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The first two structurally characterized energetic catalysts derived from dinitropyridone

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Abstract

Two energetic catalysts, 3,5-dinitro-2-pyridonate of lead (II) (Pb(2DNPO)2, 1) and 3,5-dinitro-4-pyridone-N-hydroxylate tetrahydrate of copper (II) (Cu(4DNPOH)2(H2O)4, 2) were characterized by elemental analysis, FT-IR, TG-DSC and structurally characterized by X-ray single-crystal diffraction analysis. X-ray powder diffraction analysis of complex 1 confirmed the phase homogeneity of the polycrystalline sample. Crystal data for 1: monoclinic, space group P 21/n, a = 8.5253(9), b = 9.2938(10), c = 19.654(2) Å, β = 102.289(2)°, V = 1521.6(3) Å3, Z = 4; 2: monoclinic, space group P 21/n , a = 8.3705(10), b = 9.9307(12), c = 10.5771(12) Å, β = 98.021(2)°, V = 870.62(18) Å3, Z = 2. The complex 1 is a one-dimensional coordination polymer with each Pb(II) atom being six-coordinated, forming a heavily distorted octahedral geometry, by two nitrogen and four oxygen donors. Each ligand links the Pb(II) ions in a chelating bridging mode using nitrogen and oxygen atoms of its pyridonate part. The complex 2 is a copper (II) complex with a compressed octahedral geometry. The Cu(II) atom locates on the equatorial positions defined by oxygen atoms of four water molecules. Its axial positions are filled with two oxygen donors of the pyridine-N-hydroxylate moieties of two ligands. The abundant hydrogen bonds link the molecules into one-dimensional chains. Both the complexes represent the first two examples of the energetic catalysts containing dinitropyridine derivatives characterized crystallographically

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References

  1. (a) Denisyuk1 AP, Demidova1 L (2004) Combust Explos Shock Waves 40:311 (b) Hewkin DJ, Hicks JA, Powling J, Watts SH (1971) Combust Sci Technol 2:307 (c) Denisyuk AP, Demidova LA, Galkin VI (1995) Combust Explos Shock Waves 31:61

  2. (a) Pundlik SM, Palaiah, RS, Nair JK et al (2001) J Energ Mater 19:339 (b) Klapotke TM, Rienacker CM (2001) Propellants Explos Pyrotechnics 26:43

    Google Scholar 

  3. Patchornik A (2002) Polym Adv Technol 13:1078

    Article  CAS  Google Scholar 

  4. (a) Kaye SM (1978) Encyclopedia of Explosives and Related Items, U.S. Army ARDEC, Dover, NJ 8:274 (b) Brill TB, Brush PJ, James KJ, Shepherd JE, Pfeiffer KJ (1991) Appl Spectrosc 46:900

  5. (a) Meng ZH, Hu RZ, Therm Anal (1995) 45:79 (b) Brill TB, Zhang TL, Tappan BC (2000) Combust Flame 121:662 (c) Wang YM, Chen C, Lin ST (1999) J Mol Struct (Theochem) 460:79

  6. Coburn MD, Lee KY (1990) J Heterocycl Chem 27:575

    Article  CAS  Google Scholar 

  7. (a)Song JR, Hu RZ, Kang B, Li FP (1999) Thermochim Acta 331:49 (b) Song JR, Chen ZX, Xiao HM, Hu RZ, Li FP (1999) Chin Sci Bull 44:214

  8. Yang YM, Zhang TL, Zhang JG, Shao B, Yu KB (2002) Chin J Struct Chem 21:321

    CAS  Google Scholar 

  9. Fang GY, Xu LN, Xiao HM, Ju XH (2005) Acta Chemica Sinica 63:1055

    CAS  Google Scholar 

  10. Zhang TL, Wang SZ, Yang L, Sun YH, Zhang JG, Qiao XJ (2006) Chin J Inorg Chem 22:1819

    CAS  Google Scholar 

  11. Zhao FQ, Chen P, Luo Y, Zhang RE, Li SW, Deng MZ, Zhen YM (2003) Chin J Explos Propellants 3:1

    Google Scholar 

  12. Chen P, Zhao FQ, Luo Y, Hu RZ, Zheng YM, Deng MZ, Gao Y (2004) Acta Chemica Sinica 13:1197

    Google Scholar 

  13. Zhen YM, Deng MZ, Zhao FQ, Yuan C (2002) Chin J Explos Propellants 4:51

    Google Scholar 

  14. Tanogaki M, Komura S (1994) JP 06220019

  15. Twieg R, Azema A, Jain K, Cheng YY (1982) Chem Phys Lett 92:208

    Article  CAS  Google Scholar 

  16. Driscoll PR, Fords NJ (1970) US Patent no. 3495969

  17. (a) Kemmitt T, Hubert-Pfalzgraf LG, Gainsford GJ, Richard P (2005) Inorg Chem Commun 8:1149 (b) Vassilyeva OY, Kokozay VN, Zhukova NA, Kovbasyuk LA (1997) Polyhedron 16:263

    Google Scholar 

  18. (a) Liat SL, Jenny PG, Charles WB (1998) Inorg Chem 37:1853 (b) Cecconi F, Ghilardi CA, Midollini S, Orlandini A (2000) Inorganica Chimica Acta 308:135

  19. Mahjoub AR, Morsali A (2002) Polyhedron 21:1223

    Article  CAS  Google Scholar 

  20. Chen P, Zhao FQ, Luo Y, Hu RZ, Gao SL, Zheng YM, Deng MZ, Gao Y (2004) Chin J Chem 22:1056

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We thank the Postgraduate-Innovation-Foundation of Shaanxi Normal University and the Combustion Key Laboratory of Xi’an Modern Chemistry Research Institute for financial support.

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Authors and Affiliations

  1. Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, Xi’an, 710062, P. R. China

    Jiang-Bo She, Guo-Fang Zhang & Zhong-Li Lei

  2. Xi’an Modern Chemistry Research Institute, Xi’an, 710065, P. R. China

    Feng-Qi Zhao & Xue-Zhong Fan

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  1. Jiang-Bo She
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  2. Guo-Fang Zhang
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  3. Feng-Qi Zhao
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Correspondence to Guo-Fang Zhang.

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She, JB., Zhang, GF., Zhao, FQ. et al. The first two structurally characterized energetic catalysts derived from dinitropyridone. Struct Chem 18, 373–378 (2007). https://doi.org/10.1007/s11224-007-9179-5

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