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Quantitative Generalization of Solvent Effect on Radical Halogenation of Hydrocarbons

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Abstract

The dependences of the isomer ratio in photochemical chlorination of 2,3-dimethylbutane and of the selectivity in photochemical bromination of a mixture of cyclopropylbenzene and toluene may be described by linear multiparameter equations. In the first case, the determining factors are the nonspecific solvation power and molar volume of the solvent, and in the second, the molar volume and cohesion energy density.

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REFERENCES

  1. Pincock, R.E., J. Am. Chem. Soc., 1964, vol. 86, p. 1820.

    Article  Google Scholar 

  2. Tsvetkov, N.S., Zhukovskii, V.Ya., Pirig, Ya.N., and Makitra, R.G., Reakts. Sposobn. Org. Soedin., 1976, vol. 16, p. 273.

    Google Scholar 

  3. Makitra, R.G., Pirig, Ya.N., and Yatchishin, I.I., Russ. J. Org. Chem., 1999, vol. 35, p. 1049.

    Google Scholar 

  4. Makitra, R.G., Polyuzhin, I.P., and Golovata, I.N., Russ. J. Gen. Chem., 2005, vol. 75, p. 172.

    Article  Google Scholar 

  5. Koppel, I.A. and Palm, V.A., Advances in Linear Free Energy Relationships, Chapman, N.B. and Shorter, J., Eds., London: Plenum, 1972, p. 203.

    Google Scholar 

  6. Russel, G.A., J. Am. Chem. Soc., 1958, vol. 80, p. 4987.

    Article  Google Scholar 

  7. Brown, H.C. and Brady, J.D., J. Am. Chem. Soc., 1952, vol. 74, p. 3570.

    Article  Google Scholar 

  8. Pytela, O., Collect. Czech. Chem. Commun., 1988, vol. 53, p. 1333.

    Google Scholar 

  9. Makitra, R.G., Pirig, Ya.N., and Kivelyuk, R.B., Available from VINITI, Moscow, 1985, no. 628-V86; Ref. Zh., Khim., 1986, no. 10 B 3299.

  10. Abboud, J.L.M. and Notario, R., Pure Appl. Chem., 1999, vol. 71, p. 645.

    Google Scholar 

  11. Makitra, R.G., Ukr. Khim. Zh., 1992, vol. 58, p. 228.

    Google Scholar 

  12. Tanko, M.J., Suleman, M.K., Hulvey, G.A., Park, A., and Powers, J.E., J. Am. Chem. Soc., 1993, vol. 115, p. 4520.

    Article  Google Scholar 

  13. Gur’yanova, E.N., Gol’dshtein, I.P., and Romm, I.P., Donorno-aktseptornaya svyaz’ (Donor-Acceptor Bond), Moscow: Khimiya, 1973, p. 323.

    Google Scholar 

  14. Makitra, R.G., Tsikanchuk, Ya.M., and Mel’nichuk, O.I., Zh. Obshch. Khim., 1973, vol. 43, p. 146.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Geology and Geochemistry of Fossil Fuels, National Academy of Sciences of Ukraine, Lviv, Ukraine

    R. G. Makitra & E. Ya. Pal’chikova

  2. Department of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79053, Ukraine

    G. G. Midyana

Authors
  1. R. G. Makitra
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  2. G. G. Midyana
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  3. E. Ya. Pal’chikova
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Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 7, 2005, pp. 967–972.

Original Russian Text Copyright © 2005 by Makitra, Midyana, Pal’chikova.

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Makitra, R.G., Midyana, G.G. & Pal’chikova, E.Y. Quantitative Generalization of Solvent Effect on Radical Halogenation of Hydrocarbons. Russ J Org Chem 41, 947–951 (2005). https://doi.org/10.1007/s11178-005-0274-z

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  • DOI: https://doi.org/10.1007/s11178-005-0274-z

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