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Hydrophilic functional copolymers of 1-vinyl-1,2,4-triazole with vinylsulfonic acid sodium salt

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Abstract

The free-radical copolymerization of 1-vinyl-1,2,4-triazole with vinylsulfonic acid sodium salt was conducted. New thermally stable functional water-soluble copolymers of various composition were synthesized. The structure and properties of the obtained copolymers were confirmed by IR, 1H NMR spectroscopy, and thermogravimetric methods. It was found that 1-vinyl-1,2,4-triazole has higher reactivity than sodium vinylsulfonate. TGA and DSC show that the produced copolymers are stable when heated to 260 °C.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    A. S. Pozdnyakov, E. A. Sekretarev, A. I. Emel’yanov & G. F. Prozorova

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  1. A. S. Pozdnyakov
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  2. E. A. Sekretarev
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  3. A. I. Emel’yanov
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  4. G. F. Prozorova
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Correspondence to A. S. Pozdnyakov.

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On the occasion of the 60th anniversary of A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2293–2297, December, 2017.

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Pozdnyakov, A.S., Sekretarev, E.A., Emel’yanov, A.I. et al. Hydrophilic functional copolymers of 1-vinyl-1,2,4-triazole with vinylsulfonic acid sodium salt. Russ Chem Bull 66, 2293–2297 (2017). https://doi.org/10.1007/s11172-017-2017-z

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  • DOI: https://doi.org/10.1007/s11172-017-2017-z

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