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Micellization of sodium dodecyl sulfate in the vicinity of Krafft point: an NMR and dielectric spectroscopy study

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Abstract

The structural state of ionic surfactant sodium dodecyl sulfate (SDS) on passing through the Krafft point (classical characteristic parameter determining the relationship between surfactant solubility and micelle formation) was studied by two independent physical methods, NMR and dielectric spectroscopies. It was established that the micellar structure of concentrated SDS solution is preserved on cooling down to 10 °C, which is much lower than the reported Krafft point of SDS lying near 18 °C.

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Funding

This work was carried out in the framework of the State Assignment to the Kazan Scientific Center of the Russian Academy of Sciences using the facilities (Bruker AVANCE III NMR spectrometer) at the Multiple-Access Spectro-Analytical Center for Physicochemical Studies of the Structure, Properties, and Composition of Substances and Materials at the Kazan Scientific Center of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Kazan Institute of Biochemistry and Biophysics, FRC Kazan Scientific Center of the Russian Academy of Sciences, 2/31 ul. Lobachevskogo, 420111, Kazan, Russian Federation

    Yu. F. Zuev, I. V. Lunev & A. N. Turanov

  2. Institute of Physics, Kazan Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    I. V. Lunev

  3. Kazan State Power Engineering University, 51 ul. Krasnosel’skaya, 420066, Kazan, Russian Federation

    O. S. Zueva

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  1. Yu. F. Zuev
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  2. I. V. Lunev
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  3. A. N. Turanov
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  4. O. S. Zueva
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Correspondence to Yu. F. Zuev.

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Dedicated to the memory of Academician of the Russian Academy of Sciences A. I. Konovalov (1934–2021) on the occasion of his 90th anniversary.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 73, No. 3, pp. 529–535, March, 2024.

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Zuev, Y.F., Lunev, I.V., Turanov, A.N. et al. Micellization of sodium dodecyl sulfate in the vicinity of Krafft point: an NMR and dielectric spectroscopy study. Russ Chem Bull 73, 529–535 (2024). https://doi.org/10.1007/s11172-024-4162-5

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  • DOI: https://doi.org/10.1007/s11172-024-4162-5

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