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The important role of the interaction between manganese minerals and metals in environmental remediation: a review

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Abstract

With illegal discharge of wastewater containing inorganic and organic pollutants, combined pollution is common and needs urgent attention. Understanding the migration and transformation laws of pollutants in the environment has important guiding significance for environmental remediation. Due to the characteristics of adsorption, oxidation, and catalysis, manganese minerals play important role in the environment fate of pollutants. This review summarizes the forms of interaction between manganese minerals and metals, the environmental importance of the interaction between manganese minerals and metals, and the contribution of this interaction in improving performance of Mn-based composite for environmental remediation. The literatures have indicated that the interactions between manganese minerals and metals involve in surface adsorption, lattice replacement, and formation of association minerals. The interaction between manganese minerals and metals plays an important role in environmental behavior of element and environmental significance of manganese minerals. The synergistic or antagonistic effect resulted from the interaction influence the purification of heavy metal and organism pollutant. The synergistic effect benefited from the coordination of adsorption and oxidation, convenient electron transfer, abundant oxygen vacancies, and fast migration of lattice oxygen. Based on the synergy, Mn-based composites have been widely used for environmental remediation. The synthesize methods of Mn-based composites mainly include homogeneous coprecipitation, chemical etching route, hydrothermal, homogeneous chelating sol–gel, and ethylene glycol reduction strategy. This review is helpful to fully understand the migration and transformation process of pollutants in the environment, expand the resource utilization of manganese minerals for environmental remediation.

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The datasets used during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors appreciate financial support from the National Natural Science Foundation of China (Grant Nos. 42207254, 41972037, 42172042), the Basic and Applied Basic Research Foundation of Guangdong Province (2021A1515110371, 2019B1515120015), Guangdong Special Support Program for Local Innovative and Research Teams Project (2019BT02L218), the Guangzhou Science and Technology Program (202206010055), the Guangdong Science and Technology Program (2020B121201003), and China postdoctoral science foundation (2022M711191).

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  1. School of Environment and Energy, South China University of Technology, Guangzhou, 510006, People’s Republic of China

    Meiqing Chen, Jiayan Wu, Xiaoshan Qiu, Lu Jiang & Pingxiao Wu

  2. The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou, 510006, People’s Republic of China

    Meiqing Chen, Jiayan Wu, Xiaoshan Qiu, Lu Jiang & Pingxiao Wu

  3. Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, Guangzhou, 510006, People’s Republic of China

    Pingxiao Wu

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All authors contributed to the study conception and design. References collection and analysis were performed by Meiqing Chen, Jiayan Wu, Xiaoshan Qiu and Jiang Lu. The first draft of the manuscript was written by Meiqing Chen and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Chen, M., Wu, J., Qiu, X. et al. The important role of the interaction between manganese minerals and metals in environmental remediation: a review. Environ Sci Pollut Res 30, 39319–39337 (2023). https://doi.org/10.1007/s11356-023-25575-8

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