Abstract
α-Fe2O3 nanoparticles were synthesized via a straightforward method. XRD, FTIR, SEM, ESR, and DRS techniques investigated the influence of various calcination temperatures on the crystal structure, optical, and photocatalytic properties of the samples. The obtained results demonstrated that the average crystallite size increased with the increase in the calcination temperature. Measured and computed optical properties were in accordance and the bandgap energy decreased with the increase in the calcination temperature. The highest photocatalytic degradation efficiency for diclofenac (DCF) was obtained with the sample calcinated at 300 °C (96%). The photocatalytic process occurs because of the presence of OH• radicals. The addition of H2O2 led to the inhibition of OH• radicals that H2O2 scavenged.
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Data supporting the findings are available from the corresponding author upon reasonable request.
References
Ali AS, Khan I, Zhang B, Nomura K, Homonnay Z, Kuzmann E, Scrimshire A, Bingham PA, Krehula S, Musić S, Akiyama K, Kubuki S (2020) Photo-Fenton degradation of methylene blue using hematite-enriched slag under visible light. J Radioanal Nucl Chem 325:537–549. https://doi.org/10.1007/s10967-020-07238-x
Amadine O, Essamlali Y, Fihri A, Larzek M, Zahouily M (2017) Effect of calcination temperature on the structure and catalytic performance of copper-ceria mixed oxide catalysts in phenol hydroxylation. RSC Adv 7:12586–12597. https://doi.org/10.1039/c7ra00734e
Barebita H, Naciri Y, Ferraa S, Nimour A, Guedira T (2020) Investigation of structural and photocatalytic behavior of Bi13B1-2xVxPxO20.95+2x (0 ≤ x ≤ 0.5). Solid State Sci 108:106389. https://doi.org/10.1016/J.SOLIDSTATESCIENCES.2020.106389
Karlheinz B, Schwarz Georg H, Dieter M, Joachim K, Robert L, Fabien L, Tran Laurence D, Marks PK, Blaha P, Schwarz K, et al. (2019) An augmented plane wave plus local orbitals program for calculating crystal properties
Bouziani A, Park J, Ozturk A (2020) Synthesis of α-Fe2O3/TiO2 heterogeneous composites by the sol-gel process and their photocatalytic activity. J Photochem Photobiol A Chem 400:112718. https://doi.org/10.1016/j.jphotochem.2020.112718
Council of the European Communities (2013) Directive 2013/39/EU of the European Parliament and of the Council of 12 August 2013 amending Directives 2000/60/EC and 2008/105/EC as regards priority substances in the field of water policy
Domacena AMG, Aquino CLE, Balela MDL (2020) Photo-Fenton degradation of methyl orange using hematite (α-Fe2O3) of various morphologies. In: Materials today: Proceedings. Elsevier Ltd, pp 248–254
Essekri A, Hsini A, Naciri Y, Laabd M, Ajmal Z, el Ouardi M, Ait Addi A, Albourine A (2020) Novel citric acid-functionalized brown algae with a high removal efficiency of crystal violet dye from colored wastewaters: insights into equilibrium, adsorption mechanism, and reusability. https://doi.org/10.1080/15226514.2020.1813686, 23, 336, 346
Fathima Beevi A, Sreekala G, Beena B (2021) Synthesis, characterization and photocatalytic activity of SnO2, ZnO nanoparticles against congo red: a comparative study. Mater Today Proc 45:4045–4051. https://doi.org/10.1016/J.MATPR.2020.10.755
Ferraa S, Naciri Y, Hsini A, Barebita H, Bouziani A, Albourine A, Nimour A, Guedira T (2021) Evolution of the physicochemical and photocatalytic properties of BaO embedded in bismuth phosphovanadates glasses. Chem Phys Lett 763:138173. https://doi.org/10.1016/J.CPLETT.2020.138173
Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nat 238:37–38. https://doi.org/10.1038/238037a0
