Abstract
Mercury (Hg) speciation and mobility were determined in calcines and waste rocks collected from 9 Hg mines in China. Total Hg (THg) concentrations in the mine wastes varied widely in different Hg mines (with a range of 0.369 to 2,620 mg kg−1). Cinnabar is the dominant form of Hg in the mine wastes. However, Hg2+ and Hg0 concentrations in the calcines were significantly higher than these in the waste rocks, which suggested the retorting can produce large amounts of by-product Hg compounds. The THg and Hg0 concentrations in certain mine wastes exceeded soil guidelines recommended by US Environmental Protection Agency; while total soluble Hg concentrations of leachates in certain mine wastes exceeded National Surface Water Quality Standard of China. Mine wastes are important Hg pollution sources to the aquatic ecosystem and atmosphere.
Similar content being viewed by others
References
Bailey EH, Clark AL, Smith RM (1973) Mercury. In: Brobst DA and Pratt WP (eds) United States Mineral Resources. U.S. Geological Survey, Professional Paper 820, pp. 401–414
Biester H, Gosar M, Muller G (1999) Mercury speciation in tailings of the Idrija mercury mine. J Geochem Explor 65:195–204
Biester H, Scholz C (1997) Determination of mercury binding forms in contaminated soils: mercury pyrolysis versus sequential extractions. Environ Sci Technol 31:233–239
Bonzongo JC, Heim KJ, Warwick JJ, Lyons WB (1996) Mercury levels in surface waters of the Carson River-Lahontan Reservoir system, Nevada: influence of historic mining activities. Environ Pollu 92:193–201
CMA (China Mining Association) (2011) Mercury mineral resource in China. http://www.chinamining.com.cn/report/default.asp?V_DOC_ID=1141. Accessed 10 December 2012
Ferrara R, Maserti BE, Andersson M et al (1998) Atmospheric mercury concentrations and fluxes in the Almadén district (Spain). Atmos Environ 22:3897–3904
Feng X, Li P, Qiu G et al (2008) Methylmercury exposure through rice intake to inhabitants in Wanshan mercury mining area in Guizhou, China. Environ Sci Technol 42:326–332
Fu X, Feng X, Sommar J, Wang S (2012) A review of studies on atmospheric mercury in China. Sci Total Environ 421–422:73–81
Ganguli PM, Mason RP, Abu-Saba KE, Anderson RS, Flegal AR (2000) Mercury speciation in drainage from the New Idria mercury mine, California. Environ Sci Technol 34:4773–4779
García-Sánchez A, Murciego A, Alvarez-Ayuso E, SantaRegina I, Rodríguez-González MA (2009) Mercury in soils and plants in an abandoned cinnabar mining area (SW Spain). J Hazard Mater 168:1319–1324
Gosar M, Tersic T (2012) Environmental geochemistry studies in the area of Idrija mercury mine, Slovenia. Environ Geochem Health 34:27–41
Gray JE, Crock JG, Fey DL (2002) Environmental geochemistry of abandoned mercury mines in West-Central Nevada, USA. Appl Geochem 17:1069–1079
Gray JE, Greaves IA, Bustos DM, Krabbenhoft DP (2003) Mercury and methylmercury contents in mine-waste calcine, water, and sediment collected from the Palawan Quicksilver Mine, Philippines. Environ Geol 43:298–307
Gray JE, Hines M, Biester H (2006) Mercury methylation influenced by areas of past mercury mining in the Terlingua district, Southwest Texas, USA. Appl Geochem 21:1940–1954
Gray JE, Hines ME, Higueras PL, Adatto I, Lasorsa BK (2004) Mercury speciation and microbial transformations in mine wastes, stream sediments, and surface waters at the Almadén mining district, Spain. Environ Sci Technol 38:4285–4292
Gray JE, Peter U, Theodorakos M, Bailey EA, Turner RR (2000) Distribution, speciation, and transport of mercury in stream-sediment, streamwater, and fish collected near abandoned mercury mines in southwestern Alaska, USA. Sci Total Environ 260:21–33
Gustin MS, Coolbaugh MF, Engle MA et al (2003) Atmospheric mercury emissions from mine wastes and surrounding geologically enriched terrains. Environ Geol 43:339–351
Hines ME, Horvat M, Faganeli J et al (2000) Mercury biogeochemistry in the Idrija river, Slovenia, from above the mine into the Gulf of Trieste. Environ Res 83:129–139
