Abstract
In order to avoid environmental pollution from Coal gangue (CG) and copper tailings (CT), the utilization as cement clinker calcinations was experimentally investigated. Low-calcium limestone was also selected as another raw material. The clinker component and microstructure were analyzed by XRD and SEM. The experimental results showed that qualified cement clinker could be generated by substituting CG and CT compound for clay. While mixed with high-calcium limestone and low-calcium limestone, the calcinations temperature were 50 °C or 100 °C lower than that of clay. CT and CG contain oxygen-rich minerals and potential of geological rock energy. The energy of CG performs functions and drops down sintering temperature. The calcination time was shortened and the clinker sintering coal consumption reduced while substituting CG and CT for clay, and also served the reutilization of low-calcium limestone, CG and CT.
Similar content being viewed by others
References
GUO W, ZHU JP, LI DX, et al. Early Hydration of Composite Cement with Thermal Activated Coal Gangue[J]. J. of Wuhan Univ. of Techn.-Mater. Sci. Ed., 2010, 25(1):162–166
Wang XM, Zhao B, Zhang CS. Zhang Q L. Paste-like Self-Flowing Transportation Backfilling Technology based on Coal Gangue[J]. Min. Sci. & Tech.., 2009,19(2): 0 137–0 143
Li DX, XS, Gong CC, Pan ZH. Research on Cementitious Behavior and Mechanism of Pozzolanic Cement with Coal Gangue[J]. Cem. Concr. Res., 2006,36:1 752–1 759
Li C, Wan JH, Sun HH, Li LT. Investigation on the Activation of Coal Gangue by a New Compound Method[J]. J. of Haza. Mater., 2010,179:515–520
Chana BKC, Bouzalakosb S, Dudeney AWL. Cement -ed Products Containing Waste from Mineral Processing and Bioleaching[J]. Min. Eng., 2009,22(15): 1 326–1 333
National Bureau of Statistics of China. Various Sectors of Industrial Solid Waste Generation and Emissions[EB/OL]. http://www.stats.gov.cn/tjsj/ndsj/2009/indexch.htm
Mostafa Benzaazoua, Tikou Belem, Bruno Bussie’re. Chemical Factors that Influence the Performance of Mine Sulphidic Paste Backfill[J]. Cem. Concr. Res., 2003, 32:1 133–1 144
Weaver W S, Luka R. Laboratory Studies of Cement-stabilized Mine Tailings[J]. Can. Min. Metall. Bull., 1970,64(701):988–1 001
Choi Y W, Kim Y J, Choi O, Lee K M. Mohamed Lachemi, Utilization of Tailings from Tungsten Mine Waste as a Substitution Material for Cement[J]. Constr. & Build. Mat., 2009,23(2):2 481–2 486
Carlson L, Bigham J M, Schwertmann U, Kyek A, Wagner F. Scavenging of as from Acid Mine Drainage by Schwertmannite and Ferrihydrite: A Comparison with Synthetic Analogues[J]. Env. Sci. Tech., 2002, 36(8):1712–1719
Huang S W, Yu P S. Burnability of Raw Materials and Mineral Characteristics of Clinker for Copper Slag Ingredients[J]. Cem. Eng. 2002, 6(3):18–20
Lim MH, Han GC, Ahn JW, You KS and Kim HS. Leachability of Arsenic and Heavy Metals from Mine Tailings of Abandoned Metal Mines[J]. Int. J. Env. Res. Pub. Healt., 2009, 6:2 865–2 879
Wang ZS, Fu SY. New Technologies and Theory of New Cement Raw Material for Clinker[M]. Beijing: China Science Tech Press, 1999:16–20
Shvarzman A, Kovler K, Grader G S, Shter G E. The Effect of Dehydroxylation/Amorphization Degree on Pozzolanic Activity of Kaolinite[J]. Cem. Concr. Res., 2003,33(3):405–416
Papadakis V G. Experimental Investigation and Theoretical Modeling of Silica Fume Activity Concrete[J]. Cem. Concr. Res., 1999,29(1):79–86
Horváth E, Frost RL, Makó É, Kristóf J, Cseh T. Thermal Treatment of Mechanochemically Activated Kaolinite[J]. Therm. Act., 2003,404(1):227–234
Ma XW, Niu JS. Discussion on Stimulates Method of Active Coal Gangue[J]. Mult. Util. of Min. Res., 2008,4(2):41–49
GUO W, Li DX, CHEN JH, et al. Structure and Pozzolanic Activity of Calcined Coal Gangue during the Process of Mechanical Activation[J]. J. of Wuhan Univ. of Techn.-Mater. Sci. Ed., 2009, 24(2):326–328
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the “11th-Five-Year” National Key Technologies R&D Program of China (No.2006BAC21B02)
Rights and permissions
About this article
Cite this article
Qiu, G., Luo, Z., Shi, Z. et al. Utilization of coal gangue and copper tailings as clay for cement clinker calcinations. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 26, 1205–1210 (2011). https://doi.org/10.1007/s11595-011-0391-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-011-0391-1