Guo Y, Zhang G, Liu J, Zhang Y (2013) Hierarchically structured α-Fe2O3/Bi 2WO6 composite for photocatalytic degradation of organic contaminants under visible light irradiation. RSC Adv 3:2963–2970. https://doi.org/10.1039/c2ra22741j
Hsini A, Benafqir M, Naciri Y, Laabd M, Bouziani A, Ez-zahery M, Lakhmiri R, Alem NE, Albourine A (2021a) Synthesis of an arginine-functionalized polyaniline@FeOOH composite with high removal performance of hexavalent chromium ions from water: adsorption behavior, regeneration and process capability studies. Colloids Surfaces A Physicochem Eng Asp 617:126274. https://doi.org/10.1016/J.COLSURFA.2021.126274
Hsini A, Naciri Y, Laabd M, Bouziani A, Navío JA, Puga F, Boukherroub R, Lakhmiri R, Albourine A (2021b) Development of a novel PANI@WO3 hybrid composite and its application as a promising adsorbent for Cr(VI) ions removal. J Environ Chem Eng 9:105885. https://doi.org/10.1016/J.JECE.2021.105885
Ibukun O, Evans PE, Dowben PA, Kyung Jeong H (2019) Titanium dioxide-molybdenum disulfide for photocatalytic degradation of methylene blue. Chem Phys 525:110419. https://doi.org/10.1016/j.chemphys.2019.110419
Ilmetov R (2018) Photocatalytic activity of hematite nanoparticles prepared by sol-gel method. In: Materials today: Proceedings. Elsevier Ltd, pp 11–14
Imgharn A, Ighnih H, Hsini A et al (2021) Synthesis and characterization of polyaniline-based biocomposites and their application for effective removal of Orange G dye using adsorption in dynamic regime. Chem Phys Lett 778:138811. https://doi.org/10.1016/J.CPLETT.2021.138811
Jaramillo-Páez C, Navío JA, Hidalgo MC, Bouziani A, Azzouzi ME (2017) Mixed α-Fe2O3/Bi2WO6 oxides for photoassisted hetero-Fenton degradation of methyl orange and phenol. J Photochem Photobiol A Chem 332:521–533. https://doi.org/10.1016/j.jphotochem.2016.09.031
Khan KM, Albano EV (2002) Catalytic oxidation of carbon monoxide: a lattice gas non-thermal Langmuir-Hinshelwood mechanism. Chem Phys 276:129–137. https://doi.org/10.1016/S0301-0104(01)00574-2
Liu J, Wang B, Li Z, Wu Z, Zhu K, Zhuang J, Xi Q, Hou Y, Chen J, Cong M, Li J, Qian G, Lin Z (2019a) Photo-Fenton reaction and H2O2 enhanced photocatalytic activity of α-Fe2O3 nanoparticles obtained by a simple decomposition route. J Alloys Compd 771:398–405. https://doi.org/10.1016/j.jallcom.2018.08.305
Liu J, Yang H, Xue X (2019b) Preparation of different shaped α-Fe2O3 nanoparticles with large particles of iron oxide red. CrystEngComm 21:1097–1101. https://doi.org/10.1039/c8ce01920g
Malviya KD, Dotan H, Shlenkevich D, Tsyganok A, Mor H, Rothschild A (2016) Systematic comparison of different dopants in thin film hematite (α-Fe2O3) photoanodes for solar water splitting. J Mater Chem A 4:3091–3099. https://doi.org/10.1039/c5ta07095c
Mansour AM (2015) Photocatalytic degradation of methylene blue with hematite nanoparticles synthesized by thermal decomposition of fluoroquinolones oxalato-iron(III) complexes. RSC Adv 5:62052–62061. https://doi.org/10.1039/c5ra12157d
Mehinto AC, Hill EM, Tyler CR (2010) Uptake and biological effects of environmentally relevant concentrations of the nonsteroidal anti-inflammatory pharmaceutical diclofenac in rainbow trout (oncorhynchus mykiss). Environ Sci Technol 44:2176–2182. https://doi.org/10.1021/es903702m
Miao Z, Tao S, Wang Y, Yu Y, Meng C, An Y (2013) Hierarchically porous silica as an efficient catalyst carrier for high performance vis-light assisted Fenton degradation. Microporous Mesoporous Mater 176:178–185. https://doi.org/10.1016/j.micromeso.2013.04.009
Mishra M, Chun DM (2015) α-Fe2O3 as a photocatalytic material: a review. Appl. Catal. A Gen. 498:126–141
