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Physicochemical and functional peculiarities of metal oxide whiskers

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Abstract

Practical aspects of preparation and prospects for practical use of a series of the metal oxide whiskers were studied. The procedures for the synthesis were proposed, and the phase composition, micromorphology, and electrochemical and sensor characteristics of the macroscopic (up to 5–10 mm long) whiskers in the Ba-V-O, Ba-Mn-O, and Sn-O systems were analyzed. The electroconducting BaV8O21-δ whiskers were prepared by the hydrothermal treatment. These whiskers possess stable electrochemical characteristics appropriate for the development of novel secondary current sources. The protonated form of the Ba6Mn24O48 whiskers produced by the isothermal vaporization of chloride fluxes is a mixed conductor with the proton and electron conductivity at a level of mS units at 25 °C. A new procedure by the thermal disproportionation of tin(ii) oxide under nitrogen was proposed for the growth of SnO2 whiskers of various morphology. The produced whiskers have substantial sensor sensitivity toward a series of toxic components of the gaseous medium, such as nitrogen dioxide.

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Authors and Affiliations

  1. Materials Science Department, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. A. Goodilin, E. A. Pomerantseva, D. A. Semenenko, P. B. Kocherginskaya, D. M. Itkis, S. B. Balakhonov & Yu. D. Tretyakova

  2. Chemical Department, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. A. Goodilin, M. N. Rumyantseva, A. M. Gas’kov, B. R. Churagulov & Yu. D. Tretyakova

  3. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Mосквa, Moscow, Russian Federation

    T. L. Kulova & A. M. Skundin

  4. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    L. S. Leonova & Yu. A. Dobrovol’skii

Authors
  1. E. A. Goodilin
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  2. E. A. Pomerantseva
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  3. D. A. Semenenko
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  4. P. B. Kocherginskaya
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  5. D. M. Itkis
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  6. T. L. Kulova
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  7. A. M. Skundin
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  8. L. S. Leonova
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  9. Yu. A. Dobrovol’skii
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  10. M. N. Rumyantseva
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  11. A. M. Gas’kov
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  12. S. B. Balakhonov
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  13. B. R. Churagulov
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  14. Yu. D. Tretyakova
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Correspondence to E. A. Goodilin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1023–1034, May, 2008.

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Goodilin, E.A., Pomerantseva, E.A., Semenenko, D.A. et al. Physicochemical and functional peculiarities of metal oxide whiskers. Russ Chem Bull 57, 1042–1053 (2008). https://doi.org/10.1007/s11172-008-0133-5

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  • DOI: https://doi.org/10.1007/s11172-008-0133-5

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