Abstract
Phosphogypsum (PG) is one of solid wastes with large amount of yield and serious pollution, which has attracted wide attention. The aim of this study is to investigate filling performance of PG on polypropylene (PP) or high-density polyethylene (HDPE) matrix. In this work, PG was calcined initially to improve whiteness and fix impurities. X-ray diffraction (XRD) results showed that after calcined at 500 °C, the PG phase changed from CaSO4·2H2O to CaSO4. The modification effects of the three modifiers were evaluated by Fourier transform infrared spectra (FTIR), oil absorption value, water floatability, and contact angle analysis. The effects of weight fraction of PG in PP and HDPE matrix on mechanics and morphology were observed by tensile test, impact test, and scanning electron microscope. Scanning electron microscope (SEM) showed that modified PG can be dispersed uniformly in the matrix at low filling content. With the increase of PG filling content, the analysis of mechanical properties showed that the tensile strength of HDPE matrix increased, while the tensile strength of PP matrix decreased gradually. The impact strength of HDPE matrix would decrease, but the impact strength of PP matrix increased first and then decreased. Compared with calcium carbonate (CC), the mechanical properties of HDPE filled with PG performed better. The apparent density showed that polymer composites filled with PG have the characteristics of light weight.
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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
Bai YX, Wu PL, Liu J, Zhu YQ (2009) Study on circulating washing process of phosphogypsum. Chem Fertil Ind 36:34–36. https://doi.org/10.3969/j.issn.1006-7779.2009.01.009
Cai Q, Jiang J, Ma B, Shao ZY, Hu YY, Qian BB, Wang LM (2021) Efficient removal of phosphate impurities in waste phosphogypsum for the production of cement. Sci Total Environ 780:146600. https://doi.org/10.1016/j.scitotenv.2021.146600
Cánovas CR, Chapron S, Arrachart G, Pellet-Rostaing S (2019) Leaching of rare earth elements (REEs) and impurities from phosphogypsum: a preliminary insight for further recovery of critical raw materials. J Clean Prod 219:225–235. https://doi.org/10.1016/j.jclepro.2019.02104
Chen QS, Zhang QL, Fourie A, Xin C (2017) Utilization of phosphogypsum and phosphate tailings for cemented paste backfill. J Environ Manage 201:19–27. https://doi.org/10.1016/j.jenvman.2017.06027
Chen QS, Zhang QL, Qi CC, Fourie A, Xiao CC (2018) Recycling phosphogypsum and construction demolition waste for cemented paste backfill and its environmental impact. J Clean Prod 186:418–429. https://doi.org/10.1016/j.jclepro.2018.03131
Denev YG, Denev GD, Popov AN (2009) Surface modification of phosphogypsum used as reinforcing material in polyethylene composites. J Elastomers Plast 41:119–132. https://doi.org/10.1177/0095244308092436
Ding WJ, Chen QJ, Sun HJ, Peng TJ (2019) Modified phosphogypsum sequestrating CO2 and characteristics of the carbonation product. Energy (oxford) 182:224–235. https://doi.org/10.1016/j.energy.2019.05220
Dong FQ, Huang ZY, Tan HB, Wu CL, He P (2016) Effect of additives on calcium sulfate hemihydrate whiskers morphology from calcium sulfate dehydrate and phosphogypsum. Mater Manuf Processes 31:2037–2043. https://doi.org/10.1080/10426914.2016.1176184
Essabir H, Nekhlaoui S, Bensalah MO, Rodrigue D, Bouhfid R, Aek Q (2016) Phosphogypsum waste used as reinforcing fillers in polypropylene based composites: structural, mechanical and thermal properties. J Polym Environ 25:658–666. https://doi.org/10.1007/s10924-016-0853-9
Fu QQ, Shen YH, Chen HK, Xu HJ, Liu Y (2020) Present situation and suggestions of comprehensive utilization of phosphogypsum. Phosphate Fertil Compd Fertil 35(8):44–46
He HW, Li KX, Wang J, Sun GH, Li YQ, Wang JL (2011) Study on thermal and mechanical properties of nano-calcium carbonate/epoxy composites. Mater Eng 32:4521–4527. https://doi.org/10.1016/j.matdes.2011.03026
He Q, Zhang QQ, Chen Y, Fang WC (2018) Phosphogypsum calcination technology and problems needing attention. New Build Mater 45:49–52. https://doi.org/10.3969/j.issn.1001-702X.2018.10013
Kaya N, Atagur M, Akyuz O, Seki Y, Sarikanat M, Sutcu M, Seydibeyoglu MO, Sever K (2018) Fabrication and characterization of olive pomace filled PP composites. Compos B Eng 150:277–283. https://doi.org/10.1016/j.compositesb.2017.08017
Kulczycka J, Kowalski Z, Smol M, Wirth H (2016) Evaluation of the recovery of rare earth elements (REE) from phosphogypsum waste — case study of the WIZÓW chemical plant (Poland). J Clean Prod 113:345–354. https://doi.org/10.1016/j.jclepro.2015.11039
Li Y, Luo WH, Li GX, Wang K, Gong XY (2018) Performance of phosphogypsum and calcium magnesium phosphate fertilizer for nitrogen conservation in pig manure composting. Biores Technol 250:53–59. https://doi.org/10.1016/j.biortech.2017.07172
Li JM, Wang GX, Zhou XY (2019) Process selection and key equipment selection for phosphogypsum pretreatment. Phosphate Fertil Compd Fertil 34:23–25. https://doi.org/10.3969/j.issn.1007-6220.201907.009
