Abstract
The mechanisms of microstructure evolution and dendritic growth of Inconel alloys in a drop tube were investigated in this paper. The Vickers microhardness of the solidified alloy droplets was also measured to explore the effects of grain size and precipitated phase on the mechanical properties. From XRD results, the rapidly solidified Inconel 600, 617, 625, and 718 alloys are characterized by γ phase solid solution with fcc structure. Further analyses based on EDS and SEM reveal that Laves phase precipitates at the grain boundaries of γ phase in Inconel 718 alloy. With the decrease of droplet diameter (D), the dendritic morphology experiences a transformation of “orthogonal long dendrites→irregular stubby dendrites→equiaxed grains” in Inconel 600 alloy, “orthogonal long dendrites → stubby irregular dendrites” in Inconel 625 alloy and “orthogonal long dendrites→equiaxed grains” in Inconel 617 and 718 alloys. Although the dendrites become coarse locally, the dendritic grain size obviously reduces with the decrease of droplet diameter, leading to the increase of Vickers microhardness. For Inconel 718 alloy, the Vickers microhardness firstly decreases, when the droplet diameter decreases from 1000 to 900 µm, and then increases linearly with the decrease of droplet diameter. It is found that the Vickers microhardness of Inconel 625 alloy is the largest among the four alloys.
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References
Langelier B, Persaud S Y, Korinek A, et al. Effects of boundary migration and pinning particles on intergranular oxidation revealed by 2D and 3D analytical electron microscopy. Acta Mater, 2017, 131: 280–295
Sadeghian Z, Zohari S, Lotfi B, et al. Fabrication and characterization of reactive Ni-Ti-C powder by mechanical alloying. J Alloys Compd, 2014, 589: 157–163
Sah I, Kim D, Lee H J, et al. The recovery of tensile ductility in diffusion-bonded Ni-base alloys by post-bond heat treatments. Mater Des, 2013, 47: 581–589
Ganesh P, Kaul R, Paul C P, et al. Fatigue and fracture toughness characteristics of laser rapid manufactured Inconel 625 structures. Mater Sci Eng-A, 2010, 527: 7490–7497
Ren W, Lu F, Yang R, et al. A comparative study on fiber laser and CO2 laser welding of Inconel 617. Mater Des, 2015, 76: 207–214
Sui S, Tan H, Chen J, et al. The influence of Laves phases on the room temperature tensile properties of Inconel 718 fabricated by powder feeding laser additive manufacturing. Acta Mater, 2019, 164: 413–427
Zhu L, Xu Z, Gu Y. Effect of laser power on the microstructure and mechanical properties of heat treated Inconel 718 superalloy by laser solid forming. J Alloys Compd, 2018, 746: 159–167
Khodabakhshi F, Haghshenas M, Eskandari H, et al. Hardness-strength relationships in fine and ultra-fine grained metals processed through constrained groove pressing. Mater Sci Eng-A, 2015, 636: 331–339
Li H, Ebrahimi F. Synthesis and characterization of electrodeposited nanocrystalline nickel-iron alloys. Mater Sci Eng-A, 2003, 347: 93–101
Zhang P, Li S X, Zhang Z F. General relationship between strength and hardness. Mater Sci Eng-A, 2011, 529: 62–73
Wu J, Li C, Liu Y, et al. Effect of annealing treatment on microstructure evolution and creep behavior of a multiphase Ni3Al-based superalloy. Mater Sci Eng-A, 2019, 743: 623–635
Ma K, Wen H, Hu T, et al. Mechanical behavior and strengthening mechanisms in ultrafine grain precipitation-strengthened aluminum alloy. Acta Mater, 2014, 62: 141–155
Mostafaei A, Toman J, Stevens E L, et al. Microstructural evolution and mechanical properties of differently heat-treated binder jet printed samples from gas- and water-atomized alloy 625 powders. Acta Mater, 2017, 124: 280–289
Zhang M, Liu G Q, Wang H, et al. Stability of γ′ multimodal microstructure in a Ni-based powder metallurgy superalloy. Sci China Tech Sci, 2018, 61: 1824–1828
Lu X, Zhou Y F, Xing X L, et al. Surface additive manufacturing of Ni-based superalloy/H13 steel system by laser depositing: Microstructure, microhardness and flexural response. Surf Coat Tech, 2018, 337: 525–535
Gu D, Shi Q, Lin K, et al. Microstructure and performance evolution and underlying thermal mechanisms of Ni-based parts fabricated by selective laser melting. Addit Manuf, 2018, 22: 265–278
Shi Y, Lu Z, Ren Y, et al. Microstructure and tensile properties of laser engineered net shaped reduced activation ferritic/martensitic steel. Mater Charact, 2018, 144: 554–562
Yan N, Wang Z H, Ruan Y, et al. Solute redistribution and micro-mechanical properties of rapidly solidified multicomponent Ni-based alloys. Sci China Tech Sci, 2019, 62: 472–477
Shi X, Duan S C, Yang W S, et al. Effect of cooling rate on micro-segregation during solidification of superalloy Inconel 718 under slow-cooled conditions. Metall Mater Trans B, 2018, 49: 1883–1897
Wang H P, Yao W J, Wei B. Remarkable solute trapping within rapidly growing dendrites. Appl Phys Lett, 2006, 89: 201905
Wang Q, Chen R, Gong X, et al. Microstructure, mechanical properties, and crack propagation behavior in high-Nb TiAl alloys by directional solidification. Metall Mater Trans A, 2018, 49: 4555–4564
Wang H P, Li M X, Zou P F, et al. Experimental modulation and theoretical simulation of zonal oscillation for electrostatically levitated metallic droplets at high temperatures. Phys Rev E, 2018, 98: 063106
