidate and have the ability to improve the mechanical properties of the PP/LDPE blends.
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R.E. Robertson and D.R. Paul, Stress–Strain Behavior of Polyolefin Blends, J. Appl. Polym. Sci., 1973, 17, p 2579–2595
J.W. Teh, Structure and Properties of Polyethylene–Polypropylene Blend, J. Appl. Polym. Sci., 1983, 28, p 605–618
L.M. Robeson, Applications of Polymer Blends: Emphasis on Recent Advances, Polym. Eng. Sci., 1984, 24(8), p 587–597
G. Rizzo and G. Spadaro, Mechanical Properties of Low Density Polyethylene-Isotactic Polypropylene Blends: I. Effect of Mixing Time, Eur. Polym. J., 1988, 24(4), p 303–306
L.S. Dong, R.H. Olley, and D.C. Bassett, On Morphology and the Competition Between Crystallization and Phase Separation in Polypropylene-Polyethylene Blends, J. Mater. Sci., 1998, 33, p 4043–4048
S. Danesi and R.S. Porter, Blends of Isotactic Polypropylene and Ethylene-Propylene Rubbers: Rheology, Morphol. Mech. Polym., 1978, 19(4), p 448–457
X.M. Xie, M. Matsuoka, and K. Takemura, Formation of Gradient Phase Structure during Annealing of a Polymer Blend, Polymer, 1992, 33(9), p 1996–1998
N.V. Penava, V. Rek, and I.F. Houra, Effect of EPDM as a Compatibilizer on Mechanical Properties and Morphology of PP/LDPE Blends, J. Elastom. Plast., 2012, 45(4), p 391–403
A.A. Al-Juhani and M.A. Suleiman, Study of the Effect of EPDM Structure on the Compatibility of PP/LDPE Blends, Arab J. Sci. Eng., 2012, 37, p 863–875
T. Nedkov, F. Lednický, and M. Mihailova, Compatibilization of PP/PE Blends and Scraps with Royalene: Mechanical Properties, SAXS, and WAXS, J. Appl. Polym. Sci., 2008, 109(1), p 226–233
M.A. Ramos and F.A. Belmontes, Polypropylene/Low Density Polyethylene Blends with Short Glass Fibers. II: Effect of Compounding Method on Mechanical Properties, Polym. Compos., 1991, 12(1), p 1–6
C.H. Tselios, D. Bikiaris, P. Savidis, C. Panayiotou, and A. Larena, Glass-Fiber Reinforcement of in situ Compatibilized Polypropylene/Polyethylene Blends, J. Mater. Sci., 1999, 34, p 385–394
M.R. Arroyo and M.A. Lopez-Manchado, PP/LDPE Blends Filled with Short Polyamide Fibers, Die Angew. Makromol. Chem., 1995, 226(1), p 129–141
M.A. Ramos, M.S. Berna, and J.P.V. Matheu, Effect of Talc Surface Treatment on the Mechanical Properties of Composites based on PP/LDPE Blend Matrices, Polym. Eng. Sci., 1991, 31(4), p 245–252
M.R. Arroyo and M.A. Lopez-Manchado, Impact Behaviour of Modified Talc Filled PP/LDPE Blends, J. Polym. Eng., 1995, 14(4), p 237–252
K. Şirin and M. Balcan, Mechanical Properties and Thermal Analysis of Low-Density Polyethylene + Polypropylene Blends with Dialkyl Peroxide, Polym. Adv. Technol., 2010, 21(4), p 250–255
F. Doğan, K. Şirin, İ. Kaya, and M. Balcan, The Influence of CaCO3 Filler Component on Thermal Decomposition Process of PP/LDPE/DAP Ternary Blend, Polym. Adv. Technol., 2010, 21(7), p 512–519
A.E. Zaikin and G.B. Bobrov, Compatibilization of Blends of Incompatible Polymers via Filling, Polym. Sci. Ser. A, 2012, 54(8), p 651–657
D.G. Dikobe and A.S. Luyt, Investigation of the Morphology and Properties of the Polypropylene/Low-Density Polyethylene/Wood Powder and the Maleic Anhydride Grafted Polypropylene/Low-Density Polyethylene/Wood Powder Polymer Blend Composites, J. Compos. Mater., 2016, doi:10.1177/0021998316668399