Lin Y, Chen HB, Chan CM, Wu JS (2010) The toughening mechanism of polypropylene/calcium carbonate nanocomposites. Polymer (guilford) 51:3277–3284. https://doi.org/10.1016/j.polymer.2010.04047
Liu DS, Wang CQ, Mei XD, Zhang C (2019) An effective treatment method for phosphogypsum. Environ Sci Pollut Res Int 26:30533–30539. https://doi.org/10.1007/s11356-019-06113-x
Liu SH, Fang PP, Ren J, Li SF (2020) Application of lime neutralised phosphogypsum in supersulfated cement. J Clean Prod 272:122660. https://doi.org/10.1016/j.jclepro.2020.122660
Liu SH, Ouyang JY, Ren J (2020) Mechanism of calcination modification of phosphogypsum and its effect on the hydration properties of phosphogypsum-based supersulfated cement. Constr Build Mater 243:118226. https://doi.org/10.1016/j.conbuildmat.2020.118226
Luo WS, Wang YY, Yang G (2020) Composite titanate and its effect on the properties of ultrafine calcium carbonate/PP composites. J Nanchang Aviat Univ (nat Sci Ed) 34:53–60
Matveeva VA, Smirnov YD, Suchkov DV (2021) Industrial processing of phosphogypsum into organomineral fertilizer. Environ Geochem Health. https://doi.org/10.1007/s10653-021-00988-x
Muraleedharan M, Nadir Y (2021) Factors affecting the mechanical properties and microstructure of geopolymers from red mud and granite waste powder: a review. Ceram Int 47:13257–13279. https://doi.org/10.1016/j.ceramint.2021.02.009
Pan Y (2015) Experimental study on modification of natural gypsum and filling resin Master. Wuhan University of Engineering
Rashad AM (2017) Phosphogypsum as a construction material. J Clean Prod 166:732–743. https://doi.org/10.1016/j.jclepro.2017.08049
Rychkov VN, Kirillov EV, Kirillov SV, Semenishchev VS, Bunkov GM, Botalov MS, Smyshlyaev DV, Malyshev AS (2018) Recovery of rare earth elements from phosphogypsum. J Clean Prod 196:674–681. https://doi.org/10.1016/j.jclepro.2018.06114
Shan CY, Zhang K, Long LJ, Xiang YX, Huang SW, Li J (2020) Properties of polypropylene/phosphogypsum composites. Appl Eng Plast 48:11–15. https://doi.org/10.3969/j.issn.1001-3539.2020.12003
Shi Y, Cheng L, Tao M, Tong SS, Yao XJ, Liu YF (2021) Using modified quartz sand for phosphate pollution control in cemented phosphogypsum (PG) backfill. Journal of Cleaner Production 283. https://doi.org/10.1016/j.jclepro.2020.124652
Sun HX, Qi YL, Zhang J (2020) Surface organic modified magnesium titanate particles with three coupling agents: characterizations, properties and potential application areas. Appl Surf Sci 520:146322. https://doi.org/10.1016/j.apsusc.2020.146322
Syczewski MD, Borkowski A, Gąsiński A, Raczko J, Mordak K, Grądziel I, Krzesicka M, Kałaska M, Siuda R (2020) Phosphogypsum and clay mineral/phosphogypsum ceramic composites as useful adsorbents for uranium uptake. Appl Geochem 123:104793. https://doi.org/10.1016/j.apgeochem.2020.104793
Tanniru M, Yuan Q, Misra RDK (2006) On significant retention of impact strength in clay-reinforced high-density polyethylene (HDPE) nanocomposites. Polymer (guilford) 47:2133–2146. https://doi.org/10.1016/j.polymer.2006.01.063
Tian T, Yan Y, Hu ZH, Xu YY, Chen YP, Shi J (2016) Utilization of original phosphogypsum for the preparation of foam concrete. Constr Build Mater 115:143–152. https://doi.org/10.1016/j.conbuildmat.2016.04.028
Wang JM, Dong FQ, Wang ZJ, Yang FH, Du MX, Wang Z (2020) A novel method for purification of phosphogypsum. Physicochem Probl Miner Process 56:975–983. https://doi.org/10.37190/PPMP/127854
Zhang J, Zou HT (2018) Modification and application of phosphogypsum. Guangdong Chemical Industry 45:63–66. https://doi.org/10.3969/j.issn.1007-1865.2018.22030
Zhang H, Chai WC, Cao YJ (2022) Flotation separation of quartz from gypsum using benzyl quaternary ammonium salt as collector. Appl Surf Sci 576:151834. https://doi.org/10.1016/j.apsusc.2021.151834
Zhao HT, Bao WJ, Sun ZH, Li SG, Li HQ, Lin WG (2017) Deep removal technology of impurities in phosphogypsum. Chem Ind Eng Prog 36:1240–1246. https://doi.org/10.16085/j.issn.1000-6613.2017.04.012
Zhao HY, Song Q, Liu SC, Li YH, Wang XH, Shu XQ (2018) Study on catalytic co-pyrolysis of physical mixture/staged pyrolysis characteristics of lignite and straw over an catalytic beds of char and its mechanism. Energy Convers Manage 161:13–26. https://doi.org/10.1016/j.enconman.2018.01.083
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Financial support was provided by Engineering Research Center of Non-metallic Minerals of Zhejiang Province (ZD2020K01) and Technology Program of ZJUT (KYY-HX-20200382).
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Min Sun: experiment, writing original draft. Qing Sun: conceptualization, data curation, revising, funding acquisition. Jian Zhang: resources. Jiawei Sheng: project administration, review and editing, funding.
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Sun, M., Sun, Q., Zhang, J. et al. Surface modification of phosphogypsum and application in polyolefin composites. Environ Sci Pollut Res 29, 66177–66190 (2022). https://doi.org/10.1007/s11356-022-20414-8
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DOI: https://doi.org/10.1007/s11356-022-20414-8