Abstract
Phase transformation during heating in homogenized Ti-22Al-(27-x)Nb-xZr (x = 0, 1, 6) alloys is monitored by dilatometry, differential scanning calorimetry (DSC), and detailed metallographic examination. Moreover, the dissolution of α2 into the B 2/β matrix is investigated and discussed. In Ti-22Al-27Nb alloy, the sequence of phase transformation during heating can be concluded as follows: B 2/β → O, B 2/β + α2 → O, B 2/β + O→B 2/β + O + α2, B 2/β + O + α2 → B 2/β + α2, and B 2/β + α2 → B 2/β. For Ti-22Al-21Nb-6Zr alloy, it is B 2/β → α2 + O, O + α2 + B 2/β → B 2/β + α2, and then α2 dissolves into B 2 matrix. There are considerable shifts in the maxima of the transformation rates in B 2/β + O+α2 → B 2/β + α2 and B 2/β + α2 → B 2/β transformed region to the higher temperatures with increasing x value. In the stage of B 2/β + α2 → B 2/β, there is a deceleration of reduction in α2 phase with increasing temperature for Ti-22Al-(27-x)Nb-xZr (x = 0, 1, 6) alloys. And for Ti-22Al-21Nb-6Zr, the dissolution rate of α2 phase is accelerated.
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D. Banerjee, A.K. Gogia, T.K. Nandi, and V.A. Joshi, A New Ordered Orthorhombic Phase in a Ti3Al-Nb Alloy, Acta Metall., 1988, 36, p 871–882
J. Kumpfert, Intermetallic Alloys Based on Orthorhombic Titanium Aluminide, Adv. Eng. Mater., 2001, 3, p 851–864
J. Jia, K. Zhang, L. Liu, and F. Wu, Hot Deformation Behavior and Processing Map of a Powder Metallurgy Ti-22Al-25Nb Alloy, J. Alloys Compd., 2014, 600, p 215–221
Z.L. Lei, Z.J. Dong, Y.B. Chen, J. Zhang, and R.C. Zhu, Microstructure and Tensile Properties of Laser Beam Welded Ti-22Al-27Nb Alloys, Mater. Design., 2013, 46, p 151–156
J. Shen and A.H. Feng, Recent Advances on Microstructural Controlling and Hot Forming of Ti2AlNb-based Alloys, Acta Metall. Sin., 2013, 49, p 1286–1294
C. Xue, W.D. Zeng, W. Wang, X.B. Liang, and J.W. Zhang, Coarsening Behavior of Lamellar Orthorhombic Phase and Its Effect on Tensile Properties for the Ti-22Al-25Nb Alloy, Mat. Sci. Eng. A-struct, 2014, 611, p 320–325
S. Emura, A. Araoka, and M. Hagiwara, B 2 Grain Size Refinement and Its Effect on Room Temperature Tensile Properties of a Ti-22Al-27Nb Orthorhombic Intermetallic Alloy, Scr. Mater., 2003, 48, p 629–634
C.J. Cowen and C.J. Boehlert, Microstructure, Creep, and Tensile Behavior of a Ti-21Al-29Nb (at.%) Orthorhombic + B 2 Alloy, Intermetallics, 2006, 14(issue), p 412–422
P. Lin, Z. He, S. Yuan, J. Shen, Y. Huang, and X. Liang, Instability of the O-Phase in Ti-22Al-25Nb Alloy during Elevated-Temperature Deformation, J. Alloy. Compd., 2013, 578, p 96–102
W. Wang, W. Zeng, C. Xue, X. Liang, and J. Zhang, Quantitative Analysis of the Effect of Heat Treatment on Microstructural Evolution and Microhardness of an Isothermally Forged Ti-22Al-25Nb (at.%) Orthorhombic Alloy, Intermetallics, 2014, 45, p 29–37
C. Boehlert, B. Majumdar, V. Seetharaman, and D. Miracle, Part I. The Microstructural Evolution in Ti-Al-Nb O + Bcc Orthorhombic Alloys, Titanium’95, Vol 1, P.A. Blenklnsop, W.J. Evans, and H.M. Flower, Ed., The University Press, Cambridge, UK, 1996, p 372–379
A. Li, G. Fan, R. Chen, Z. Tan and L. Gen. A Method of Fabricating Ti2AlNb Alloys by Vacuum Pressure Infiltration, 2014, Patent, CN 103710554.
