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Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers

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Abstract

Two new cobalt(II) coordination polymers, namely [Co1.5(PhCOO)3(bbbm)1.5(H2O)] n (1) and [Co(chdc)(bbbm)] n (2) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H2chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray diffraction. The cobalt(II) centers display different environments, with trigonal–bipyramidal and octahedral geometries in 1 and a tetrahedral geometry in 2. The 1D linear chains of complex 1 and ladder-like chains of complex 2 are bridged by bbbm in bis-monodentate coordination mode; the variation of the carboxylate co-ligand effectively tunes the resulting framework architecture. The degradation of methyl orange in a photochemical Fenton-like process using complexes 1 and 2 as catalysts was investigated.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, 46 West Xinhua Road, Tangshan, 063009, Hebei, People’s Republic of China

    Cui-huan Jiao, Cui-hong He, Jian-chen Geng & Guang-hua Cui

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  1. Cui-huan Jiao
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  2. Cui-hong He
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  3. Jian-chen Geng
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  4. Guang-hua Cui
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Corresponding author

Correspondence to Guang-hua Cui.

Electronic supplementary material

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Supplementary material 1 (DOCX 599 kb)

Appendix: Supplementary data

Appendix: Supplementary data

CCDC 837270 and 837269 contain the supplementary crystallographic data for complexes 1 and 2. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk. The figure of 1D ladder-like chain in complex 2 and TG studies of the two compounds are also available (Figures S1, S2 and S3).

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Jiao, Ch., He, Ch., Geng, Jc. et al. Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers. Transition Met Chem 37, 17–23 (2012). https://doi.org/10.1007/s11243-011-9550-7

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