Abstract
1,6-Dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole and 4- and 5-nitro-1,6-dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole were synthesized starting from 2,4-dinitrosore-sorcinol, whereas 4,7-dihydro-1,4,7-trihydroxy-1H-benzo[1,2-d:3,4-d′:5,6-d″]tris[1,2,3]-triazole was synthesized starting from phloroglucinol. The reaction of trinitrosophloroglucinol with hydrazine hydrate in acetic acid led to 2,4,6-tridiazocyclohexane-1,3,5-trione.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1760–1766, September, 2012.
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Samsonov, V.A., Gatilov, Y.V. & Volodarskii, L.B. Synthesis of 1,6-dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole, 4- and 5-nitro-1,6-dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole and 4,7-dihydro-1,4,7-trihydroxy-1H-benzo-[1,2-d:3,4-d′:5,6-d″]tris[1,2,3]triazole. Russ Chem Bull 61, 1776–1782 (2012). https://doi.org/10.1007/s11172-012-0244-x
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DOI: https://doi.org/10.1007/s11172-012-0244-x