C. Leyens and H. Gedanitz, Long-term Oxidation of Orthorhombic Alloy Ti-22Al-25Nb in Air between 650 and 800°C, Scr. Mater., 1999, 41, p 901–906
L. Germann, D. Banerjee, J.Y. Guedou, and J.L. Strudel, Effect of Composition on the Mechanical Properties of Newly Developed Ti2AlNb-Based Titanium Aluminide, Intermetallics, 2005, 13, p 920–924
O.G. Khadzhieva, A.G. Illarionov, and A.A. Popov, Effect of Aging on Structure and Properties of Quenched Alloy Based on Orthorhombic Titanium Aluminide Ti2AlNb, Phys. Met. Metallogr., 2014, 115, p 12–20
C. Xue, W.D. Zeng, W. Wang, X.B. Liang, and J.W. Zhang, The Enhanced Tensile Property by Introducing Bimodal Size Distribution of Lamellar O for O + B 2 Ti2AlNb Based Alloy, Mat. Sci. Eng. A-struct, 2013, 587, p 54–60
C. Xue, W. Zeng, B. Xu, X. Liang, J. Zhang, and S. Li, B 2 Grain Growth and Particle Pinning Effect of Ti-22Al-25Nb Orthorhombic Intermetallic Alloy During Heating Process, Intermetallics, 2012, 29, p 41–47
W. Wang, W. Zeng, C. Xue, X. Liang, and J. Zhang, Microstructural Evolution, Creep, and Tensile Behavior of a Ti-22Al-25Nb (at%) Orthorhombic Alloy, Mat. Sci. Eng. A Struct., 2014, 603, p 176–184
Y.X. Wang, K.F. Zhang, and B.Y. Li, Microstructure and High Temperature Tensile Properties of Ti-22Al-25Nb Alloy Prepared by Reactive Sintering with Element Powders, Mat. Sci. Eng. A-Struct., 2014, 608, p 229–233
C.J. Boehlert, The Phase Evolution and Microstructural Stability of an Orthorhombic Ti-23Al-27Nb Alloy, J. Phase Equilib., 1999, 20, p 101–108
A. Grajcar, W. Zalecki, P. Skrzypczyk, A. Kilarski, A. Kowalski, and S. Kołodziej, Dilatometric Study of Phase Transformations in Advanced High-strength Bainitic Steel, J. Therm. Anal. Calorim., 2014, 118, p 739–748
Y. Liu, F. Sommer, and E. Mittemeijer, Abnormal Austenite–Ferrite Transformation Behaviour in Substitutional Fe-based Alloys, Acta Mater., 2003, 51, p 507–519
M.I. Daoudi, A. Triki, A. Redjaimia, and C. Yamina, The Determination of the Activation Energy Varying with the Precipitated Fraction of β″ Metastable Phase in an Al-Si-Mg Alloy Using Non-Isothermal Dilatometry, Thermochim. Acta, 2014, 577, p 5–10
C. Boehlert, B. Majumdar, V. Seetharaman, and D. Miracle, Part I. The Microstructural Evolution in Ti-Al-Nb O + Bcc Orthorhombic Alloys, Metall. Mater. Trans. A, 1999, 30, p 2305–2323
W. Sha and Z. Guo, Phase Evolution of Ti–6Al–4V during Continuous Heating, J. Alloy. Compd., 1999, 290, p L3–L7
Q. Hui, X.Y. Xue, H.C. Kou, M.J. Lai, B. Tang, and J.S. Li, Kinetics of the Omega Phase Transformation of Ti-7333 Titanium Alloy During Continuous Heating, J. Mater. Sci., 2013, 48, p 1966–1972
S.V. Divinski, C. Herzig, and C. Klinkenberg, Tracer Diffusion of Niobium and Titanium in Binary and Ternary Titanium Aluminides, J. Phase Equilib. Diff., 2005, 26, p 452–457
R. Perez, H. Nakajima, and F. Dyment, Diffusion in α-Ti and Zr, Mater. Trans., 2003, 44, p 2–13
Y. Hao, D. Xu, Y. Cui, R. Yang, and D. Li, The Site Occupancies of Alloying Elements in TiAl and Ti3Al Alloys, Acta Mater., 1999, 47, p 1129–1139
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The authors thank the financial supports from the National Basic Research Program of China (2011CB605503).
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Dang, W., Li, J., Zhang, T. et al. Microstructure and Phase Transformation in Ti-22Al-(27-x)Nb-xZr Alloys During Continuous Heating. J. of Materi Eng and Perform 24, 3951–3957 (2015). https://doi.org/10.1007/s11665-015-1659-y
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DOI: https://doi.org/10.1007/s11665-015-1659-y