Abstract
A brief review of the experimental methods used to evaluate vapour pressures and sublimation enthalpies is presented. The methods discussed have been used for determining the results of several substituted benzenes that were collected in a database, with the main purpose of developing new estimation methods of these thermodynamic properties. A critical evaluation of the two most used calorimetric techniques for determining enthalpies of sublimation is also addressed.
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Acknowledgments
This study was financially supported by FEDER through the Program COMPETE and by national funds of FCT—Fundação para a Ciência e a Tecnologia under strategic project PEst-C/QUI/UI0081/2011. A.R.R.P.A also thanks FCT and the European Social Fund (ESF) under the Community Support Framework (CSF) for the award of a PhD Research Grant (SFRH/BD/39210/2007).
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This article is dedicated to Maria Victoria Roux.
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Almeida, A.R.R.P., Monte, M.J.S. A brief review of the methods used to evaluate vapour pressures and sublimation enthalpies. Struct Chem 24, 1993–1997 (2013). https://doi.org/10.1007/s11224-013-0290-5
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DOI: https://doi.org/10.1007/s11224-013-0290-5