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A mass and energy estimation for the hydrogen utilization in the iron-making process

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Abstract

The possibility of using hydrogen to lower CO2 emissions in the iron-making process was confirmed by the heat and mass balances in the blast furnace operation. The mass and heat balances for hydrogen utilization in the blast furnace were estimated by using the basic concept of RIST operating diagram. In this study, the RIST operating diagram was modified to be suitable for representing the operation with respect to hydrogen, where the RIST operating diagram is a graphical representation of heat and mass balance in blast furnace operation. RIST operating diagram was applied here to some individual parameters of interest such as H2 injection in blast furnace process to reduce coke (carbon consumption). It was observed that the point W moved to the right in the RIST operating diagram under the condition of increasing hydrogen injection at tuyere, which originates from the contribution of gas composition (O/H2) equilibrated with Fe/FeO at a certain temperature. Point P also moved downward due to heat requirement with respect to hydrogen utilization, by which the new RIST operating diagram for hydrogen utilization was able to be constructed. Under the condition of hydrogen injection, the expected overall carbon consumption in the blast furnace decreased due to the contribution of hydrogen.

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References

  1. Ono Y. Rist operating diagram (II). Tetsu-to-Hagané, 1993, 79: N711–N715

    Google Scholar 

  2. Ujisawa Y, Nakano K, Matsukura Y, et al. Subjects for achievement of blast furnace operation with low reducing agent. ISIJ Int, 2005, 45: 1379–1385

    Article  Google Scholar 

  3. Davis C G, McFarlin J F, Pratt H R, et al. Direct reduction technology and economics. Ironmak Steelmak, 1982, 9: 93–129

    Google Scholar 

  4. Turkdogan E T, Vinters J V. Gaseous reduction of iron oxides: Part I. Reduction of hematite in hydrogen. Met Trans B, 1971, 2: 3175–3188

    Article  Google Scholar 

  5. El-Geassy A A, Shehata K A, Ezz S Y, et al. Mechanism of iron oxide reduction with hydrogen/carbon monoxide mixtures. Trans ISIJ, 1977, 17: 629–635

    Google Scholar 

  6. El-Geassy A A, Rajakumar V. Gaseous reduction of wustite with hydrogen, carbon monoxide, and hydrogen-carbon monoxide mixtures. Trans ISIJ, 1985, 25: 449–458

    Article  Google Scholar 

  7. El-Geassy A A. Gaseous reduction of Fe2O3 compacts at 600 to 1050° C. J Mater Sci, 1986, 21: 3889–3900

    Article  Google Scholar 

  8. Fruehan R J, Li Y, Brabie L, et al. Final stage of reduction of iron ores by hydrogen. Scand J Metall, 2005, 34: 205–212

    Article  Google Scholar 

  9. Lin H Y, Chen Y W, Li C, et al. The mechanism of reduction of iron oxide by hydrogen. Thermochim Acta, 2003, 400: 61–67

    Article  Google Scholar 

  10. Ono-Nakazato H, Yonezawa T, Usui T, et al. Effect of water-gas shift reaction on reduction of iron oxide powder packed bed with H2-CO mixtures. ISIJ Int, 2003, 43: 1502–1511

    Article  Google Scholar 

  11. Pineau A, Kanari N, Gaballah I, et al. Kinetics of reduction of iron oxides by H2 Part I: Low temperature reduction of hematite. Thermochim Acta, 2006, 447: 89–100

    Article  Google Scholar 

  12. Jozwiak W K, Kaczmarek E, Maniecki T P, et al. Reduction behavior of iron oxides in hydrogen and carbon monoxide atmospheres. Appl Catal A, 2007, 326: 17–27

    Article  Google Scholar 

  13. Rist A, Meysson N. A dual graphic representation of blast-furnace mass and heat balances. J Met, 1967, 19: 50–59

    Google Scholar 

  14. Ono Y. Rist operating diagram (I). Tetsu-to-Hagané, 1993, 79: N618–N624

    Google Scholar 

  15. Peacey J G, Davenport W G. The Iron Blast Furnace, Theory and Practice. Pergamon Press, 1979

  16. Turkdogan E T. Physical Chemistry of High Temperature Technology. New York: Academic Press, 1980

    Google Scholar 

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Correspondence to Dong Joon Min.

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Kim, W.H., Min, D.J. A mass and energy estimation for the hydrogen utilization in the iron-making process. Sci. China Technol. Sci. 54, 1655–1660 (2011). https://doi.org/10.1007/s11431-011-4387-z

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  • DOI: https://doi.org/10.1007/s11431-011-4387-z

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