Abstract
Compression ignition engines powered by diesel are the work horses of developing countries like India. However, burning fossil fuel causes a lot of air pollution and the depletion of fuel at an alarming rate. Fuels produced from biomass or wastes can partially substitute fossil diesel to decrease its consumption. One such feedstock is waste cooking oil (WCO) which can be easily converted into fuel for diesel engines. The hydrotreating process stands out among the methods available for converting WCO into fuel, since its properties are almost similar to fossil diesel with little or no oxygen content. In this study, the physico-chemical properties of the hydrotreated waste cooking oil (HVO), biodiesel of waste cooking oil, diesel and blends of HVO and diesel are compared. The blends were prepared by mixing 10%, 20%, 30%, 40% and 50% of HVO on volume basis in diesel. The evaporation rate and ignition probability of the fuel samples were found by using a hot-plate test setup. HVO had higher ignition probability than all the test sample. As the percentage of HVO increased in the test samples, the ignition probability increased. The Sauter mean diameter (SMD) of the samples was also found using Malvern Spraytec. The SMD of HVO was larger than diesel but smaller than biodiesel. The study shows that blends of HVO up to 30% are feasible for present use in diesel engines, as the viscosity (2.54, 2.59 and 2.62cSt) and calorific value (42.41, 42.29, 42.08 MJ/kg) of the three blends (10%, 20% and 30%) is close to diesel (2.51cSt and 42.58 MJ/kg). Also, due to high cetane index, neat HVO or blends having higher HVO content (> 30%) cannot be used in the existing engines as the engine power output may be affected. Therefore, to use these fuels, the engine needs to be modified which is not feasible for existing engines. The FTIR and GC-MS analysis shows that the HVO has low oxygen content and high amount of paraffins, whereas biodiesel of waste cooking oil has high unsaturation and high oxygen content.
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References
Abu-Zaid M (2004) An experimental study of the evaporation characteristics of emulsified liquid droplets. Heat Mass Transf 40(9):737–741. https://doi.org/10.1007/s00231-003-0473-5
Ahlawat V, Gupta M, Anand S, Bansal V, Jain V, Kumar N (2013) Evaluation of performance and emission characteristics of an unmodified naturally aspirated compression ignition engine on blends of diethyl ether and diesel. In 8th SAEINDIA International Mobility Conference & Exposition and Commercial Vehicle Engineering Congress 2013 (SIMCOMVEC). SAE International. https://doi.org/10.4271/2013-01-2888
Alwi A, Zulkifli NW, Sukiman NL, Yusoff A, Zakaria Z, Jamshaid M, Hasnul MH, Amzar MS (2019) Evaluation of engine performance and exhaust emission characteristics in a diesel engine using isobutanol—Calophyllum inophyllumbiodiesel—diesel ternary blends. Environ Sci Pollut Res 26(12):11815–11826. https://doi.org/10.1007/s11356-019-04603-6
Arifin YM, Arai M (2010) The effect of hot surface temperature on diesel fuel deposit formation. Fuel 89(5):934–942. https://doi.org/10.1016/j.fuel.2009.07.014
Arifin YM, Furuhata T, Saito M, Arai M (2008) Diesel and bio-diesel fuel deposits on a hot surface. Fuel 87(8):1601–1609. https://doi.org/10.1016/j.fuel.2007.07.030
Arslan R, Ulusoy Y (2018) Utilization of waste cooking oil as an alternative fuel for Turkey. Environ Sci Pollut Res 25(25):24520–24525. https://doi.org/10.1007/s11356-017-8899-3
