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Selective cross-coupling of 1-ethynyl-4-iodobenzenes with activated arylacetylenes

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Abstract

Conditions were found for selective cross-coupling of 1-ethynyl-2,5-dihexyl-4-iodobenzene with arylethynyl-activated arylacetylenes. The reaction is not accompanied by homo-condensation of 1-ethynyl-2,5-dihexyl-4-iodobenzene.

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Authors and Affiliations

  1. Joint Research Center for Precision Polymerization, 1-1 Higashi, 305-8565, Tsukuba, Ibaraki, Japan

    A. I. Kovalev, K. Takeuchi, M. Asai & M. Ueda

  2. National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 5, 1-1-1 Higashi, 305-8565, Tsukuba, Ibaraki, Japan

    A. I. Kovalev, K. Takeuchi, M. Asai & M. Ueda

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. I. Kovalev & A. L. Rusanov

  4. Tokyo Institute of Technology, Meguro-ku, 152-8552, Tokyo, Japan

    M. Ueda

Authors
  1. A. I. Kovalev
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  2. K. Takeuchi
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  3. M. Asai
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  4. M. Ueda
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  5. A. L. Rusanov
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Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1682–1687, August, 2004.

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Kovalev, A.I., Takeuchi, K., Asai, M. et al. Selective cross-coupling of 1-ethynyl-4-iodobenzenes with activated arylacetylenes. Russ Chem Bull 53, 1749–1754 (2004). https://doi.org/10.1007/s11172-005-0029-6

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  • DOI: https://doi.org/10.1007/s11172-005-0029-6

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