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Langmuir monolayers based on rigid wedge-shaped dendrons of benzenesulfonic acid

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Abstract

The structure formation of wedge-shaped monodendrons based on symmetric benzenesulfonic acid with different lengths of peripheral alkyl chains was studied in Langmuir monolayers and Langmuir–Blodgett (LB) films. A phase transition from the liquid-expanded state to the liquid-condensed state was observed on compression of the Langmuir monolayers of the dendrons containing dodecyl lateral chains. The transition is accompanied by the formation of star-shaped aggregates visualized by Brewster angle microscopy. The three-layer LB transfer results in the reorganization of the monolayer into regions of bi-, tetra-, and hexalayers on a solid substrate with a low coverage of the surface. Homogeneous liquid-condensed mono layers are formed for the dendrons with hexa- and octadecyl chains, and the film thickness achieved by the LB transfer corresponds to the monolayer alignment of the molecules with the surface coverage up to 90%. It was determined that varying the alkyl length of wedge-shaped dendrones based on symmetric benzenesulfonic acid leads to a change in phase behavior of Langmuir monolayers as well as Langmuir–Blodgett films formed by them.

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Authors and Affiliations

  1. MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technologies, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    Yu. N. Malakhova & A. A. Stupnikov

  2. National Research Center “Kurchatov Institute,”, 1 pl. Kurchatova, 123182, Moscow, Russian Federation

    Yu. N. Malakhova, A. A. Stupnikov, A. V. Bakirov, M. A. Shcherbina & S. N. Chvalun

  3. N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    A. V. Bakirov, M. A. Shcherbina & S. N. Chvalun

  4. University Osnabrück, Institute of Chemistry, Osnabrück, D-49069, Germany

    U. Beginn

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  1. Yu. N. Malakhova
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  2. A. A. Stupnikov
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  3. A. V. Bakirov
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  4. M. A. Shcherbina
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  5. U. Beginn
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Correspondence to Yu. N. Malakhova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1589–1594, September, 2018.

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Malakhova, Y.N., Stupnikov, A.A., Bakirov, A.V. et al. Langmuir monolayers based on rigid wedge-shaped dendrons of benzenesulfonic acid. Russ Chem Bull 67, 1589–1594 (2018). https://doi.org/10.1007/s11172-018-2262-9

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  • DOI: https://doi.org/10.1007/s11172-018-2262-9

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