Horvat M, Nolde N, Fajon V et al (2003) Total mercury, methylmercury and selenium in mercury polluted areas in the province Guizhou, China. Sci Total Environ 304:231–256
Hua Y, Cui M (1994) Wanshan Mercury Deposit in Guizhou Province. China Geological Press, Beijing (in Chinese)
Hylander L, Meili M (2003) 500 years of mercury production: global annual inventory by region until 2000 and associated emissions. Sci Total Environ 304:13–27
Jian X, Shen Y, Yao W et al (2009) Status analysis and reduction countermeasures of China’s mercury supply and demand. Res Environ Sci 22:788–792 (in Chinese with English abstract)
Jew AD, Kim CS, Rytuba JJ, Gustin MS, Jr B (2011) New technique for quantification of elemental Hg in mine wastes and its implications for mercury evasion into the atmosphere. Environ Sci Technol 45:412–417
Kim CS, Jr G, Rytuba JJ (2000) Characterization and speciation of mercury-bearing mine waste using X-ray adsorption spectroscopy. Sci Total Environ 261:157–168
Kim CS, Rytuba J, Brown-Jr G (2004) Geological and anthropogenic factors influencing mercury speciation in mine wastes: an EXAFS spectroscopy study. Appl Geochem 19:379–393
Kocman D, Horvat M (2011) Non-point source mercury emission from the Idrija Hg-mine region: GIS mercury emission model. J Environ Manage 92:2038–2046
Kocman D, Horvat M, Kotnik J (2004) Mercury fractionation in contaminated soils from the Idrija mercury mine region. J Environ Monit 6:696–703
Li P, Feng X, Qiu G, Shang L, Wang S (2012) Mercury pollution in Wuchuan mercury mining area, Guizhou, Southwestern China: The impacts from large scale and artisanal mercury mining. Environ Int 42:59–66
Li P, Feng X, Shang L, Qiu G, Meng B, Liang P, Zhang H (2008) Mercury pollution from artisanal mercury mining in Tongren, Guizhou, China. Appl Geochem 23:2055–2064
Lin Y, Larssen T, Vogt R, Feng X, Zhang H (2011) Modelling transport and transformation of mercury fractions in heavily contaminated mountain streams by coupling a GIS-based hydrological model with a mercury chemistry model. Sci Total Environ 409:4596–4605
Lindberg S, Bullock R, Ebinghaus R et al (2007) A synthesis of progress and uncertainties in attributing the sources of mercury in deposition. Ambio 36:19–32
Liu G, Cabrera J, Allen M, Cai Y (2006) Mercury characterization in a soil sample collected nearby the DOE Oak Ridge Reservation utilizing sequential extraction and thermal desorption method. Sci Total Environ 369:384–392
Liu JY (1998) The influence of environmental pollution on eco-agriculture systems in Guizhou province. Guizhou Environ Protect Sci Technol 4:40–44 (in Chinese)
Liu J (2000) Introductory remarks on mercury pollution in China. J Environ Sci-China 12(suppl):3–8
Loredo J, Alvarez R, Ordonez A (2005) Release of toxic metals and metalloids from Los Rueldos mercury mine (Asturias, Spain). Sci Total Environ 340:247–260
Loredo J, Ordonez A, Alvarez R (2006) Environmental impact of toxic metals and metalloids from the Munon Cimero mercury-mining area (Asturias, Spain). J Hazard Mater 136:455–467
Mason RP, Sheu GR (2002) Role of the ocean in the global mercury cycle. Global Biogeochem Cycles 16:1093. doi:10.1029/2001GB001440
MEP (Minister of Environmental Protection) (2002) Environmental quality standards for surface water (GB3838-2002). Environmental Science Press of China, Beijing
Mergler D, Anderson AH, Chan HM et al (2007) Methylmercury exposure and health effects in humans: a worldwide concern. Ambio 36:3–11
Navarro A, Cardellach E, Corbella M (2009) Mercury mobility in mine waste from Hg-mining areas in Almería, Andalusia (Se Spain). J Geochem Explor 101:236–246
Qiu G, Feng X, Meng B, Sommar J, Gu C (2012) Environmental geochemistry of an active Hg mine in Xunyang, Shaanxi Province, China. Appl Geochem 27:2280–2288
