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Cuboidal oxalate cluster complexes with the Mo3CuQ4 5+ cluster core (Q = S or Se): synthesis, structure, and electrochemical properties

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Abstract

The reactions of the [Mo3(μ3-Q)(μ2-Q)3(H2O)3(C2O4)3]2− complex (Q = S or Se) with CuX salts (X = Cl, Br, I, or SCN) in water produce the cuboidal heterometallic clusters [Mo3(CuX)(μ3-Q)4(H2O)3(C2O4)3]2−, which were isolated as the potassium and tetraphenylphosphonium salts. Two new compounds, K2[Mo3(CuI)(μ3-S)4(H2O)3(C2O4)3]·6H2O and (PPh4)2[Mo3(CuBr)(μ3-S)4(H2O)3(C2O4)3]·7H2O, were structurally characterized. All compounds were characterized by elemental analysis and IR spectroscopy. The K2[Mo3(CuI)(μ3-Se)4(H2O)3(C2O4)3] compound was characterized by the 77Se NMR spectrum; the (PPh4)2[Mo3(CuI)(μ3-S)4(H2O)3(C2O4)3], (PPh4)2[Mo3(CuI)(μ3-Se)4(H2O)3(C2O4)3] and K2[Mo3(CuSCN)(μ3-S)4(H2O)3(C2O4)3]·7H2O compounds, by electrospray mass spectra.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    A. L. Gushchin, K. A. Kovalenko, M. N. Sokolov, D. Yu. Naumov, N. F. Zakharchuk & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    K. A. Kovalenko

  3. Jaume I University, 12080, Castellon, Spain

    C. Vicent

Authors
  1. A. L. Gushchin
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  2. K. A. Kovalenko
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  3. M. N. Sokolov
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  4. D. Yu. Naumov
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  5. N. F. Zakharchuk
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  6. C. Vicent
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  7. V. P. Fedin
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Correspondence to V. P. Fedin.

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Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1639–1644, September, 2007.

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Gushchin, A.L., Kovalenko, K.A., Sokolov, M.N. et al. Cuboidal oxalate cluster complexes with the Mo3CuQ4 5+ cluster core (Q = S or Se): synthesis, structure, and electrochemical properties. Russ Chem Bull 56, 1701–1706 (2007). https://doi.org/10.1007/s11172-007-0264-0

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  • DOI: https://doi.org/10.1007/s11172-007-0264-0

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