Bacha J, Freel J, et al. (2007)Diesel fuels technical review. San Ramon, CA. Retrieved from https://www.chevron.com/-/media/chevron/operations/documents/diesel-fuel-tech-review.pdf
Bennett M (2001) Ignition of combustible fluids by heated surfaces. Process Saf Prog 10(1):29–36
Bezergianni S, Dimitriadis A (2013) Temperature effect on co-hydroprocessing of heavy gas oil-waste cooking oil mixtures for hybrid diesel production. Fuel 103:579–584. https://doi.org/10.1016/j.fuel.2012.08.006
Bezergianni S, Dimitriadis A, Kalogianni A, Pilavachi PA (2010) Hydrotreating of waste cooking oil for biodiesel production. Part I: effect of temperature on product yields and heteroatom removal. Bioresour Technol 101(17):6651–6656. https://doi.org/10.1016/j.biortech.2010.03.081
Bezergianni S, Dimitriadis A, Kalogianni A, Knudsen KG (2011) Toward hydrotreating of waste cooking oil for biodiesel production, effect of pressure, H2/oil ratio, and liquid hourly space velocity. Ind Eng Chem Res 50(7):3874–3879. https://doi.org/10.1021/ie200251a
Bezergianni S, Kalogianni A, Dimitriadis A (2012) Catalyst evaluation for waste cooking oil hydroprocessing. Fuel 93:638–641. https://doi.org/10.1016/j.fuel.2011.08.053
Bezergianni S, Dimitriadis A, Chrysikou LP (2014) Quality and sustainability comparison of one- vs. Two-step catalytic hydroprocessing of waste cooking oil. Fuel 118:300–307. https://doi.org/10.1016/j.fuel.2013.10.078
Bhuiya MMK, Rasul MG, Khan MMK, Ashwath N, Azad AK, Hazrat MA (2016) Prospects of 2nd generation biodiesel as a sustainable fuel – part 2: properties, performance and emission characteristics. Renew Sust Energ Rev 55:1129–1146. https://doi.org/10.1016/J.RSER.2015.09.086
Boopathi D, Sonthalia A, Devanand S (2017) Experimental investigations on the effect of hydrogen induction on performance and emission behaviour of a single cylinder diesel engine fuelled with palm oil methyl ester and its blend with diesel. J Eng Sci Technol 12(7):1972–1984
Cengel Y, Turner R (2017) Fundamentals of thermal fluid sciences (fourth). Mc-Graw Hill Education, New York
Daho T, Vaitilingom G, Ouiminga SK, Piriou B, Zongo AS, Ouoba S, Koulidiati J (2013) Influence of engine load and fuel droplet size on performance of a CI engine fueled with cottonseed oil and its blends with diesel fuel. Appl Energy 111:1046–1053. https://doi.org/10.1016/j.apenergy.2013.05.059
Damanik N, Ong HC, Tong CW, Mahlia TMI, Silitonga AS (2018) A review on the engine performance and exhaust emission characteristics of diesel engines fueled with biodiesel blends. Environ Sci Pollut Res 25(16):15307–15325. https://doi.org/10.1007/s11356-018-2098-8
Demirbas A, Dincer K (2008) Sustainable green diesel: a futuristic view. Energy Sources Part A 30(13):1233–1241. https://doi.org/10.1080/15567030601082829
Ejim CE, Fleck BA, Amirfazli A (2007) Analytical study for atomization of biodiesels and their blends in a typical injector: surface tension and viscosity effects. Fuel 86(10–11):1534–1544. https://doi.org/10.1016/J.FUEL.2006.11.006
Geo VE, Sonthalia A, Nagarajan G, Nagalingam B (2017) Studies on performance, combustion and emission of a single cylinder diesel engine fuelled with rubber seed oil and its biodiesel along with ethanol as injected fuel. Fuel 209:733–741. https://doi.org/10.1016/j.fuel.2017.08.036
Heywood JB (1988) Internal combustion engine fundamentals. Mc-Graw Hill
Hribernik A, Kegl B (2009) Performance and exhaust emissions of an indirect-injection ( IDI ) diesel engine when using waste cooking oil as fuel. Energy Fuel 23:1754–1758
