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Synthesis, structure, photo- and electroluminescence studies of bis[2-(N-tosylamino)benzylidene-4′-dimethylaminophenylaminato]zinc

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Abstract

A new bis[2-(N-tosylamino)benzylidene-4′-dimethylaminophenylaminato]zinc complex was synthesized, its structure was studied by methods of elemental analysis, IR spectroscopy, 1H NMR spectroscopy, X-ray absorption spectroscopy, and quantum chemical calculations. Electron absorption and photoluminescence spectra of the zinc complex were investigated. An OLED device based on it was made and found to emit “soft” yellow light with CIE coordinates (x = 0.431, y = 0.537) and radiation luminance 1300 cd m−2 at a working voltage of 14 V.

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References

  1. I. K. Yakushchenko, M. G. Kaplunov, S. N. Shamaev, O. N. Efimov, G. V. Nikolaeva, M. Yu. Belov, A. P. Pivovarov, A. G. Skvortsov, V. A. Voronina, Pat. RF No. 2155204, publ. 27.08.2000 (in Russian); http://www.findpatent.ru/patent/215/2155204.html

  2. J. Xie, J. Qiao, L. Wang, J. Xie, Y. Qiu, Inorg. Chim. Acta, 2005, 358, 4451.

    Article  CAS  Google Scholar 

  3. L. P. Wang, S. B. Jiao, W. F. Zhang, Y. Q. Liu, G. Yu, Chin. Sci. Bull., 2013, 58, 2733.

    Article  CAS  Google Scholar 

  4. L. Chen, J. Qiao, J. Xie, L. Duan, D. Zhang, L. Wang, Y. Qiu, Inorg. Chim. Acta, 2009, 362, 2327.

    Article  CAS  Google Scholar 

  5. A. P. Pivovarov, M. G. Kaplunov, I. K. Yakuscchenko, M. Yu. Belov, G. V. Nikolaeva, O. N. Efimov, Russ. Chem. Bull. (Int. Ed.), 2002, 51, 67 [Izv. Akad. Nauk, Ser. Khim., 2002, 65].

    Article  CAS  Google Scholar 

  6. M. G. Kaplunov, I. K. Yakuscchenko, S. S. Krasnikova, S. N. Shamaev, A. P. Pivovarov, O. N. Efimov, Russ. Chem. Bull. (Int. Ed.), 2004, 53, 2148 [Izv. Akad. Nauk, Ser. Khim., 2004, 2056].

    Article  CAS  Google Scholar 

  7. A. V. Metelitsa, A. S. Burlov, S. O. Bezuglyi, A. D. Garnovskii, V. A. Bren’, V. I. Minkin, N. N. Kharabaev, Pat. RF No. 2295527, publ. 20.03.2007, Byull. [Bull.] No. 8 (in Russian); http://www.findpatent.ru/patent/229/2295527.html

  8. A. V. Metelitsa, A. S. Burlov, S. O. Bezuglyi, I. G. Borodkina, I. S. Vasil’chenko, D. A. Garnovskii, S. A. Mashchenko, G. S. Borodkin, A. D. Garnovskii, V. I. Minkin, Pat. RF No. 2395512, publ. 27.07.2010, Byull. [Bull.] No. 21 (in Russian); http://www.findpatent.ru/patent/239/2395512.html

  9. M. R. Bermejo, M. Vasquez, J. Sanmartin, A. M. Garcia-Deibe, M. Fondo, C. Lodeiro, New J. Chem., 2002, 26, 1365.

    Article  CAS  Google Scholar 

  10. M. Vazquez, A. Taglietti, D. Gatteschi, L. Sorace, C. Sangregorio, A. M. Gonzalez, M. Maneiro, R. M. Pedrido, M. R. Bermejo, Chem. Commun., 2003, 15, 1840.

    Article  Google Scholar 

  11. M. Vazquez, M. R. Bermejo, M. Licchelli, A. M. Gonzalez-Noya, R. M. Pedrido, C. Sangregorio, L. Sorace, A. M. Garcia-Deibe, J. Sanmartin, Eur. J. Inorg. Chem., 2005, 17, 3479.

    Article  Google Scholar 

  12. L. Rodriguez, E. Labisbal, A. Sousa-Pedrares, J. Romero, J.-A. G. Vazquez, A. Sousa, Z. Anorg. Allg. Chem., 2007, 633, 1832.

    Article  CAS  Google Scholar 

  13. N. I. Chernova, Yu. S. Ryabokobylko, V. G. Brudz’, B. M. Bolotin, Zh. Org. Khim., 1971, 7, 1680 [J. Org. Chem. USSR (Engl. Transl.), 1971, 7, No. 8].

    CAS  Google Scholar 

  14. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, J. A. Pople, Gaussian 03, Revision A.1, Gaussian, Inc., Pittsburgh (PA), USA, 2003.

    Google Scholar 

  15. C. Lee, W. Yang, R. G. Parr, Phys. Rev. B., 1988, 37, 785.

    Article  CAS  Google Scholar 

  16. A. D. Becke, J. Chem. Phys., 1993, 98, 5648.

    Article  CAS  Google Scholar 

  17. A. D. McLean, G. S. Chandler, J. Chem. Phys., 1980, 72, 5639.

    Article  CAS  Google Scholar 

  18. R. Krishnan, J. S. Binkley, R. Seeger, J. A. Pople, J. Chem. Phys., 1980, 72, 650.

    Article  CAS  Google Scholar 

  19. A. A. Chernyshov, A. A. Veligzhanin, Y. V. Zubavichus, Nucl. Instr. Meth. Phys. Res. A., 2009, 603, 95.

    Article  CAS  Google Scholar 

  20. M. Newville, J. Synchrotron Rad., 2001, 8, 96.

    Article  CAS  Google Scholar 

  21. S. I. Zabinski, J. J. Rehr, A. Ankudinov, R. C. Alber, Phys. Rev. B, 1995, 52, 2995.

    Article  Google Scholar 

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov on Don, Russian Federation

    A. S. Burlov, D. A. Garnovskii, A. I. Uraev, G. S. Borodkin & A. V. Metelitsa

  2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Korp. 4, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. I. Mal’tsev, A. V. Dmitriev & D. A. Lypenko

  3. Research Institute of Physics, Southern Federal University, 194 prosp. Stachki, 344090, Rostov on Don, Russian Federation

    V. G. Vlasenko

  4. Southern Research Center, Russian Academy of Sciences, 41 ul. Chekhova, 344006, Rostov on Don, Russian Federation

    D. A. Garnovskii

Authors
  1. A. S. Burlov
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  2. E. I. Mal’tsev
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  3. V. G. Vlasenko
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  4. A. V. Dmitriev
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  5. D. A. Lypenko
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  6. D. A. Garnovskii
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  7. A. I. Uraev
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  8. G. S. Borodkin
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  9. A. V. Metelitsa
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Corresponding author

Correspondence to A. S. Burlov.

Additional information

Based on the materials of the XI International Seminar on Magnetic Resonance (Spectroscopy, Tomography, and Ecology) (September 9–14, 2013, Rostov-on-Don).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1759–1764, August, 2014.

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Burlov, A.S., Mal’tsev, E.I., Vlasenko, V.G. et al. Synthesis, structure, photo- and electroluminescence studies of bis[2-(N-tosylamino)benzylidene-4′-dimethylaminophenylaminato]zinc. Russ Chem Bull 63, 1759–1764 (2014). https://doi.org/10.1007/s11172-014-0664-x

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  • DOI: https://doi.org/10.1007/s11172-014-0664-x

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