Abstract
TiO2 shows great potential as ideal and powerful photocatalyst to degrade and eliminate harmful organic pollutants from waste water. It is desirable to prepare anatase TiO2 with good aqueous solubility and photocatalytic activity for water decontamination. In this paper, water-soluble TiO2 nanoparticles were successfully prepared using polytetramethylene ether glycol (PTMG), poly(ethylene glycol) (PEG), and poly(propylene glycol) (PPG) as stabilizers. The anatase phase of TiO2 was well controlled by introduction of HCl in the reaction system. The results showed that all the polymer-capped TiO2 were well dissolved in water and their aqueous solutions could maintain stable for more than 2 months. The photocatalytic activities of polymer-capped TiO2 were evaluated by monitoring the degradation of Rhodamine B (RhB) with Degussa P25 as a control. The results showed that all the polymer-capped TiO2 presented better photocatalytic activity than that of Degussa P25. PTMG capped TiO2 exhibited the longest average lifetime of charge carriers, indicating the lowest charge recombination rate. Thus, PTMG capped TiO2 presented the best photocatalytic activity. In summary, PTMG, PEG, and PPG can be used as stabilizers to prepare water-soluble TiO2. PTMG is an ideal stabilizer for the synthesis of water-soluble TiO2 with good photocatalytic activity.
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References
Ansari SA, Cho MH (2016) Highly visible light responsive, narrow band gap TiO2 nanoparticles modified by elemental red phosphorus for photocatalysis and photoelectrochemical applications. Sci Rep-UK 6:1–9
Banerjee S, Pillai SC, Falaras P, O’shea KE, Byrne JA, Dionysiou DD (2014) New insights into the mechanism of visible light photocatalysis. J Phys Chem Lett 5:2543–2554
Chen X, Liu L, Peter YY, Mao SS (2011) Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science 331:746–750
Chen X, Mao SS (2007) Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107:2891–2959
Chong MN, Jin B, Chow CW, Saint C (2010) Recent developments in photocatalytic water treatment technology: a review. Water Res 44:2997–3027
Fujishima A (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38
Fujishima A, Zhang X, Tryk DA (2008) TiO2 photocatalysis and related surface phenomena. Surf Sci Rep 63:515–582
Jaiswal R, Patel N, Dashora A, Fernandes R, Yadav M, Edla R, Varma R, Kothari D, Ahuja B, Miotello A (2016) Efficient Co-B-codoped TiO2 photocatalyst for degradation of organic water pollutant under visible light. Appl Catal B Environ 183:242–253
He HY (2016) Facile synthesis of ultrafine CuS nanocrystalline/TiO2: Fe nanotubes hybrids and their photocatalytic and Fenton-like photocatalytic activities in the dye degradation. Microporous Mesoporous Mater 227:31–38
He HY, Huang JF, Cao LY, Wu JP (2010) Photodegradation of methyl orange aqueous on MnWO4 powder under different light resources and initial pH. Desalination 252:66–70
He Y, Sutton NB, Rijnaarts HHH, Langenhoff AAM (2016) Degradation of pharmaceuticals in wastewater using immobilized TiO2 photocatalysis under simulated solar irradiation. Appl Catal B Environ 182:132–141
Hu XF, Mohamood T, Ma WH, Chen CC, Zhao JC (2006) Oxidative decomposition of rhodamine B dye in the presence of VO2+ and/or Pt(IV) under visible light irradiation: N-deethylation, chromophore cleavage, and mineralization. J Phys Chem B 110:26012–26018
Khan MA, Jung HT, Yang OB (2006) Synthesis and characterization of ultrahigh crystalline TiO2 nanotubes. J Phys Chem B 110:6626–6630
Konstantinou IK, Albanis TA (2004) TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: a review. Appl Catal B Environ 49:1–14