Karmakar A, Karmakar S, Mukherjee S (2012) Biodiesel production from neem towards feedstock diversification: Indian perspective. Renew Sust Energ Rev 16(1):1050–1060. https://doi.org/10.1016/J.RSER.2011.10.001
Kiss AA, Dimian AC, Rothenberg G (2006) Solid acid catalysts for biodiesel production –-towards sustainable energy. Advanced Synthesis & Catalysis 348(1–2):75–81. https://doi.org/10.1002/adsc.200505160
Kiss AA, Dimian AC, Rothenberg G (2008) Biodiesel by catalytic reactive distillation powered by metal oxides. Energy Fuel 22(1):598–604. https://doi.org/10.1021/ef700265y
Kline SJ, McClintock FA (1953) Describing uncertainties in single sample experiments. Mech Eng:3–8. https://doi.org/10.1111/jcmm.13453
Kumar N, Sidharth (2018) Some studies on use of ternary blends of diesel, biodiesel and n-octanol. Energy Sources Part A 40(14):1721–1728. https://doi.org/10.1080/15567036.2018.1486902
Kumar N, Tomar M (2019) Influence of nanoadditives on ignition characteristics of Kusum (Schleichera oleosa) biodiesel. Int J Energy Res 43(8):3223–3236. https://doi.org/10.1002/er.4446
Li X, Luo X, Jin Y, Li J, Zhang H, Zhang A, Xie J (2018) Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels. Renew Sust Energ Rev 82(July):3762–3797. https://doi.org/10.1016/j.rser.2017.10.091
Machalaba C, Romanelli C, Stoett P, Baum SE, Bouley TA, Daszak P, Karesh WB (2015) Climate change and health: transcending silos to find solutions. Ann Glob Health 81(3):445–458. https://doi.org/10.1016/J.AOGH.2015.08.002
Mahesh SE, Ramanathan A, Begum KMMS, Narayanan A (2015) Biodiesel production from waste cooking oil using KBr impregnated CaO as catalyst. Energy Convers Manag 91:442–450. https://doi.org/10.1016/J.ENCONMAN.2014.12.031
Manchanda T, Tyagi R, Sharma DK (2018) Comparison of fuel characteristics of green (renewable) diesel with biodiesel obtainable from algal oil and vegetable oil. Energy Sources Part A 40(1):54–59. https://doi.org/10.1080/15567036.2017.1405109
Matwijczuk A, Zając G, Kowalski R, Kachel-Jakubowska M, Gagoś M (2017) Spectroscopic studies of the quality of fatty acid methyl esters derived from waste cooking oil. Pol J Environ Stud 26(6):2643–2650. https://doi.org/10.15244/pjoes/70431
Mortensen PM, Grunwaldt J-D, Jensen PA, Knudsen KG, Jensen AD (2011) A review of catalytic upgrading of bio-oil to engine fuels. Appl Catal A Gen 407(1–2):1–19. https://doi.org/10.1016/J.APCATA.2011.08.046
Ogunkoya D, Roberts WL, Fang T, Thapaliya N (2015) Investigation of the effects of renewable diesel fuels on engine performance, combustion, and emissions. Fuel 140:541–554. https://doi.org/10.1016/j.fuel.2014.09.061
Omidvarborna H, Kumar A, Kim D-S (2016) Variation of diesel soot characteristics by different types and blends of biodiesel in a laboratory combustion chamber. Sci Total Environ 544:450–459. https://doi.org/10.1016/J.SCITOTENV.2015.11.076
Pali HS, Kumar N (2016a) Combustion, performance and emissions of Shorea robusta methyl ester blends in a diesel engine. Biofuels 7(5):447–456. https://doi.org/10.1080/17597269.2016.1153363
Pali HS, Kumar N (2016b) Comparative assessment of Sal and kusum biodiesel properties. Energy Sources Part A 38(22):3391–3396. https://doi.org/10.1080/15567036.2015.1136974
Parada Hernandez NL, Bonon AJ, Bahú JO, Barbosa MIR, Wolf Maciel MR, Filho RM (2017) Epoxy monomers obtained from castor oil using a toxicity-free catalytic system. J Mol Catal A Chem 426:550–556. https://doi.org/10.1016/J.MOLCATA.2016.08.005
