Skip to main content
SpringerLink
Log in

Synthesis and electrocatalytic properties of a dinuclear palladium(I) 1-[(2-bromo)benzene]-3-[(2-carboxymethyl)benzene]triazenide complex

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The reaction of 1-[(2-bromo)benzene]-3-[(2-carboxymethyl)benzene]triazene and [Pd(CH3CN)4]Cl2 gave a new dinuclear triazenido complex [Pd2L2] 1, which has been characterized by NMR spectra and X-ray crystallography. Electrochemical studies showed that complex 1 is capable of generating hydrogen from acetic acid in CH2Cl2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Walter MG, Warren EL, McKone JR, Boettcher SW, Mi Q, Santori EA, Lewis NS (2010) Chem Rev 110:6446–6473

    Article  CAS  Google Scholar 

  2. Song LC, Xie ZJ, Wang MM, Zhao GY, Song HB (2012) Inorg Chem 51:7466–7468

    Article  CAS  Google Scholar 

  3. Fontecilla-Camps JC, Volbeda A, Cavazza C, Nicolet Y (2007) Chem Rev 107:4273–4303

    Article  CAS  Google Scholar 

  4. Vignais PM, Billoud B (2007) Chem Rev 107:4206–4272

    Article  CAS  Google Scholar 

  5. Pickett CJ, Tard C (2009) Chem Rev 109:2245–2274

    Article  Google Scholar 

  6. Vincent KA, Parkin A, Armstrong FA (2007) Chem Rev 107:4366–4413

    Article  CAS  Google Scholar 

  7. Appel AM, Pool DH, O’Hagan M, Shaw WJ, Yang JY, DuBois MR, DuBois DL, Bullock RM (2011) ACS Catal 1:777–785

    Article  CAS  Google Scholar 

  8. Wiese S, Kilgore UJ, DuBois DL, Bullock RM (2012) ACS Catal 2:720–727

    Article  CAS  Google Scholar 

  9. Helm ML, Stewart MP, Bullock RM, DuBois MR, DuBois DL (2011) Science 333:863–866

    Article  CAS  Google Scholar 

  10. Kilgore UJ, Roberts JA, Pool DH, Appel AM, Stewart MP, DuBois MR, Dougherty WG, Kassel WS, Bullock RM, DuBois DL (2011) J Am Chem Soc 133:5861–5872

    Article  CAS  Google Scholar 

  11. Artero V, Chavarot-Kerlidou M, Fontecave M (2011) Angew Chem Int Ed 50:7238–7266

    Article  CAS  Google Scholar 

  12. Razavet M, Artero V, Fontecave M (2005) Inorg Chem 44:4786–4795

    Article  CAS  Google Scholar 

  13. Baffert C, Artero V, Fontecave M (2007) Inorg Chem 46:1817–1824

    Article  CAS  Google Scholar 

  14. Berben LA, Peters JC (2010) Chem Commun 46:398–400

    Article  CAS  Google Scholar 

  15. Stubbert BD, Peters JC, Gray HB (2011) J Am Chem Soc 133:18070–18073

    Article  CAS  Google Scholar 

  16. Chang CJ, Bigi JP, Hanna TE, Harman WH, Chang A (2010) Chem Commun 46:958–960

    Article  Google Scholar 

  17. Hall MB, Surawatanawong P, Tye JW, Darensbourg MY (2010) Dalton Trans 39:3093–3104

    Article  Google Scholar 

  18. Lichtenberger DL, Vannucci AK, Wang SH, Nichol GS, Evans DH, Glass RS (2010) Dalton Trans 39:3050–3056

    Article  Google Scholar 

  19. Camara JM, Rauchfuss TB (2012) Nat. Chem 4:26–30

    Article  CAS  Google Scholar 

  20. Liu M, Zhan C, Wang X, Wei Z, Evans DJ, Ru X, Zeng X (2010) Dalton Trans 39:11255–11262

    Article  Google Scholar 

  21. Karunadasa HI, Montalvo E, Sun Y, Majda M, Long JR, Chang CJ (2012) Science 335:698–702

    Article  CAS  Google Scholar 

  22. Karunadasa HI, Chang CJ, Long JR (2010) Nature 464:1329–1333

    Article  CAS  Google Scholar 

  23. Lei WJ, Tan XW, Han LJ, Zhan SZ, Li BT (2010) Inorg Chem Commun 13:1325–1328

    Article  CAS  Google Scholar 

  24. Johnson AL, Willcocks AM, Richards SP (2009) Inorg Chem 48:8613–8622

    Article  CAS  Google Scholar 

  25. Sheldrick GM (1996) SADABS, Program for empirical absorption correction of area detector data, University of Götingen, Götingen, Germany

  26. Sheldrick GM (1997) SHELXS 97, Program for crystal structure refinement, University of Götingen, Götingen, Germany

  27. Nuricumbo-Escobar JJ, Campos-Alvarado C, Ríos-Moreno G, Morales-Morales D, Walsh PJ, Parra-Hake M (2007) Inorg Chem 46:6182–6189

    Article  CAS  Google Scholar 

  28. Tanase T, Kawahara K, Ukaji H, Kobayashi K, Yamazaki H, Yamamoto Y (1993) Inorg Chem 32:3682–3688

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Research Foundation for Returned Chinese Scholars Overseas of Chinese Education Ministry (No. B7050170), the National Science Foundation of China (No. 20971045, 21271073), the Science Foundation of GuiZhou (No. J-[2012]2190), and the Student Research Program (SRP) of South China University of Technology.

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China

    Jing Chu, Qi-ying Lv & Shuzhong Zhan

  2. College of Chinese Language and Culture, Jinan University, Guangzhou, 510610, China

    Xiao-hua Xie

  3. Department of Chemistry, Guizhou Minzu University, Guiyang, 550000, China

    Wei Li

Authors
  1. Jing Chu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qi-ying Lv
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiao-hua Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wei Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shuzhong Zhan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shuzhong Zhan.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chu, J., Lv, Qy., Xie, Xh. et al. Synthesis and electrocatalytic properties of a dinuclear palladium(I) 1-[(2-bromo)benzene]-3-[(2-carboxymethyl)benzene]triazenide complex. Transition Met Chem 38, 843–847 (2013). https://doi.org/10.1007/s11243-013-9757-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-013-9757-x

Keywords

Search

Navigation