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The gas phase enthalpies of formation of hydrazine, its methylated derivatives, and the corresponding values for ammonia and its methylated derivatives

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Abstract

Hydrazine and some of its methylated derivatives are highly important species. Despite their molecular simplicity and those of the other methylated derivatives, ammonia, and the corresponding amines, there are significant problems with the literature values of their gas phase enthalpies of formation. We present our high level quantum chemical calculations at the G4 level for all of these species.

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References

  1. Curtius T (1889) J Prakt Chem 39:107

    Article  Google Scholar 

  2. Schirmann J-P, Bourdauducq P (2002) Hydrazine. In: Ullmann’s encyclopedia of industrial chemistry. Wiley–VCH, Weinheim

  3. Klapötke TM (2011) Chemistry of high-energy materials, Chap. 2.4. In: Rocket propellants. Walter de Gruyter, Berlin

  4. Bohn MA, Klapötke TM (2004) Z Naturforsch 59B:148

    Google Scholar 

  5. Schmidt EW (2001) In: Hydrazine and its derivatives, 2nd edn, vols 1 and 2. Wiley–VCH, Weinheim

  6. Wagman DD, Evans WH, Parker VB, Schumm RH, Halow I, Bailey SM, Churney KL, Nuttall RL (1982) The NBS tables of chemical thermodynamic properties: selected values for inorganic and C1 and C2 organic substances in SI units. J Phys Chem Ref Data 11(Suppl 2):1

    Google Scholar 

  7. Pedley JB (1994) In: Thermochemical data and structures of organic compounds, vol 1. TRC Data Series, College Station

  8. Aston JG, Rock EJ, Isserow S (1952) J Am Chem Soc 64:2484

    Article  Google Scholar 

  9. Aylett BJ (1957) J Chem Soc 4152

  10. Gengeliczki Z, Borkar SN, Sztáray B (2010) J Phys Chem A 114:6103

    Article  CAS  Google Scholar 

  11. Curtiss LA, Redfern PC, Raghavachari K (2007) J Chem Phys 126:084108

    Article  Google Scholar 

  12. Rayne S, Forest K (2010) J Chem Eng Data 55:5359

    Article  CAS  Google Scholar 

  13. Stull DR, Westrum EF Jr, Sinke GC (1969) In: The chemical thermodynamics of organic compounds. Wiley, New York (in particular, see Tables 601, 607 and 609 and associated text)

  14. Engel PS, Owens WH, Wang C (1993) J Phys Chem 97:10486

    Article  CAS  Google Scholar 

  15. Evans FW, Fairbrother DM, Skinner HA (1959) Trans Faraday Soc 55:399

    Article  CAS  Google Scholar 

  16. Lemoult MP (1907) Ann Chim Phys 12:395

    Google Scholar 

  17. McEwan WS, Rigg MW (1951) J Am Chem Soc 73:4725

    Article  CAS  Google Scholar 

  18. Lebedeva ND, Gutner N, Katin YA, Kozlova NM, Kiseleva NN, Makhina EF, Dobychin SL (1984) J Appl Chem USSR 57:2118

    Google Scholar 

  19. Steele WV, Chirico RD, Nguyen A, Hossenlopp IA, Smith NK (1989) AIChE Symp Ser 85:140–162

    CAS  Google Scholar 

  20. Lemoult MP (1908) Ann Chim Phys 13:562

    CAS  Google Scholar 

  21. Anderson CM, Gilbert EC (1942) J Am Chem Soc 64:2369

    Article  CAS  Google Scholar 

  22. Cole LG, Gilbert EC (1951) J Am Chem Soc 73:5423

    Article  CAS  Google Scholar 

  23. Lebedeva ND, Katin YA (1972) Russ J Phys Chem (Engl Transl) 46:1088

    Google Scholar 

  24. Liebman JF, Afeefy HY, Slayden SW (1997) In: Patai S (ed) The chemistry of hydrazo, azo and azoxy groups, vol 2. Wiley, Chichester, pp 79–104

    Chapter  Google Scholar 

  25. Liebman JF, Campbell, Slayden SW (1996) In: Patai S (ed) The chemistry of functional groups supplement F2: the chemistry of amino, nitroso, nitro and related groups. Wiley, Chichester, pp 337–378

    Chapter  Google Scholar 

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Acknowledgments

Rafael Notario and Joel F. Liebman gratefully acknowledge the support of the Spanish Ministerio de Economía y Competitividad under Project CTQ2010-16402.

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Authors and Affiliations

  1. Instituto de Química Física “Rocasolano”, CSIC, Serrano 119, 28006, Madrid, Spain

    Rafael Notario

  2. Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5-13 (Haus D), 81377, Munich, Germany

    Thomas M. Klapötke

  3. Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, MD, 21250-1000, USA

    Joel F. Liebman

Authors
  1. Rafael Notario
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  2. Thomas M. Klapötke
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  3. Joel F. Liebman
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Correspondence to Rafael Notario.

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Special Issue in honor of Prof. Maria Victoria Roux.

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Notario, R., Klapötke, T.M. & Liebman, J.F. The gas phase enthalpies of formation of hydrazine, its methylated derivatives, and the corresponding values for ammonia and its methylated derivatives. Struct Chem 24, 1817–1819 (2013). https://doi.org/10.1007/s11224-013-0235-z

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  • DOI: https://doi.org/10.1007/s11224-013-0235-z

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