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Thermodynamic description for concentrated metallic solutions using interaction parameters

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Abstract

The integral molar excess Gibbs energy of a multicomponent system is expressed in terms of interaction parameters, from which the analytical formulae of the activity coefficients of the solutes and solvent, as Eqs. [23] and [24], were deduced. This approach, named the ε approach, is able to describe quantitatively the thermodynamic properties of multicomponent systems. It features thermodynamic consistency, high accuracy, and a rather small influence of the higher-interaction parameters on the thermodynamic properties of metallic solutions. A simple modification to the first-order interaction parameters extends the ε approach, to be applicable to systems with strong interactions between components at both low and concentrated levels.

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  1. Zhongting MA (Associate Professor)

    Present address: the Beijing University of Science and Technology, Beijing, P.R. China

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  1. the Institute of Iron and Steel Technology, Freiberg University of Mining and Technology, Freiberg, Germany

    Zhongting MA (Associate Professor)

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MA, Z. Thermodynamic description for concentrated metallic solutions using interaction parameters. Metall Mater Trans B 32, 87–103 (2001). https://doi.org/10.1007/s11663-001-0011-0

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  • DOI: https://doi.org/10.1007/s11663-001-0011-0

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