Wang T M, Xu J J, Li J, et al. In situ study on dendrite growth of metallic alloy by a synchrotron radiation imaging technology. Sci China Tech Sci, 2010, 53: 1278–1284
Lü P, Wang H P. Effects of undercooling and cooling rate on peritectic phase crystallization within Ni-Zr alloy melt. Metall Mater Trans B, 2018, 49: 499–508
Oloyede O, Cochrane R F, Mullis A M. Effect of rapid solidification on the microstructure and microhardness of BS1452 grade 250 hypoeutectic grey cast iron. J Alloys Compd, 2017, 707: 347–350
Erol M, Büyük U. Solidification behavior of Ge-Al eutectic alloy in a drop tube. T Indian I Metals, 2015, 69: 961–970
Li M X, Wang H P, Yan N, et al. Heat transfer of micro-droplet during free fall in drop tube. Sci China Tech Sci, 2018, 61: 1021–1030
Levi C G, Mehrabian R. Heat flow during rapid solidification of undercooled metal droplets. Metall Trans-A, 1982, 13: 221–234
Lee E S, Ahn S. Solidification progress and heat transfer analysis of gas-atomized alloy droplets during spray forming. Acta Metall Mater, 1994, 42: 3231–3243
Wu Y H, Chang J, Wang W L, et al. A triple comparative study of primary dendrite growth and peritectic solidification mechanism for undercooled liquid Fe59Ti41 alloy. Acta Mater, 2017, 129: 366–377
Wang H P, Zheng C H, Zou P F, et al. Density determination and simulation of Inconel 718 alloy at normal and metastable liquid states. J Mater Sci Tech, 2018, 34: 436–439
Bogno A, Nguyen-Thi H, Reinhart G, et al. Growth and interaction of dendritic equiaxed grains: In situ characterization by synchrotron X-ray radiography. Acta Mater, 2013, 61: 1303–1315
Gong T Z, Chen Y, Cao Y F, et al. Fast simulations of a large number of crystals growth in centimeter-scale during alloy solidification via nonlinearly preconditioned quantitative phase-field formula. Comput Mater Sci, 2018, 147: 338–352
Zhou S, Hu R, Li J, et al. Stress induced deformation in the solidification of undercooled Co80Pd20 alloys. Mater Sci Eng-A, 2011, 528: 973–977
Li X G, Cao L F, Zhang J Y, et al. Tuning the microstructure and mechanical properties of magnetron sputtered Cu-Cr thin films: The optimal Cr addition. Acta Mater, 2018, 151: 87–99
Theska F, Stanojevic A, Oberwinkler B, et al. On conventional versus direct ageing of Alloy 718. Acta Mater, 2018, 156: 116–124
Zhang D, Niu W, Cao X, et al. Effect of standard heat treatment on the microstructure and mechanical properties of selective laser melting manufactured Inconel 718 superalloy. Mater Sci Eng-A, 2015, 644: 32–40
Wang W L, Wu Y H, Li L H, et al. Homogeneous granular microstructures developed by phase separation and rapid solidification of liquid Fe-Sn immiscible alloy. J Alloys Compd, 2017, 693: 650–657
Zhang C, Cui L, Liu Y, et al. Microstructures and mechanical properties of friction stir welds on 9% Cr reduced activation ferritic/martensitic steel. J Mater Sci Tech, 2018, 34: 756–766
Karthik D, Swaroop S. Laser shock peening enhanced corrosion properties in a nickel based Inconel 600 superalloy. J Alloys Compd, 2017, 694: 1309–1319
Ruan J J, Ueshima N, Oikawa K. Phase transformations and grain growth behaviors in superalloy 718. J Alloys Compd, 2018, 737: 83–91
Bian H, Cui Y, Li Y, et al. The influence of Mo on Suzuki-segregation-related microstructure evolution and mechanical properties of Co-Ni-based superalloy. J Alloys Compd, 2018, 768: 136–142
Zhang B, Cheng J, Liang X. Effects of Cr and Mo additions on formation and mechanical properties of Arc-sprayed FeBSiNb-based glassy coatings. J Non-Cryst Solids, 2018, 499: 245–251
Hu J, Shi Y N, Sauvage X, et al. Grain boundary stability governs hardening and softening in extremely fine nanograined metals. Science, 2017, 355: 1292–1296
Özgün Ö, Özkan Gülsoy H, Yilmaz R, et al. Injection molding of nickel based 625 superalloy: Sintering, heat treatment, microstructure and mechanical properties. J Alloys Compd, 2013, 546: 192–207
Taheri N, Naffakh-Moosavy H, Ghaini F M. A new procedure for refurbishment of power plant Superalloy 617 by pulsed Nd:YAG laser process. Opt Laser Tech, 2017, 91: 71–79
Chandrasekar G, Kailasanathan C, Vasundara M. Investigation on unpeened and laser shock peened dissimilar weldments of Inconel 600 and AISI 316L fabricated using activated-TIG welding technique. J Manuf Process, 2018, 35: 466–478
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This work was supported by the National Natural Science Foundation of China (Grant Nos. 51734008 & 51522102). The authors would like to thank the director of Laboratory of Space Materials Science and Technology (LMSS), Prof. B. Wei, for his consistent support. The authors are grateful to Mr. C. H. Zheng, Mr. B. Zhai, Mr M. X. Li, and Mr. J. F. Zhao for their valuable discussions. The authors also thank Dr. D. L. Gengfor his help on the experiments.
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Liu, W., Yan, N. & Wang, H. Dendritic morphology evolution and microhardness enhancement of rapidly solidified Ni-based superalloys. Sci. China Technol. Sci. 62, 1976–1986 (2019). https://doi.org/10.1007/s11431-019-9519-9
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DOI: https://doi.org/10.1007/s11431-019-9519-9