Naciri Y, Ait Ahsaine H, Chennah A, Amedlous A, Taoufyq A, Bakiz B, Ezahri M, Villain S, Benlhachemi A (2018) Facile synthesis, characterization and photocatalytic performance of Zn3(PO4)2 platelets toward photodegradation of rhodamine B dye. J Environ Chem Eng 6:1840–1847. https://doi.org/10.1016/J.JECE.2018.02.009
Naciri Y, Bouddouch A, Bakiz B, Taoufyq A, Ezahri M, Benlhachemi A (2020a) Photocatalytic degradation of sulfadiazine by Zn3(PO4)2/BiPO4 composites upon UV light irradiation. Mater Today Proc 22:48–51. https://doi.org/10.1016/J.MATPR.2019.08.071
Naciri Y, Hsini A, Ajmal Z, Navío JA, Bakiz B, Albourine A, Ezahri M, Benlhachemi A (2020b) Recent progress on the enhancement of photocatalytic properties of BiPO4 using π-conjugated materials. Adv Colloid Interface Sci 280:102160. https://doi.org/10.1016/J.CIS.2020.102160
Naciri Y, Hsini A, Ajmal Z, Bouddouch A, Bakiz B, Navío JA, Albourine A, Valmalette JC, Ezahri M, Benlhachemi A (2020c) Influence of Sr-doping on structural, optical and photocatalytic properties of synthesized Ca3(PO4)2. J Colloid Interface Sci 572:269–280. https://doi.org/10.1016/J.JCIS.2020.03.105
Naciri Y, Hsini A, Ajmal Z, Bouddouch A, Bakiz B, Navío JA, Albourine A, Valmalette JC, Ezahri M, Benlhachemi A (2020d) Influence of Sr-doping on structural, optical and photocatalytic properties of synthesized Ca3(PO4)2. J Colloid Interface Sci 572:269–280. https://doi.org/10.1016/j.jcis.2020.03.105
Omrani N, Nezamzadeh-Ejhieh A, Alizadeh M (2019) Brief study on the kinetic aspect of photodegradation of sulfasalazine aqueous solution by cuprous oxide/cadmium sulfide nanoparticles. Desalin Water Treat. 162:290–302. https://doi.org/10.5004/dwt.2019.24352
Ouyang S, Ye J (2011) β-AgAl1-xGaxO2 solid-solution photocatalysts: continuous modulation of electronic structure toward high-performance visible-light photoactivity. J Am Chem Soc 133:7757–7763. https://doi.org/10.1021/ja110691t
Pastrana-Martínez LM, Pereira N, Lima R, Faria JL, Gomes HT, Silva AMT (2015) Degradation of diphenhydramine by photo-Fenton using magnetically recoverable iron oxide nanoparticles as catalyst. Chem Eng J 261:45–52. https://doi.org/10.1016/j.cej.2014.04.117
Piazzesi G, Nicosia D, Devadas M, Kröcher O, Elsener M, Wokaun A (2007) Investigation of HNCO adsorption and hydrolysis on Fe-ZSM5. Catal Letters 115:33–39. https://doi.org/10.1007/s10562-007-9072-2
Pourshirband N, Nezamzadeh-Ejhieh A, Nezamoddin Mirsattari S (2020) The CdS/g-C3N4 nano-photocatalyst: brief characterization and kinetic study of photodegradation and mineralization of methyl orange. Spectrochim Acta Part A Mol Biomol Spectrosc 119110:119110. https://doi.org/10.1016/j.saa.2020.119110
Rabindranathan S, Devipriya S, Yesodharan S (2003) Photocatalytic degradation of phosphamidon on semiconductor oxides. J Hazard Mater 102:217–229. https://doi.org/10.1016/S0304-3894(03)00167-5
Ravina M, Campanella L, Kiwi J (2002) Accelerated mineralization of the drug diclofenac via Fenton reactions in a concentric photo-reactor. Water Res 36:3553–3560. https://doi.org/10.1016/S0043-1354(02)00075-1
Ruan HD, Frost RL, Kloprogge JT (2001) The behavior of hydroxyl units of synthetic goethite and its dehydroxylated product hematite. Spectrochim Acta - Part A Mol Biomol Spectrosc 57:2575–2586. https://doi.org/10.1016/S1386-1425(01)00445-0
Sajjad AKL, Shamaila S, Tian B, Chen F, Zhang J (2010) Comparative studies of operational parameters of degradation of azo dyes in visible light by highly efficient WOx/TiO2 photocatalyst. J Hazard Mater 177:781–791. https://doi.org/10.1016/j.jhazmat.2009.12.102
