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Electrochemical switching of monomer—associate in the system tetraviologen calix[4]resorcinol—3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane

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Abstract

The possibility of controlling the association of tetraviologen calix[4]resorcinol (MVCA-C5 8+) with 3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane (APCO-22−) in the electrochemical cycle of reduction-reoxidation of viologen units was shown. Reduction to tetra(radical cation) MVCA-C5 4+· transforms monomeric MVCA-C5 8+ and APCO-22- into the associate (π-polymer) (xAPCO-22−·yMVCA-C5 4+·) n , which is completely returned by reoxidation to the initial state.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    G. R. Nasybullina, V. V. Yanilkin, A. Yu. Ziganshina, V. I. Morozov, E. D. Sultanova, D. E. Korshin, Yu. S. Spiridonova, A. S. Balueva, A. A. Karasik & A. I. Konovalov

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  1. G. R. Nasybullina
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  2. V. V. Yanilkin
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  3. A. Yu. Ziganshina
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  4. V. I. Morozov
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  7. Yu. S. Spiridonova
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  8. A. S. Balueva
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  9. A. A. Karasik
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  10. A. I. Konovalov
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Correspondence to V. V. Yanilkin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2158–2170, October, 2013.

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Nasybullina, G.R., Yanilkin, V.V., Ziganshina, A.Y. et al. Electrochemical switching of monomer—associate in the system tetraviologen calix[4]resorcinol—3,7-di(l-menthyl)-1,5-di(p-sulfonatophenyl)-1,5-diaza-3,7-diphosphacyclooctane. Russ Chem Bull 62, 2158–2170 (2013). https://doi.org/10.1007/s11172-013-0315-7

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