Abstract
Nanocrystalline ZnO and Mn (1 wt.%)-doped ZnO particles have been synthesized via reverse micelle method. The structural, particulate, and optical properties of the synthesized nanoparticles have been studied by XRD, TEM, UV-Vis, and PL spectroscopy. The obtained data indicate the synthesis of the pure nanoparticles structure with wurtzite structure, average particle size of 18-21 nm, and high optical quality. Gas sensing properties of the nanocrystalline ZnO and Mn-doped ZnO particles toward gasoline and ethanol vapors have been investigated at different temperatures and concentrations. The results show that the optimum working temperature of the gas sensors based on ZnO and Mn-doped ZnO particles are about 633 and 620 K toward ethanol vapor and about 560 and 608 K toward gasoline vapor, respectively. Based on the results, although Mn impurities reduce the sensitivity of the ZnO gas sensor, they cause sensor to saturate at much higher gas concentration.
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S. Maensiri, C. Masingboon, V. Promarak, and S. Seraphin, Synthesis and Optical Properties of Nanocrystalline V-Doped ZnO Powders, Opt. Mater., 2007, 29, p 1700–1705
D. Kumar, S. Kumar, H.S. Bhatti, A. Gupta, and J.K. Sharma, Synthesis of ZnO:Mn Nanoparticles, Nanobelts and Nanorods, J. Ovonic Res., 2008, 4, p 101–105
P. Kumbhakar, D. Singh, C.S. Tiwary, and A.K. Mitra, Chemical Synthesis and Visible Photoluminescence Emission from Monodispersed ZnO Nanoparticles, Chalcogenide Lett., 2008, 5, p 387–394
J.G. Lu, P. Chang, and Z. Fan, Metal Oxide Nanowires: Synthesis, Properties and Applications, Mater. Sci. Eng. R, 2006, 52, p 49–91
Z.L. Wang, Zinc Oxide Nanostructures: Growth, Properties and Applications, J. Phys. Condens. Matter, 2004, 16, p R829–R858
W.E. Mahmoud and A.A. Al-Ghamdi, Synthesis of CdZnO Thin Film as a Potential Candidate for Optical Switches, Opt. Laser Technol., 2010, 42, p 1134–1138
M. Karimi, J. Saydi, M. Mahmoodi, J. Seidi, M. Ezzati, S. Shamsi Anari, and B. Ghasemian, A Comparative Study on Ethanol Gas Sensing Properties of ZnO and Zn0.94Cd0.06O Nanoparticles, J. Phys. Chem. Sol., 2013, 74, p 1392–1398
M. Karimi, V. Jahangir, M. Ezzati, J. Saydi, and M. Behtaj Lejbini, Zn0.94Cd0.06O Nanoparticles with Various Structures, Morphologies and Optical Properties Toward MB Optodecolorization, Opt. Mater., 2014, 36, p 697–703
O.D. Jayakumar, I.K. Gopalakrishnan, R.M. Kadam, A. Vinu, A. Asthana, and A.K. Tyagi, Magnetization and Structural Studies of Mn Doped ZnO Nanoparticles: Prepared by Reverse Micelle Method, J. Cryst. Growth, 2007, 300, p 358–363
C. Xu, J. Tamaki, N. Miura, and N. Yamazor, Grain Size Effects on Gas Sensitivity of Porous SnO2-Based Elements, Sens. Actuators B, 1991, 3, p 147–155
G. Zhang and M. Liu, Effect of Particle Size and Dopant on Properties of SnO2-Based Gas Sensors, Sens. Actuators B, 2000, 69, p 144–152
J. Xu, Q. Pan, Y. Shun, and Z. Tian, Grain Size Control and Gas Sensing Properties of ZnO Gas Sensor, Sens. Actuators B, 2000, 66, p 277–279
Z. Khorsand, W.H.A. Majid, M.E. Abrishami, and R. Yousefi, X-ray Analysis of ZnO Nanoparticles by Williamson-Hall and Size-Strain Plot Methods, Solid State Sci., 2011, 13, p 251–256
W.I. Park, G.C. Yi, and H.M. Jang, Metalorganic Vapor-Phase Epitaxial Growth and Photoluminescent Properties of Zn1−x Mg x O (0 ≤ x ≤ 0.49) Thin Films, Appl. Phys. Lett., 2001, 79, p 2022–2024
O.K. Tan, W. Cao, Y. Hu, and W. Zhu, Nano-structured Oxide Semiconductor Materials for Gas-Sensing Applications, Ceram. Inter., 2004, 30, p 1127–1133
A. Mohamadrezaei and R. Afzalzadeh, Ethanol Sensing Properties of Pure and Ag Nanoparticles-Doped Zinc Oxide with Noble Metal Catalytic Contacts, Sens. Lett., 2010, 8, p 777–783
N. Hongsith, C. Viriyaworasakul, P. Mangkorntong, N. Mangkorntong, and S. Choopun, Ethanol Sensor Based on ZnO and Au-Doped ZnO Nanowires, Ceram. Int., 2008, 34, p 823–826
M. Takata, D. Tsubone, and H. Yanagida, Dependence of Electrical Conductivity of ZnO on Degree of Sintering, J. Am. Ceram. Soc., 1976, 59, p 4–8
Z. Yang, Y. Huang, G. Chen, Z. Guo, S. Cheng, and S. Huang, Ethanol Gas Sensor Based on Al-doped ZnO Nanomaterial with Many Gas Diffusing Channels, Sens. Actuators B, 2009, 140, p 549–556
S. Santra, P.K. Guha, S.Z. Ali, P. Hiralal, H.E. Unalan, J.A. Covington, G.A.J. Amaratunga, W.I. Milne, J.W. Gardner, and F. Udrea, ZnO Nanowires Grown on SOI, CMOS Substrate for Ethanol Sensing, Sens. Actuators B, 2010, 146, p 559–565
T.J. Hsueh and C.L. Hsu, Fabrication of Gas Sensing Devices with ZnO Nanostructure by the Low-Temperature Oxidation of Zinc Particles, Sens. Actuators B, 2008, 131, p 572–576
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The financial support of Iran Nanotechnology Initiative Council and Islamic Azad University is gratefully acknowledged.
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Saydi, J., Karimi, M., Mazhdi, M. et al. Synthesis, Characterization, and Gas Sensing Properties of Pure and Mn-doped ZnO Nanocrystalline Particles. J. of Materi Eng and Perform 23, 3489–3496 (2014). https://doi.org/10.1007/s11665-014-1162-x
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DOI: https://doi.org/10.1007/s11665-014-1162-x