Sherman D, Waite T, Sherman DM (1985) Electronic-spectra of Fe-3+ oxides and oxide hydroxides in the near IR to near UV. Am Mineral 70:1262–1269
Shinde PS, Go GH, Lee WJ (2012) Facile growth of hierarchical hematite (α-Fe2O3) nanopetals on FTO by pulse reverse electrodeposition for photoelectrochemical water splitting. J Mater Chem 22:10469–10471. https://doi.org/10.1039/c2jm31254a
Show B, Mukherjee N, Mondal A (2016) α-Fe2O3 nanospheres: facile synthesis and highly efficient photo-degradation of organic dyes and surface activation by nano-Pt for enhanced methanol sensing. RSC Adv 6:75347–75358. https://doi.org/10.1039/c6ra13385a
Sivula K, Le Formal F, Grätzel M (2011) Solar water splitting: progress using hematite (α-Fe 2O3) photoelectrodes. ChemSusChem 4:432–449
Tran F, Blaha P (2009) Accurate band gaps of semiconductors and insulators with a semilocal exchange-correlation potential. Phys Rev Lett 102:226401. https://doi.org/10.1103/PhysRevLett.102.226401
Tsedenbal B, Hussain I, Anwar MS, Koo BH (2018) Morphological, magnetic and optical properties of α-Fe2O3 nanoflowers. J Nanosci Nanotechnol 18:6127–6132. https://doi.org/10.1166/jnn.2018.15614
Verlicchi P, Al Aukidy M, Zambello E (2012) Occurrence of pharmaceutical compounds in urban wastewater: removal, mass load and environmental risk after a secondary treatment-a review. Sci. Total Environ. 429:123–155
Vogna D, Marotta R, Napolitano A, Andreozzi R, d’Ischia M (2004) Advanced oxidation of the pharmaceutical drug diclofenac with UV/H2O2 and ozone. Water Res 38:414–422. https://doi.org/10.1016/j.watres.2003.09.028
Wang H, Geng WC (2011) Preparation of monodispersed α-Fe2O3 nanoparticles by a hydrothermal synthetic route. In: Research on chemical intermediates. Springer, pp 523–529
Zhang N, Liu G, Liu H, Wang Y, He Z, Wang G (2011) Diclofenac photodegradation under simulated sunlight: effect of different forms of nitrogen and kinetics. J Hazard Mater 192:411–418. https://doi.org/10.1016/j.jhazmat.2011.05.038
Zhang X, Ai Z, Jia F, Zhang L (2008) Generalized one-pot synthesis, characterization, and photocatalytic activity of hierarchical BiOX (X = Cl, Br, I) nanoplate microspheres. J Phys Chem C 112:747–753. https://doi.org/10.1021/jp077471t
Zhang Z, Hossain MF, Takahashi T (2010) Fabrication of shape-controlled α-Fe2O3 nanostructures by sonoelectrochemical anodization for visible light photocatalytic application. Mater Lett 64:435–438. https://doi.org/10.1016/j.matlet.2009.10.071
Zhao J, Yang P, Chen HS, Li J, Che Q, Zhu Y, Shi R (2015) Effect of sequential morphology adjustment of hematite nanoplates to nanospindles on their properties and applications. J Mater Chem C 3:2539–2547. https://doi.org/10.1039/c4tc02752c
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M. Boujnah thanks DGAPA-UNAM for the postdoctoral fellowship.
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Ibtihal Mamoni: formal analysis, investigation, data curation, writing—original draft. Asmae Bouziani: conceptualization, validation, writing—review and editing. Yassine Naciri: writing—review and editing. Mourad Boujnah: theoretical calculation. Mohammed Alaoui El Belghiti: supervision. Mohammed El Azzouzi: conceptualization, validation, supervision.
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Mimouni, ., Bouziani, A., Naciri, Y. et al. Effect of heat treatment on the photocatalytic activity of α-Fe2O3 nanoparticles: towards diclofenac elimination. Environ Sci Pollut Res 29, 7984–7996 (2022). https://doi.org/10.1007/s11356-021-16146-w
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DOI: https://doi.org/10.1007/s11356-021-16146-w