A. Dhoble, B. Kulshreshtha, S. Ramaswami, and D.A. Zumbrunnen, Mechanical Properties of PP-LDPE Blends with Novel Morphologies Produced with a Continuous Chaotic Advection Blender, Polymer, 2005, 46, p 2244–2256
X. Sun, H. Kharbas, J. Peng, and L.S. Turng, A Novel Method of Producing Lightweight Microcellular Injection Molded Parts with Improved Ductility and Toughness, Polymer, 2015, 56, p 102–110
J.W. Teh, A. Rudin, and J.C. Keung, A Review of Polyethylene–Polypropylene Blends and their Compatibilization, Adv. Polym. Technol., 1994, 13(1), p 1–23
Y.G. Zhou, B. Su, and L.S. Turng, Fabrication of Super-Ductile PP/LDPE Blended Parts With a Chemical Foaming Agent, J. Appl. Polym. Sci., 2016, 133(42), p 44101. doi:10.1002/app.44101
Y.G. Zhou, B. Su, and L.S. Turng, Influence of Processing Conditions on Morphological Structure and Ductility of Water-Foamed Injection Molded PP/LDPE Blended Parts, Cell. Polym., 2017, 36(2), p 51–74
C. Gao, L. Yu, H. Liu, H. Liu, and L. Chen, Development of Self-Reinforced Polymer Composites, Prog. Polym. Sci., 2012, 37, p 767–780
J. Li, R.A. Shanks, and Y. Long, Mechanical Properties and Morphology of Polyethylene–Polypropylene Blends with Controlled Thermal History, J. Appl. Polym. Sci., 2000, 76(7), p 1151–1164
H. Bai, F. Luo, T. Zhou, H. Deng, K. Wang, and Q. Fu, New Insight on the Annealing Induced Microstructural Changes and their Roles in the Toughening of β-form Polypropylene, Polymer, 2011, 52, p 2351–2360
R.H. Somani, L.S. Yang, I. Hsiao, B.S. Pogodina, N.V. Winter, and H.H. Agarwal, Orientation Induced Crystallization in isotactic Polypropylene Melt by Shear Deformation, Macromol. Symp., 2002, 185, p 105–118
A. Maus, E. Hempel, T. Thurn-Albrecht, and K. Saalwachter, Memory Effect in Isothermal Crystallization of Syndiotactic Polypropylene—Role of Melt Structure and Dynamics, Eur. Phys. J. E, 2007, 23, p 91–101
A. Ziabicki and G.C. Alfonso, Memory Effects in Isothermal Crystallization I, Theory, Colloid Polym. Sci., 1994, 272, p 1027–1042
G.C. Alfonso and A. Ziabicki, Memory Effects in Isothermal Crystallization II, Isotactic Polypropylene, Colloid Polym. Sci., 1995, 273, p 317–323
Acknowledgments
The authors would like to express their gratitude to the National Natural Science Foundation of China (Grant No. 51373048), the Priority Academic Program Development of Jiangsu Higher Education Institutions, the Postgraduate Research Innovation Program of Jiangsu University of Science and Technology (Grant No. YCX16S-19), and the Postgraduate Research and Practice Innovation Program of Jiangsu Province (Grant No. KYCX17_1833) for their financial support. The correspondence author also thanks Prof. Chang-Yu Shen at State Intellectual Property Office, Prof. Jing-Bo Chen and Prof. Cun-Tai Liu at Zhengzhou University, and Prof. Lih-Sheng Turng at University of Wisconsin-Madison for their helpful suggestion.
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Zhou, YG., Su, B. & Wu, HH. Effect of Cold-Drawn Fibers on the Self-Reinforcement of PP/LDPE Composites. J. of Materi Eng and Perform 26, 4072–4082 (2017). https://doi.org/10.1007/s11665-017-2823-3
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DOI: https://doi.org/10.1007/s11665-017-2823-3