Qiu G, Feng X, Wang S, Shang L (2005) Mercury and methylmercury in riparian soil, sediments, mine-waste calcines, and moss from abandoned Hg mines in east Guizhou province, southwestern China. Appl Geochem 20:627–638
Qiu G, Feng X, Wang S, Shang L (2006a) Environmental contamination of mercury from Hg-mining areas in Wuchuan, northeastern Guizhou, China. Environ Pollu 142:549–558
Qiu G, Feng X, Wang S, Xiao T (2006b) Mercury contaminations from historic mining to water, soil and vegetation in Lanmuchang, Guizhou, southwestern China. Sci Total Environ 368:56–68
Rimondi V, Gray EJ, Costagliola P, Vaselli O, Lattanzi P (2012) Concentration, distribution, and translocation of mercury and methylmercury in mine-waste, sediment, soil, water, and fish collected near the Abbadia San Salvatore mercury mine, Monte Amiata district, Italy. Sci Total Environ 414:318–327
Rytuba JJ (2003) Mercury from mineral deposits and potential environmental impact. Environ Geol 43:326–338
Schroeder WH, Munthe J (1998) Atmospheric mercury—an overview. Atmos Environ 32:809–822
Schuster PF, Krabbenhoft PF, Naftz DL et al (2002) Atmospheric mercury deposition during the last 270 years: a glacial ice core record of natural and anthropogenic sources. Environ Sci Technol 36:2303–2310
Shi J, Liang L, Jiang G, Jin X (2005) The speciation and bioavailability of mercury in sediments of Haihe River, China. Environ Int 31:357–365
Sholupov S, Pogarev S, Ryzhov V, Mashyanov N, Stroganov A (2004) Zeeman atomic absorption spectrometer RA-915+ for direct determination of mercury in air and complex matrix samples. Fuel Process Technol 85:473–485
US Environmental Protection Agency (2011) Human health medium specific screening levels. http://www.epa.gov/region6/6pd/rcra_c/pd-n/screen.htm. Accessed 25 February 2013
Wang J, Feng X, Anderson WNC et al (2011a) Ammonium thiosulphate enhanced phytoextraction from mercury contaminated soil—results from a greenhouse study. J Hazard Mater 186:119–127
Wang J, Feng X, Anderson WNC et al (2011b) Mercury distribution in the soil–plant–air system at the Wanshan mercury mining district in Guizhou, Southwest China. Environ Toxicol Chem 30:2725–2731
Wang S, Feng X, Qiu G, Fu X, Wei Z (2007) Characteristics of mercury exchange flux between soil and air in the heavily air-polluted area, eastern Guizhou, China. Atmos Environ 41:5584–5594
Zhang G, Liu C, Wu P, Yang Y (2004) The geochemical characteristics of mine-waste calcines and runoff from the Wanshan mercury mine, Guizhou, China. Appl Geochem 19:1735–1744
Zhang H, Feng X, Thorjørn L et al (2010a) Fractionation, distribution and transport of mercury in rivers and tributaries around Wanshan Hg mining district, Guizhou Province, Southwestern China: part 1. Total mercury. Appl Geochem 25:633–641
Zhang H, Feng X, Thorjørn L et al (2010b) Fractionation, distribution and transport of mercury in rivers and tributaries around Wanshan Hg mining district, Guizhou Province, Southwestern China: part 2. Methylmercury. Appl Geochem 25:642–649
Zhang L, Jin Y, Lu J, Zhang C (2009) Concentration, distribution and bioaccumulation of mercury in the Xunyang mercury mining area, Shaanxi Province, China. Appl Geochem 24:950–956
Acknowledgments
This study was funded by the National Key Basic Research Program of China (2013CB430004), the National Natural Science Foundation of China (21007068 and 41021062), the West Light Foundation of the Chinese Academy of Sciences, the Natural Science Foundation of Guizhou Province (2009–2003), and the Social Development Project of Guizhou Province (2012–3044).
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Stuart Simpson
Electronic supplementary material
Below is the link to the electronic supplementary material.
ESM 1
(DOCX 119 KB)
Rights and permissions
About this article
Cite this article
Li, P., Feng, X., Qiu, G. et al. Mercury speciation and mobility in mine wastes from mercury mines in China. Environ Sci Pollut Res 20, 8374–8381 (2013). https://doi.org/10.1007/s11356-013-1731-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-013-1731-9