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Synthesis and physicochemical properties of polyurethane block copolymers and their compositions with plasticizers

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Abstract

The synthesis of polyurethane block based on oligoesterdiols 4,4′-methylene-bis(phenylisocyanate), and various chain elongating agents was studied. The properties of these copolymers were compared (using literature data) with selected properties of polyurethanes obtained by the reactions of oligoetherdiols, viz., oligo-3,3′-bis(azidomethyl)oxetanediol and oligo-3-azidomethyl-3′-methyloxetanediol with diisocyanates. The complex of rheological and physicomechanical properties of the initial and plasticized polyurethane block copolymers was studied. Regularities of their deformation behavior were established. The process of mutual solubility was studied by the microinterference method for a wide range of systems block copolymers—plasticizers. On the basis of the data obtained, the phase diagrams were constructed for limitedly compatible systems.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    Yu. M. Mikhailov, L. V. Ganina, E. R. Badamshina, V. S. Smirnov & Yu. B. Kalmykov

  2. Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, 3 ul. Akad. Koroleva, 614013, Perm, Russian Federation

    V. V. Tereshatov

  3. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125190, Moscow, Russian Federation

    Yu. M. Lotmentsev

Authors
  1. Yu. M. Mikhailov
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  2. L. V. Ganina
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  3. V. V. Tereshatov
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  4. E. R. Badamshina
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  5. V. S. Smirnov
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  6. Yu. B. Kalmykov
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  7. Yu. M. Lotmentsev
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Corresponding author

Correspondence to L. V. Ganina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1900—1906, September, 2011.

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Mikhailov, Y.M., Ganina, L.V., Tereshatov, V.V. et al. Synthesis and physicochemical properties of polyurethane block copolymers and their compositions with plasticizers. Russ Chem Bull 60, 1933–1939 (2011). https://doi.org/10.1007/s11172-011-0291-8

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  • DOI: https://doi.org/10.1007/s11172-011-0291-8

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