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Preparation of new anion exchangers based on cross-linked polystyrene, their use in the CO2 addition to oxiranes and sorption of high field strength elements

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Abstract

Chloromethylation of cross-linked styrene-divinylbenzene beads with subsequent quaternization with amines was carried out. The resulting anion exchangers were tested as catalysts for the addition of CO2 to oxiranes and as sorbents for the separation of Zr, Nb, Hf, Ta, and Th salts from nitric acid solutions. The anion exchanger can be used in six catalytic cycles for the reaction of CO2 addition to oxiranes, which led to cyclic carbonates in quantitative yields.

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Funding

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (State Assignment No. 075-03-2023-642).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, S. T. Gazheev, A. Yu. Popov & P. V. Cherkasova

  2. Geological Institute, Russian Academy of Sciences, Build. 1, 7 Pyzhevskiy per., 119017, Moscow, Russian Federation

    Yu. A. Maksimova

Authors
  1. S. E. Lyubimov
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  2. S. T. Gazheev
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  3. A. Yu. Popov
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  4. P. V. Cherkasova
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  5. Yu. A. Maksimova
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Correspondence to S. E. Lyubimov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 73, No. 4, pp. 1046–1051, April, 2024.

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Lyubimov, S.E., Gazheev, S.T., Popov, A.Y. et al. Preparation of new anion exchangers based on cross-linked polystyrene, their use in the CO2 addition to oxiranes and sorption of high field strength elements. Russ Chem Bull 73, 1046–1051 (2024). https://doi.org/10.1007/s11172-024-4219-5

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  • DOI: https://doi.org/10.1007/s11172-024-4219-5

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