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Synthesis, structure and catalytic activity of an oxo-bridged dinuclear oxovanadium complex of an isonicotinohydrazide ligand

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Abstract

A mononuclear dioxo vanadium(V) complex of a hydrazone ONO donor ligand, [VVO2(L1)] (1), was synthesized by the reaction of V2O5 and terephthalic acid with H2L1 in 1:1:1 mol ratio, while an oxo-bridged bis(vanadium(IV)oxo) complex, [μ 2–O–{VIVO(L2)}2] (2), was synthesized by the treatment of isonicotinic acid hydrazide, salicylaldehyde and CoSO4·7H2O with bis(acetylacetonato)oxovanadium(IV) (H2L1 = isonicotinic acid(2-hydroxy-benzylidene)-hydrazide, H2L2 = isonicotinic acid (1-methyl-3-oxo-butylidene)-hydrazide). The complexes were characterized by elemental analyses and spectroscopic methods. The crystal structure of complex 2 was determined by X-ray analysis. The complexes were tested as catalysts for the oxidation of cycloalkenes and benzyl alcohol using H2O2 as terminal oxidant. Excellent selectivity was achieved in the oxidation of cyclohexene.

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Acknowledgments

This work was financially supported by the University of Zanjan, the Faculty of Chemistry and Biochemistry of the Ludwig-Maximilians-Universität München, and the School of Chemistry.

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Authors and Affiliations

  1. Department of Chemistry, University of Zanjan, 45195-313, Zanjan, Islamic Republic of Iran

    Hassan Hosseini-Monfared, Afsaneh Farrokhi & Sohaila Alavi

  2. Fakultät für Chemie und Pharmazie, Ludwig-Maximilians-Universität, München, Butenandtstr. 5-13, Haus D, 81377, Munchen, Germany

    Peter Mayer

Authors
  1. Hassan Hosseini-Monfared
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  2. Afsaneh Farrokhi
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  3. Sohaila Alavi
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  4. Peter Mayer
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Correspondence to Hassan Hosseini-Monfared.

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Hosseini-Monfared, H., Farrokhi, A., Alavi, S. et al. Synthesis, structure and catalytic activity of an oxo-bridged dinuclear oxovanadium complex of an isonicotinohydrazide ligand. Transition Met Chem 38, 267–273 (2013). https://doi.org/10.1007/s11243-012-9687-z

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  • DOI: https://doi.org/10.1007/s11243-012-9687-z

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