Abstract
The reaction with chloral of 2-[1-(3-chlorophenyl)-2,2,2-trifluoroethoxy]-5,6-benzo-1,3,2-dioxaphosphorinan-4-one containing a chiral fluorinated exocyclic substituent on phosphorus leads to formation of 2-[1-(3-chlorophenyl)-2,2,2-trifluoroethoxy]-3-(trichloromethyl)-6,7-benzo-1,4,2λ5-dioxaphosphepin-5-one 2-oxide with a high regio- and stereoselectivity. The molecular and supramolecular structure of the isolated diastereomer was established by means of X-ray diffraction.
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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 12, 2004, pp. 1973–1980.
Original Russian Text Copyright © 2004 by Gubaidullin, Burnaeva, Mironov, Litvinov, Kotorova, Ivkova, Goryunov, Konovalova, Mastryukova.
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Gubaidullin, A.T., Burnaeva, L.M., Mironov, V.F. et al. Synthesis and steric structure of 2-[1-(3-chlorophenyl)-2,2,2-trifluoroethoxy]-3-(trichloromethyl)-6,7-benzo-1,4,2λ5-dioxaphosphepin-5-one 2-oxide. Russ J Gen Chem 74, 1861–1867 (2004). https://doi.org/10.1007/s11176-005-0109-1
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DOI: https://doi.org/10.1007/s11176-005-0109-1