Li J, Wu X, Pan W, Zhang G, Chen H (2018) Vacancy-rich monolayer BiO2−x as a highly efficient UV, visible, and near-infrared responsive photocatalyst. Angew Chem Int Ed 57:491–495
Liu M, Inde R, Nishikawa M, Qiu X, Atarashi D, Sakai E, Nosaka Y, Hashimoto K, Miyauchi M (2014) Enhanced photoactivity with nanocluster-grafted titanium dioxide photocatalysts. ACS Nano 8:7229–7238
Melcher J, Feroz S, Bahnemann D (2017) Comparing photocatalytic activities of commercially available iron-doped and iron-undoped aeroxide TiO2 P25 powders. J Mater Sci 52:6341–6348
Ohtani B (2013) Titania photocatalysis beyond recombination: a critical review. Catalysts 3:942–953
Park H, Park Y, Kim W, Choi W (2013) Surface modification of TiO2 photocatalyst for environmental applications. J Photoch Photobio C 15:1–20
Schneider J, Matsuoka M, Takeuchi M, Zhang J, Horiuchi Y, Anpo M, Bahnemann DW (2014) Understanding TiO2 photocatalysis: mechanisms and materials. Chem Rev 114:9919–9986
Sivalingam G, Nagaveni K, Hegde M, Madras G (2003) Photocatalytic degradation of various dyes by combustion synthesized nano anatase TiO2. Appl Catal B Environ 45:23–38
Song JN, Zheng MJ, Yuan XL, Li Q, Wang FZ, Ma LG, You YX, Liu SH, Liu PJ, Jiang DK, Ma L, Shen WZ (2017) Electrochemically induced Ti3+ self-doping of TiO2 nanotube arrays for improved photoelectrochemical water splitting. J Mater Sci 52:6976–6986
Wang K, Zhang G, Li J, Li Y, Wu X (2017) 0D/2D Z-scheme heterojunctions of bismuth tantalate quantum dots/ultrathin g-C3N4 nanosheets for highly efficient visible light photocatalytic degradation of antibiotics. ACS Appl Mater Interfaces 9:43704–43715
Wang P, Wang D, Li H, Xie T, Wang H, Du Z (2007) A facile solution-phase synthesis of high quality water-soluble anatase TiO2 nanocrystals. J Colloid Interface Sci 314:337–340
Wang WK, Chen JJ, Gao M, Huang YX, Zhang X, Yu HQ (2016) Photocatalytic degradation of atrazine by boron-doped TiO2 with a tunable rutile/anatase ratio. Appl Catal B: Environ 195:69–76
Wang Y, Duo F, Peng S, Jia F, Fan C (2014) Potassium iodate assisted synthesis of titanium dioxide nanoparticles with superior water-dispersibility. J Colloid Interface Sci 430:31–39
Yan X, Pan D, Li Z, Liu Y, Zhang J, Xu G, Wu M (2010) Controllable synthesis and photocatalytic activities of water-soluble TiO2 nanoparticles. Mater Lett 64:1833–1835
Yao Y, Qin J, Chen H, Wei F, Liu X, Wang J, Wang S (2015) One-pot approach for synthesis of N-doped TiO2/ZnFe2O4 hybrid as an efficient photocatalyst for degradation of aqueous organic pollutants. J Hazard Mater 291:28–37
Yu JC, Yu J, Ho W, Jiang Z, Zhang L (2002) Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem Mater 14:3808–3816
Zhang D, Li J, Wang QG, Wu QS (2013) High {001} facets dominated BiOBr lamellas: facile hydrolysis preparation and selective visible-light photocatalytic activity. J Mater Chem A 1:8622–8629
Zhang M, Lei J, Shi Y, Zhang L, Ye Y, Li D, Mu C (2016) Photocatalytic degradation of various dyes by combustion synthesized nano anatase TiO2. RSC Adv 6:83366–83372
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This study was supported by the Project of Youth Science and Technology Innovation Research Team of Sichuan Province (2017TD0010).
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Responsible editor: Suresh Pillai
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Lei, J., Deng, L., Li, X. et al. Comparative study of the physicochemical and photocatalytic properties of water-soluble polymer-capped TiO2 nanoparticles. Environ Sci Pollut Res 25, 26259–26266 (2018). https://doi.org/10.1007/s11356-018-2679-6
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DOI: https://doi.org/10.1007/s11356-018-2679-6