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Cycloaddition of diazoacetates to C60 fullerene catalysed by Pd complexes

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Abstract

An efficient catalytic method of the cycloaddition to C60 fullerene of the diazoacetates, containing substituents of diverse structures in ester groups, in the presence of a Pd-based three-component catalyst was developed. An influence of nature and the structure of substituent in the ester group on the activity of diazoacetates in the reaction with C60 was studied. Yields of respective cycloadducts were determined.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    A. R. Tuktarov, A. R. Akhmetov, L. L. Khasanova, L. M. Khalilov & U. M. Dzhemilev

Authors
  1. A. R. Tuktarov
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  2. A. R. Akhmetov
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  3. L. L. Khasanova
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  4. L. M. Khalilov
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  5. U. M. Dzhemilev
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Corresponding author

Correspondence to A. R. Tuktarov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1909–1913, October, 2010.

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Tuktarov, A.R., Akhmetov, A.R., Khasanova, L.L. et al. Cycloaddition of diazoacetates to C60 fullerene catalysed by Pd complexes. Russ Chem Bull 59, 1959–1963 (2010). https://doi.org/10.1007/s11172-010-0339-1

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  • DOI: https://doi.org/10.1007/s11172-010-0339-1

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