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Synthesis and characterization of octakis-(9-anthracenylmethylthio) substituted novel porphyrazines

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Abstract

A magnesium porphyrazinate carrying eight (9-anthracenyl) units on the periphery through flexible methylthio-bridges has been synthesized by cyclotetramerization of 3,4-(9-anthracenylmethylthio) pyrroline-2,5-diimine in the presence of magnesium butanolate. The metal-free derivative was obtained by treatment with trifluoroacetic acid and further reaction of this product with copper(II) acetate, zinc(II) acetate, and cobalt(II) acetate led to the metal porphyrazinates (M = Cu, Zn, Co). These novel compounds were characterized by elemental analysis, together with FT-IR, 1H-NMR, UV–Vis, and mass spectral data.

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Acknowledgments

This work was supported by the Scientific Research Fund of Fatih University under the project number P50020606.

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Authors and Affiliations

  1. Department of Chemistry, Fatih University, B.Cekmece, Istanbul, 34500, Turkey

    Ergün Gonca

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  1. Ergün Gonca
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Correspondence to Ergün Gonca.

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Gonca, E. Synthesis and characterization of octakis-(9-anthracenylmethylthio) substituted novel porphyrazines. Transition Met Chem 33, 547–551 (2008). https://doi.org/10.1007/s11243-008-9078-7

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  • DOI: https://doi.org/10.1007/s11243-008-9078-7

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