Abstract
The lunar volcanic glasses and Mg-suite rocks represent the early enigmatic episodes of lunar magmatism. Due to the gravitational instability of the Fe–Ti enriched (± KREEP) layer, which is formed at the later stage of fractional crystallization, a post-magma-ocean cumulate overturn occurred contemporaneously or near-contemporaneously with the lunar magma ocean (LMO) solidification. The radioactive elements within the KREEP layer were transferred downward and provided continuous energy for the partial melting of the Moon’s interior. The melt from the Moon’s interior and those from decompression melting, in turn, provide source magma for the origin of lunar volcanic glasses and Mg-suite. However, experimental and theoretical studies on the formation process of lunar volcanic glasses and Mg-suite show that the origin of their parental magma is poorly constrained, which largely depends on the initial depth and composition of the LMO. This review examines the mineralogy, petrogenesis, and distribution of lunar volcanic glasses and Mg-suite. Combining with existing models, we constrain the degree, distribution, and timescale of lunar mantle overturn and explore their relationship with later stages of LMO differentiation. We propose an updated chemical composition of the lunar interior, which provides a useful reference for estimating the bulk composition and early differentiation of the Moon and the early Earth.
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This work was funded by the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB 41000000), the National Natural Science Foundation of China (41773052, 41973058, 41603067, and 42003054), Key Research Program of Frontier Sciences, CAS (ZDBS-SSW-JSC007-10), and Technical Support Talent Program of Chinese Academy of Sciences, 2021.
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Li, R., Du, W. & Yang, J. Petrogenesis of the Lunar volcanic glasses and Mg-suite: constraints on a post-magma-ocean cumulate overturn. Acta Geochim 41, 717–729 (2022). https://doi.org/10.1007/s11631-022-00539-w
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DOI: https://doi.org/10.1007/s11631-022-00539-w