Rajesh M, Sau M, Malhotra RK, Sharma DK (2015) Hydrotreating of gas oil, Jatropha oil, and their blends using a carbon supported cobalt-molybdenum catalyst. Pet Sci Technol 33(19):1653–1659. https://doi.org/10.1080/10916466.2015.1036291
Rajesh M, Sau M, Malhotra RK, Sharma DK (2016a) Synthesis and characterization of Ni-Mo catalyst using Jatropha curcas leaves as carbon support and its catalytic activity for hydrotreating of gas oil, Jatropha oil, and their blends. Pet Sci Technol 34(3):240–246. https://doi.org/10.1080/10916466.2015.1124890
Rajesh M, Sau M, Malhotra RK, Sharma DK (2016b) Synthesis and characterization of Ni-Mo catalyst using pea pod (Pisum sativum L) as carbon support and its hydrotreating potential for gas oil, Jatropha oil, and their blends. Pet Sci Technol 34(4):394–400. https://doi.org/10.1080/10916466.2015.1120748
Saidi M, Samimi F, Karimipourfard D, Nimmanwudipong T, Gates BC, Rahimpour MR (2014) Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation. Energy Environ Sci 7(1):103–129. https://doi.org/10.1039/C3EE43081B
Sankaranarayanan TM, Banu M, Pandurangan A, Sivasanker S (2011) Hydroprocessing of sunflower oil-gas oil blends over sulfided Ni-Mo-Al-zeolite beta composites. Bioresour Technol 102(22):10717–10723. https://doi.org/10.1016/j.biortech.2011.08.127
Satyarthi JK, Srinivas D (2011) Fourier transform infrared spectroscopic method for monitoring hydroprocessing of vegetable oils to produce hydrocarbon-based biofuel. Energy Fuels 25(7):3318–3322. https://doi.org/10.1021/ef200722q
Shams Z, Moghiman M (2018) Effect of metal oxide nanoparticles on the ignition characteristics of diesel fuel droplets: an experimental study. J Braz Soc Mech Sci Eng 40(2):1–10. https://doi.org/10.1007/s40430-018-1010-2
Singh D, Subramanian KA, Bal R, Singh SP, Badola R (2018) Combustion and emission characteristics of a light duty diesel engine fueled with hydro-processed renewable diesel. Energy 154:498–507. https://doi.org/10.1016/j.energy.2018.04.139
Somandepalli V, Kelly S, Davis S (2008) Hot surface ignition of ethanol-blended fuels and biodiesel. SAE Tech Pap 2008(724). https://doi.org/10.4271/2008-01-0402
Sonthalia A, Kumar N (2017) Hydroprocessed vegetable oil as a fuel for transportation sector: a review. J Energy Inst. https://doi.org/10.1016/j.joei.2017.10.008
Varuvel EG, Sonthalia A, Subramanian T, Aloui F (2018) NOx-smoke trade-off characteristics of minor vegetable oil blends synergy with oxygenate in a commercial CI engine. Environ Sci Pollut Res 25(35):35715–35724. https://doi.org/10.1007/s11356-018-3484-y
Vermeulen R, Silverman DT, Garshick E, Vlaanderen J, Portengen L, Steenland K (2014) Exposure-response estimates for diesel engine exhaust and lung cancer mortality based on data from three occupational cohorts. Environ Health Perspect 122(2):172–177. https://doi.org/10.1289/ehp.1306880
Zarchin R, Rabaev M, Vidruk-Nehemya R, Landau MV, Herskowitz M (2015) Hydroprocessing of soybean oil on nickel-phosphide supported catalysts. Fuel 139:684–691. https://doi.org/10.1016/j.fuel.2014.09.053
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Sonthalia, A., Kumar, N. Comparison of fuel characteristics of hydrotreated waste cooking oil with its biodiesel and fossil diesel. Environ Sci Pollut Res 28, 11824–11834 (2021). https://doi.org/10.1007/s11356-019-07110-w
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DOI: https://doi.org/10.1007/s11356-019-07110-w